2,2-Bis[4-(4-aminophenoxy)phenyl]propane
- Product Name
- 2,2-Bis[4-(4-aminophenoxy)phenyl]propane
- CAS No.
- 13080-86-9
- Chemical Name
- 2,2-Bis[4-(4-aminophenoxy)phenyl]propane
- Synonyms
- BAPP;2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE;4-BAPOPP;4,4'-(4,4'-Isopropyl;2,2’-bis(4-aminophenoxyphenyl)propane;2,2'-Bis(4-aminophenoxyphenyl) propane;2,2-Bis[4-(4-aminophenoxy)phenyl]propan;2,2-Bis[p-(4-aMinophenoxy)phenyl]propane;2,2'-Bis[4-(4-aminophenoxy)pheny]propane;2,2-Bis[p-(p-aminophenoxy)phenyl]propane
- CBNumber
- CB3780578
- Molecular Formula
- C27H26N2O2
- Formula Weight
- 410.51
- MOL File
- 13080-86-9.mol
2,2-Bis[4-(4-aminophenoxy)phenyl]propane Property
- Melting point:
- 127-130 °C(lit.)
- Boiling point:
- 587.1±50.0 °C(Predicted)
- Density
- 1.178±0.06 g/cm3(Predicted)
- vapor pressure
- 0-0Pa at 20-25℃
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- Solid:particulate/powder
- pka
- 5.16±0.10(Predicted)
- Water Solubility
- Very slightly soluble in water. Soluble in acetone, Dimethyl sulfoxide(DMSO).
- InChI
- InChI=1S/C27H26N2O2/c1-27(2,19-3-11-23(12-4-19)30-25-15-7-21(28)8-16-25)20-5-13-24(14-6-20)31-26-17-9-22(29)10-18-26/h3-18H,28-29H2,1-2H3
- InChIKey
- KMKWGXGSGPYISJ-UHFFFAOYSA-N
- SMILES
- C(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C)C
- LogP
- 4.3-4.9 at 35℃ and pH7
- CAS DataBase Reference
- 13080-86-9(CAS DataBase Reference)
- EPA Substance Registry System
- Benzenamine, 4,4'-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis- (13080-86-9)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26-36
- WGK Germany
- 3
- RTECS
- CY1062500
- TSCA
- Yes
- HS Code
- 29222990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 476331
- Product name
- 4,4′-(4,4′-Isopropylidenediphenyl-1,1′-diyldioxy)dianiline
- Purity
- 98%
- Packaging
- 50g
- Price
- $82.8
- Updated
- 2024/03/01
- Product number
- B1551
- Product name
- 2,2-Bis[4-(4-aminophenoxy)phenyl]propane
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 25g
- Price
- $37
- Updated
- 2024/03/01
- Product number
- B1551
- Product name
- 2,2-Bis[4-(4-aminophenoxy)phenyl]propane
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 250g
- Price
- $228
- Updated
- 2024/03/01
- Product number
- H55057
- Product name
- 2,2-Bis[4-(4-aminophenoxy)phenyl]propane, 98%
- Packaging
- 25g
- Price
- $34.65
- Updated
- 2024/03/01
- Product number
- H55057
- Product name
- 2,2-Bis[4-(4-aminophenoxy)phenyl]propane, 98%
- Packaging
- 100g
- Price
- $112
- Updated
- 2024/03/01
2,2-Bis[4-(4-aminophenoxy)phenyl]propane Chemical Properties,Usage,Production
Description
2,2-Bis[4-(4-aminophenoxy)phenyl]propane (BAPP), also known as 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline, is a diamino monomer with a diphenoxy-phenyl core. Since the molecule has two amine groups at both ends, it can be cross-linked with carboxylic acids or carboxylic dianhydrides to synthesize polyimides. It is commonly as a monomer for the preparation of polyimides in application of batteries, fuel cells, low dielectric materials and OLEDs.
Chemical Properties
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (2,2-Bis[4-(4-aminophenoxy)phenyl]propane) is white solid
Uses
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline is used for preparation polyimide and epoxy resin material.
Uses
It is applied in pharmaceutical industry.
Application
2,2-Bis[4-(4-aminophenoxy)phenyl] propane (BAPP) can be used for:
(1) Preparation of polyimides. The glass transition temperature of this new polyimide is about 225-230°C. It has the typical yield of thermoplastic polymers. It has a typical thermoplastic polymer yield behaviour, which is very different from other polyimides. The elongation at break was 6% and 29% for polyamide and polyimide, respectively.
(2) Curing epoxy resin (ER) and poly(?-caprolactone) (PCL) for the preparation of crystalline thermoset blends.
(3) Constructing dental resin composites.
Synthesis
2,2‐Bis[4‐(4‐aminophenoxy)phenyl] propane (BAPP), as a monomer to prepare polyimide, was synthesized from Bisphenol A and p‐chloronitrobenzene via the nucleophilic substitution reaction[1].
References
[1] CUILI KONG. Synthesis, Structures and Properties of Polyimide Based on 2,2′‐Bis(4‐aminophenoxy phenyl) Propane[J]. Journal of Macromolecular Science, Part A, 2006. DOI:10.1080/10601320600941086.
2,2-Bis[4-(4-aminophenoxy)phenyl]propane Preparation Products And Raw materials
Raw materials
Preparation Products
2,2-Bis[4-(4-aminophenoxy)phenyl]propane Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28398
- Advantage
- 80
View Lastest Price from 2,2-Bis[4-(4-aminophenoxy)phenyl]propane manufacturers
- Product
- 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline 13080-86-9
- Price
- US $142.00-135.00/kg
- Min. Order
- 1kg
- Purity
- 99.99%
- Supply Ability
- 100Tons
- Release date
- 2023-03-03
- Product
- 2,2'-Bis[4-(4- aMinophenoxy)phenyl]propane(BAPP) 13080-86-9
- Price
- US $30.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100 tons
- Release date
- 2022-10-18
- Product
- 4,4'-((Propane-2,2-diylbis(4,1-phenylene))bis(oxy))dianiline 13080-86-9
- Price
- US $111.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-08