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3-Chlorotoluene

Product Name
3-Chlorotoluene
CAS No.
108-41-8
Chemical Name
3-Chlorotoluene
Synonyms
MCT;META CHLORO TOLUENE;M-CHLOROTOLUENE;1-CHLORO-3-METHYLBENZENE;3-Chlortoluol;m-Chlortoluol;M-Chlorotoluen;3-CHLOROTOLUENE;m-Tolylchloride;3-Chlorobenzene
CBNumber
CB3852749
Molecular Formula
C7H7Cl
Formula Weight
126.58
MOL File
108-41-8.mol
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3-Chlorotoluene Property

Melting point:
-48 °C (lit.)
Boiling point:
160-162 °C (lit.)
Density 
1.072 g/mL at 25 °C (lit.)
vapor pressure 
3.6 mbar @ 20 C
refractive index 
n20/D 1.522(lit.)
Flash point:
123 °F
storage temp. 
0-6°C
solubility 
0.04g/l
form 
Liquid
color 
Clear colorless to slightly yellow
explosive limit
1.3-8.3%(V)
Water Solubility 
slightly soluble
Merck 
14,2171
BRN 
1903632
Dielectric constant
5.5499999999999998
Stability:
Stable. Flammable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
108-41-8(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-chloro-3-methyl-(108-41-8)
EPA Substance Registry System
m-Chlorotoluene (108-41-8)
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Safety

Hazard Codes 
Xn,N
Risk Statements 
20-51/53
Safety Statements 
24/25-61
RIDADR 
UN 2238 3/PG 3
WGK Germany 
2
RTECS 
XS8990000
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29039990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H332Harmful if inhaled

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
138509
Product name
3-Chlorotoluene
Purity
98%
Packaging
100g
Price
$113
Updated
2024/03/01
Sigma-Aldrich
Product number
36696
Product name
3-Chlorotoluene
Purity
PESTANAL?, analytical standard
Packaging
1G
Price
$24.7
Updated
2022/05/15
TCI Chemical
Product number
C0296
Product name
3-Chlorotoluene
Packaging
25G
Price
$23
Updated
2024/03/01
TCI Chemical
Product number
C0296
Product name
3-Chlorotoluene
Packaging
500G
Price
$104
Updated
2024/03/01
Alfa Aesar
Product number
A16991
Product name
3-Chlorotoluene, 98%
Packaging
500g
Price
$122
Updated
2023/06/20
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3-Chlorotoluene Chemical Properties,Usage,Production

Chemical Properties

o-Chlorotoluene is a flammable, colorless liquid with an aromatic odor. Insoluble in water, easily soluble in benzene, ethanol, ether and chloroform.

Uses

3-Chlorotoluene was used as catalyst in the synthesis of glycidyl methacrylate grafted multi-walled carbon nanotubes/polypropylene nanocomposites. It was used to study paramagnetic contributions from dioxygen to solute proton spin-lattice relaxation rate constants for a series of aromatic hydrocarbons and drug molecule fragments.

Application

3-Chlorotoluene is used as a reagent to synthesize 4-Arylchromene derivatives, compounds that induce apoptosis and act as anti-cancer agents. 3-Chlorotoluene is also used as an ingredient in deodorant, and is suspected to cause allergic contact dermatitis in humans.

Preparation

3-Chlorotoluene is obtained from m-toluidine by diazotization and substitution. Add m-toluidine to water, slowly add concentrated hydrochloric acid, and add sodium nitrite solution dropwise at 0-5°C. Then the diazo solution is added to the cuprous chloride for replacement reaction. The crude product generated is distilled to obtain the finished product. If the diazo salt is made into a zinc chloride complex salt of m-toluidine diazo salt, it is decomposed by reflux in ether, and the reactants are cooled, washed and dried. After recovering the ether, it is distilled at atmospheric pressure and m-chlorotoluene is obtained by collecting 160-162°C fraction. The advantage of this method is that the diazonium salt is not easy to hydrolyze and generate phenols.

General Description

3-Chlorotoluene is a colorless liquid. Specific gravity 1.072. Denser than water, thus sinks in water. Flash point less than 141°F. Vapors irritating and narcotic in high concentrations. Used as solvents and as an intermediate for making other chemicals and dyes.

Air & Water Reactions

Flammable. Slightly soluble in water.

Reactivity Profile

3-Chlorotoluene is generally unreactive. May be incompatible with strong oxidizing and reducing agents. May be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Hazard

Narcotic in high concentration. Avoid inhalation.

Health Hazard

Inhalation causes upper respiratory irritation. Irritating to skin and eyes. May be absorbed through the skin. Prolonged exposure may result in systemic toxic effects. Harmful if swallowed.

Potential Exposure

o-Chlorotoluene is widely used as a solvent and intermediate in the synthesis of dyes, synthetic rubber; pharmaceuticals; and other organic chemicals. Used as an insecticide, bactericide.

Shipping

UN2238 Chlorotoluenes, Hazard Class: 3; Labels: 3-Flammable liquid.

Purification Methods

Purify it as for 2-chlorotoluene above. [Beilstein 5 IV 806.]

Incompatibilities

Incompatible with acids, alkalis, oxidizers, reducing materials; water

Waste Disposal

In accordance with 40CFR165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

3-Chlorotoluene Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Chlorotoluene Suppliers

Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
China Langchem Inc.
Tel
0086-21-58956006
Fax
0086-21-58956100
Country
China
ProdList
7811
Advantage
57
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View Lastest Price from 3-Chlorotoluene manufacturers

Shanghai Xin Cheng Yue Chemical Co.,Ltd
Product
3-Chlorotoluene 108-41-8
Price
US $0.00-0.00/kg
Min. Order
1000kg
Purity
99.8%
Supply Ability
100000ton
Release date
2024-01-26
Hebei Weibang Biotechnology Co., Ltd
Product
3-Chlorotoluene 108-41-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-08
Henan Fengda Chemical Co., Ltd
Product
3-Chlorotoluene 108-41-8
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26

108-41-8, 3-ChlorotolueneRelated Search:


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