ChemicalBook > CAS DataBase List > 2,4-diaminophenol

2,4-diaminophenol

Product Name
2,4-diaminophenol
CAS No.
95-86-3
Chemical Name
2,4-diaminophenol
Synonyms
Nsc5727;AIDS-025968;DIAMINOPHENOL;Phenol, 2,4-diamino-
CBNumber
CB3907708
Molecular Formula
C6H8N2O
Formula Weight
124.14
MOL File
95-86-3.mol
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2,4-diaminophenol Property

Melting point:
79°C (rough estimate)
Boiling point:
230.92°C (rough estimate)
Density 
1.1683 (rough estimate)
refractive index 
1.5745 (estimate)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
10.02±0.18(Predicted)
LogP
-1.290 (est)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Matrix Scientific
Product number
119803
Product name
2,4-Diaminophenol
Purity
95+%
Packaging
1g
Price
$216
Updated
2021/12/16
AK Scientific
Product number
6564AC
Product name
2,4-Diaminophenol
Packaging
1g
Price
$341
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0143401
Product name
2,4-DIAMINOPHENOL
Purity
95.00%
Packaging
5MG
Price
$503.1
Updated
2021/12/16
Matrix Scientific
Product number
119803
Product name
2,4-Diaminophenol
Purity
95+%
Packaging
5g
Price
$648
Updated
2021/12/16
Matrix Scientific
Product number
119803
Product name
2,4-Diaminophenol
Purity
95+%
Packaging
10g
Price
$1044
Updated
2021/12/16
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2,4-diaminophenol Chemical Properties,Usage,Production

Uses

Used in dye manufacture, in hair and fur dyeing, and in tests for formaldehyde and ammonia.

Synthesis

51-28-5

95-86-3

In a 1000 mL autoclave, 100 g of 2,4-dinitrophenol, 405 mL of methanol, and 6 g of Pd/C catalyst were sequentially added, and the mixture was stirred at room temperature for 5 min, followed by system displacement with nitrogen. After ensuring that the autoclave was well sealed, the temperature was gradually increased to 65 °C, while the hydrogen inlet valve was opened to maintain the reaction system pressure at 0.48 MPa, and the reaction lasted for 1 hour. Subsequently, the hydrogen inlet valve was adjusted to increase the pressure to 0.85 MPa, and the reaction was continued for 0.5 hours. Upon completion of the reaction, the system temperature was lowered to 40°C and replaced three times with nitrogen to remove residual hydrogen. The reaction mixture was separated by filtration to recover the Pd/C catalyst, and the filtrate was treated under nitrogen protection to give 64.8 g of 2,4-diaminophenol in 96.16% yield and 99.2% purity.

References

[1] Synthetic Communications, 2006, vol. 36, # 18, p. 2699 - 2704
[2] Applied Organometallic Chemistry, 2017, vol. 31, # 12,
[3] Patent: CN108440333, 2018, A. Location in patent: Paragraph 0037-0046
[4] Synthetic Communications, 2003, vol. 33, # 2, p. 281 - 289
[5] Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2009, vol. 48, # 9, p. 1315 - 1318

2,4-diaminophenol Preparation Products And Raw materials

Raw materials

Preparation Products

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2,4-diaminophenol Suppliers

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View Lastest Price from 2,4-diaminophenol manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2,4-diaminophenol 95-86-3
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-15
Shaanxi Dideu Medichem Co. Ltd
Product
2,4-diaminophenol 95-86-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000KG
Release date
2024-08-15
Henan Bao Enluo International TradeCo.,LTD
Product
2,4-diaminophenol 95-86-3
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500t/month
Release date
2023-08-03