ChemicalBook > CAS DataBase List > (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
- Product Name
- (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
- CAS No.
- 791616-62-1
- Chemical Name
- (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
- Synonyms
- SF110005;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-;1-{[(2-Methyl-2-propanyl)oxy]carbonyl}-7-indolinecarboxylic acid;(R)-3,3''-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1''-BINAPH-2,2''-DIYL HYDRPHOS;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate;(R)-3,3'-Bis[3,5-bis(trifluoroMethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 95%;(R)-3,3'-bis[3,5-Bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate;2,6-bis(3,5-bis(trifluoromethyl)phenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
- CBNumber
- CB3972825
- Molecular Formula
- C36H17F12O4P
- Formula Weight
- 772.47
- MOL File
- 791616-62-1.mol
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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Property
- Melting point:
- 162-175 °C
- Boiling point:
- 722.1±70.0 °C(Predicted)
- Density
- 1.63±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- 1.09±0.20(Predicted)
- form
- Powder
- color
- white to light-yellow
- optical activity
- [α]20/D -220°, c = 1 in chloroform (typical)
- InChIKey
- DQORDVSQWPKAQJ-UHFFFAOYSA-N
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 674605
- Product name
- (R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
- Purity
- 95%
- Packaging
- 100mg
- Price
- $189
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1366
- Product name
- (11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
- Packaging
- 100mg
- Price
- $127
- Updated
- 2024/03/01
Biosynth Carbosynth
- Product number
- FB103049
- Product name
- (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
- Packaging
- 25mg
- Price
- $65
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB103049
- Product name
- (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
- Packaging
- 50mg
- Price
- $100
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB103049
- Product name
- (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
- Packaging
- 100mg
- Price
- $170
- Updated
- 2021/12/16
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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Chemical Properties,Usage,Production
Uses
As a chiral Bronsted acid, BINOL- derived cyclic phosphoric acid (such as Akiyama chiral Bronsted acid) was also shown to be an efficient catalyst for the hydrophosphonylation of aldimines at room temperature.
General Description
(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate is a BINOL-based chiral phosphoric acid, which can efficiently catalyze the nucleophilic addition to imine substrates. [BINOL=1,1′-bi-2-naphthol]
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Preparation Products And Raw materials
Raw materials
Preparation Products
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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Suppliers
- Tel
- --
- Fax
- --
- sales@carbosynth.com
- Country
- United Kingdom
- ProdList
- 6005
- Advantage
- 58
- Tel
- --
- Fax
- --
- sales@apolloscientific.co.uk
- Country
- United Kingdom
- ProdList
- 6084
- Advantage
- 88
791616-62-1, (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&Related Search:
S-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
R-4-oxide-4-hydroxy-2,6-bis[4-(trifluoroMethyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
R- 4-oxide-4-hydroxy-2,6-bis([1,1':3',1''-terphenyl]-5'-yl)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%
S-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
S-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
R-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate
R-3,3'-bis(4-nitrophenyl)-1,1'-Binaphthalene]-2,2'-diol
R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
R- 4-oxide--hydroxy-2,6-bis[4-(2-naphthalenyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&
(S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate
(S)-3,3'-DI(ANTHRACEN-9-YL)-1,1'-BINAPHTHYL-2,2'-DIOL
R-3,3'-bis[4-(2-naphthalenyl)phenyl]-1,1'-Binaphthalene]-2,2'-diol
R-3,3'-bis((3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
R-5,5',6,6',7,7',8,8'-octahydro-3,3'-diphenyl-[1,1'-Binaphthalene]-2,2'-diol