ChemicalBook > CAS DataBase List > 2-Nitrodiphenylamine

2-Nitrodiphenylamine

Product Name
2-Nitrodiphenylamine
CAS No.
119-75-5
Chemical Name
2-Nitrodiphenylamine
Synonyms
Nitrodiphenylamine;2-NITRO-N-PHENYLANILINE;NSC 4754;NSC 629274;NSC 105613;c.i. 10335;Sudan Yellow 1339;TIMTEC-BB SBB000544;2-NITRODIPHENYLAMINE;2-Nitrodophenylamine
CBNumber
CB4113940
Molecular Formula
C12H10N2O2
Formula Weight
214.22
MOL File
119-75-5.mol
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2-Nitrodiphenylamine Property

Melting point:
74-76 °C(lit.)
Boiling point:
346 °C
Density 
1.36
vapor density 
10.7 (vs air)
refractive index 
1.6660 (estimate)
Flash point:
346°C
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly), , DMSO (Slightly), Methanol (Slightly, Sonicated)
form 
Solid
pka
-3.39±0.20(Predicted)
color 
Red
Water Solubility 
negligible
BRN 
2213591
InChIKey
RUKISNQKOIKZGT-UHFFFAOYSA-N
CAS DataBase Reference
119-75-5(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, 2-nitro-N-phenyl-(119-75-5)
EPA Substance Registry System
2-Nitrodiphenylamine (119-75-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29214400
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
N504458
Product name
(2-Nitrophenyl)phenylamine
Packaging
5g
Price
$100
Updated
2021/12/16
TRC
Product number
N504458
Product name
(2-Nitrophenyl)phenylamine
Packaging
50g
Price
$275
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0021629
Product name
2-NITRO DIPHENYL AMINE
Purity
95.00%
Packaging
50MG
Price
$693
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0021629
Product name
2-NITRO DIPHENYL AMINE
Purity
95.00%
Packaging
500MG
Price
$1501.5
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
12633
Product name
(2-Nitrophenyl)phenylamine
Packaging
250mg
Price
$1800
Updated
2021/12/16
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2-Nitrodiphenylamine Chemical Properties,Usage,Production

Description

2-Nitrodiphenylamine is a double-base (DB) rocket propellant stabilizer and its microencapsulation potentially improves the shelf life of DB rocket propellants.

Chemical Properties

Red Crystalline Solid

Uses

(2-Nitrophenyl)phenylamine (cas# 119-75-5) is a compound useful in organic synthesis.

Uses

2-Nitrodiphenylamine is used to control the combustion of propylene glycol dinitrate in Otto fuel II (US navy propellant for torpedoes and other weapons systems); Also used as a solvent dye; Used as stabilizer for nitroglycerin and as a chemical intermediate

General Description

Red-brown crystalline powder or reddish-brown solid.

Air & Water Reactions

2-Nitrodiphenylamine may be sensitive to prolonged exposure to air. Insoluble in water.

Reactivity Profile

2-Nitrodiphenylamine is incompatible with strong oxidizers, strong acids and strong bases.

Health Hazard

Symptoms of exposure to this chemical include irritation of the skin, eyes, mucous membranes and upper respiratory tract. Structurally similar chemicals may cause methemoglobinemia.  
ACUTE/CHRONIC HAZARDS: This chemical may be harmful by inhalation or ingestion. When heated to decomposition it emits toxic fumes of carbon monoxide, carbon dioxide and nitrogen oxides

Fire Hazard

Flash point data for 2-Nitrodiphenylamine are not available; however, 2-Nitrodiphenylamine is probably combustible.

Synthesis

The synthesis of 2-Nitrodiphenylamine is as follows:The mixture of phenylboronic acid (1 mmol), aromatic amine (1.2 mmol) and 0.12 g (2 mmol) of KF in DMSO (4 mL) were added to Cu-IS-AMBA-MNPs (0.06 g, 0.025 mmol) at 130 °C under nitrogen atmosphere for 2 h with vigorous stirring. Then, after completion of the reaction, the catalyst was separated by an external magnet and washed with dry CH2Cl2 three times and checked for its reusability. The solvent of the reaction mixture was evaporated by a rotary evaporator and then ethyl acetate and water were added to the residue. The organic layer was dried over anhydrous MgSO4. The solvent was evaporated under reduced pressure and the crude product was purified by column chromatography using ethyl acetate/n-hexane.

2-Nitrodiphenylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Nitrodiphenylamine Suppliers

Shandong RuiYue Biotechnology Co., Ltd.
Tel
0531-88581623 18805314509
Fax
0531-88581623
Email
1456922171@126.com
Country
China
ProdList
65
Advantage
50
Nanjing King-pharm Co.,LTD.
Tel
025-58748998 18951874644
Email
shanhui.zhan@king-pharm.com
Country
China
ProdList
138
Advantage
65
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14103
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
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View Lastest Price from 2-Nitrodiphenylamine manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
2-Nitrodiphenylamine 119-75-5
Price
US $150.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500kg
Release date
2024-12-20
Hebei Weibang Biotechnology Co., Ltd
Product
2-Nitrodiphenylamine 119-75-5
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-12-05
Hebei Chuanghai Biotechnology Co,.LTD
Product
2-Nitrodiphenylamine 119-75-5
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-19

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