ChemicalBook > CAS DataBase List > 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose

2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose

Product Name
2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose
CAS No.
97614-43-2
Chemical Name
2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose
Synonyms
D-Arabinofuranose;1,3,5-TRI-O-BENZOYL-2-DEOXY-2-FLUORO-A-D-ARABINOFURANOSE;2-DEOXY-2-FLUORO-1,3,5-TRI-O-BENZOYL-ALPHA-D-ARABINOFURANOSE;FLuorosugar;2-fluoro-2-deoxy-1;2-Deoxy-2-fluoro-1,3;InterMediate of Clofarabine;2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-α2-deoxy-2-fluoro-tribenzoyl - α - d-alarbulose;2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofur
CBNumber
CB4137232
Molecular Formula
C26H21FO7
Formula Weight
464.44
MOL File
97614-43-2.mol
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2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose Property

Melting point:
74-77°C
Boiling point:
584.1±50.0 °C(Predicted)
Density 
1.35±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Soluble in chloroform or dichloromethane
form 
Powder
color 
White to Off-white
InChIKey
JOAHVPNLVYCSAN-PPTKZWKYSA-N
SMILES
[C@H]1(OC(=O)C2=CC=CC=C2)[C@H](F)[C@@H](OC(=O)C2C=CC=CC=2)O[C@@H]1COC(=O)C1C=CC=CC=1 |&1:0,10,12,23,r|
CAS DataBase Reference
97614-43-2(CAS DataBase Reference)
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Safety

Safety Statements 
24/25
WGK Germany 
3
HS Code 
29329990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D4594
Product name
2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-alpha-D-arabinofuranose
Purity
>98.0%(GC)
Packaging
1g
Price
$36
Updated
2025/07/31
TCI Chemical
Product number
D4594
Product name
2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-alpha-D-arabinofuranose
Purity
>98.0%(GC)
Packaging
5g
Price
$124
Updated
2025/07/31
TRC
Product number
D235500
Product name
2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-α-D-arabinofuranose
Packaging
10g
Price
$60
Updated
2021/12/16
Usbiological
Product number
008101
Product name
2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-α-D-arabinofuranose|
Packaging
250mg
Price
$446
Updated
2021/12/16
TRC
Product number
D235500
Product name
2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-α-D-arabinofuranose
Packaging
25g
Price
$120
Updated
2021/12/16
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2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

It is a pharmaceutical intermediate and is used as an OLED materials.

Uses

Clofarabine intermediate.

Synthesis

97614-42-1

97614-43-2

Synthesis of Compound VIII: Compound VII (2.2 mmol) was dissolved in ethyl acetate (54 mL) and triethylamine (Et3N) was added. Hydrogen trifluoride (3HF, 2.08 mL, 0.013 mmol) was added slowly under stirring. The reaction mixture was heated to 60°C with continuous stirring for 3 hours, followed by warming to 70°C with continued stirring for 1.5 hours. Upon completion of the reaction, the reaction was quenched by the addition of ice brine (10 mL) and extracted with dichloromethane. The organic phases were combined and washed sequentially with brine, water and saturated sodium bicarbonate solution and dried over anhydrous sodium sulfate for 4 hours. The solvent was removed by concentration under reduced pressure to give a dark yellow syrupy crude product. Purification by silica gel column chromatography (5 cm × 5 cm, eluted with dichloromethane) gave a light yellow syrupy product in 86.8% yield. Finally, the crude product was recrystallized in 95% ethanol to give the white crystalline compound VIII in 66.4% yield.1H NMR (CDCl3) δ ppm: 7.31-8.10 (m, 15H, OBz), 6.71 (d, J = 9.0 Hz, 1H, H-1), 5.68 (dd, J = 19.44 Hz, 1H, H-3). 5.32 (d, J = 48.2 Hz, 1H, H-2), 4.65-4.77 (m, 3H, H-4, H-5). Melting point: 80-82°C.

References

[1] Patent: EP2177527, 2010, A1. Location in patent: Page/Page column 11-12
[2] Journal of Labelled Compounds and Radiopharmaceuticals, 1999, vol. 42, # SUPPL. 1, p. S638-S640
[3] Tetrahedron Letters, 1996, vol. 37, # 1, p. 17 - 20

2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose Suppliers

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View Lastest Price from 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose 97614-43-2
Price
US $0.00/G
Min. Order
1G
Purity
98%min
Supply Ability
30kg/month
Release date
2023-02-17
Henan Aochuang Chemical Co.,Ltd.
Product
2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose 97614-43-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-29
Zhuozhou Wenxi import and Export Co., Ltd
Product
Fluorosugar 97614-43-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

97614-43-2, 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranoseRelated Search:

Triethyl phosphonoacetate Benzoyl peroxide Benzoyl chloride Diethylstilbestrol Methyl-2-deoxy-D-erythropentofuranoside dibenzoate Methyl-2-deoxy-alpha-D-ribofuranoside 2-Deoxy-D-ribose 1,3,5-Tri-O-acetyl-2-deoxy-D-erythro-pentofuranose 1,3,5-Tri-O-acetyl-2-deoxy-alpha-D-erythro-pentofuranose Methyl-2-deoxy-D-ribofuranoside diacetate 2-DEOXY-2-FLUORO-1,3,5-TRI-O-BENZOYL-L-RIBOFURANOSE 1,3,5-Tri-O-benzoyl-D-ribofuranose Triphenylformazan D-RIBOFURANOSE, 2-DEOXY-2-FLUORO-1-ACETATE 3,5-DIBENZOATE 2-(Acetoxymethoxy)-1,3-propanediyl Dibenzoate METHYL-2-DEOXY-2-FLUORO-D-ARABINOFURANOSIDE 1-Acetyl-2-deoxy-3,5-di-O-benzoylribofuranose 2-FLUORO-2-DEOXY-1,3,5-TRI-O-ACETYL-A-D-ARABINOFURANOSE DISCONTINUED

  • 1,3,5-TRI-O-BENZOYL-2-DEOXY-2-FLUORO-A-D-ARABINOFURANOSE
  • 2-DEOXY-2-FLUORO-1,3,5-TRI-O-BENZOYL-A-D-ARABINOFURANOSE
  • 2-DEOXY-2-FLUORO-1,3,5-TRI-O-BENZOYL-ALPHA-D-ARABINOFURANOSE
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-arabinofuranose
  • 2-Deoxy-2-Fluoro-1,3,5-Tribenzoate-alpha-D- Arabinofuranose Min98% C3
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-α- D-arabinof
  • InterMediate of Clofarabine
  • 2-Fluoro-2deoxy-1,3,5-O-benzoyl-a-D-arabinofuranos
  • 2-fluoro-2-deoxy-1,3,5-tri-O-benzoyl-*A-D-arabino
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-alpha- D-ribofuranose
  • FLuorosugar
  • Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-alpha-D-arabinofuranose
  • 2-Fluoro-2-deoxy-1,3,5-tri-O-benzoyl-α-D-arabinofuranose
  • 1,3,5-Tri-O-benzoyl-2-deoxy-2-fluoro -α-D-arabinose
  • 2-Deoxy-2-fluoro-1,3
  • 1,3,5-Tri-O-benzoyl-2-deoxy-2-fluoro-α-D-arabinofuranose ,98%
  • 1,3,5-tri-O-benzoyl-2-deoxy-2-fluoro-α-D-arabinofuranose
  • 2-deoxy-2-fluoro-tribenzoate-a-D-Arabinofuranose
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranos
  • 1,3,5-Tri-O-benzoyl-2'-deoxy-2'-fluoro-arabinoside
  • [3,5-BIS(BENZOYLOXY)-4-FLUOROOXOLAN-2-YL]METHYL BENZOATE
  • 2-fluoro-2-deoxy-1
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-&alpha
  • [(2R,3R,4S,5R)-3,5-bis(benzoyloxy)-4-fluorooxolan-2-yl]methyl benzoate
  • α-D-Arabinofuranose, 2-deoxy-2-fluoro-, tribenzoate (9CI)
  • 2-deoxy-2-fluoro-1,3,5-tri-O-benzoyl-1-α-D- arabinofuranose
  • 2-deoxy-2-fluoro-1,3,5-tribenzoate-alpha-d-arabinofuranose
  • a-D-Arabinofuranose,2-deoxy-2-fluoro-, 1,3,5-tribenzoate
  • α-D-Arabinofuranose,2-deoxy-2-fluoro-,1,3,5-tribenzoate
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose (Decitabine)
  • 1,3,5-tri-benzoyl-2-Deoxy-2-fluoro-α-D-arabinofunose
  • 2-deoxy-2-fluoro-1,3,5-tri-o-benzoyl-d-ribofuranose
  • 2-FLUORO-2DEOXY-1,3,5-O-BENZOYL-A-D-ARABINOFURANOSE
  • 2-FLUORO-2-DEOXY-1,3,5-TRIBENZOYL-ALPHA-D-ARABINOFURANOSE
  • 2-FLUORO-2-DEOXY-1,3,5-TRI-O-BENZOYL-ALPHA-D-ARABINOFURANOSE
  • a-D-Arabinofuranose, 2-deoxy-2-fluoro-, tribenzoate
  • alpha-D-Arabinofuranose-2-deoxy-2-fluoro-1,3,5-tribenzoate
  • 2-Deoxy-2-Flouro-1,3,5-Tri-O-Benzoylalpha-D-Araninofuranose
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-Bza-D-ribofuranose
  • D-Arabinofuranose
  • 2-FLUORO-2-DEOXY-1,3,5-TRI-O-BENZOYL-*A-D-ARABINOFUR
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-α-D-arabinofuranose≥ 98% (HPLC)
  • α-D-Arabinofuranose, 2-deoxy-2-fluoro-, tribenzoate
  • 2-deoxy-2-fluoro-tribenzoyl - α - d-alarbulose
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-α-D-arabinofuranose &gt
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-α-D-arabinofuranose
  • 1,3,5-Tri-O-Benzoyl-2-Deoxy-2-Fluoro -α-D-Arabinose
  • 2-deoxy-2-fluoro-1,3,5-tri-o-benzoyl-alpha-D-arabinofuranoseenzoyl-alpha-D-arabinofuranose
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofuranose USP/EP/BP
  • 2-Deoxy-2-fluoro-α-D-arabinofuranose 1,3,5-tribenzoate
  • 2-Deoxy-2-Fluoro-1,3,5-Tribenzoate-α-D-Arabinofuranose
  • [(2R,3R,4S,5R)-3,5-dibenzoyloxy-4-fluorooxolan-2-yl]methyl benzoate
  • 1,3,5-Tri-O-benzoyl-2-deoxy-2-fluoro-alpha-D-arab
  • 2- deoxy -2- fluoro -1,3,5- tribenzoyl -alpha-D- arabinofuranose
  • α-D-Arabinofuranose, 2-deoxy-2-fluoro-, 1,3,5-tribenzoate
  • 2-deoxy-2-fluoro-1,3,5-tribenzoyl-alpha-D-arabofuranose (fluorose)
  • 2-deoxy-2-fluoro-1,3,5-tribenzoyl-alpha D-arabifurose (fluorose)
  • 2-Deoxy-2-fluoro-1,3,5-tri-O-benzoyl-D-ribofur