ChemicalBook > CAS DataBase List > Tributyl borate

Tributyl borate

Product Name
Tributyl borate
CAS No.
688-74-4
Chemical Name
Tributyl borate
Synonyms
TRI-N-BUTYL BORATE;BORIC ACID TRIBUTYL ESTER;AI311060;borester2;AI3 11060;AI3-11060;Borester 2;n-Butoxide;(n-C4H9O)3B;Buty borate
CBNumber
CB4145842
Molecular Formula
C12H27BO3
Formula Weight
230.16
MOL File
688-74-4.mol
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Tributyl borate Property

Melting point:
-70 °C (lit.)
Boiling point:
114-115 °C/12 mmHg (lit.) 230-235 °C (lit.)
Density 
0.853 g/mL at 25 °C (lit.)
vapor density 
7.95 (vs air)
vapor pressure 
3.79hPa at 25℃
refractive index 
n20/D 1.409(lit.)
Flash point:
200 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Methanol,Benzene,Ethanol
form 
Liquid
Specific Gravity
0.853
color 
Clear colorless
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
1703865
Stability:
Stables, but reacts rapidly with moisture, water. Reacts vigorously with oxidizing agents. Incompatible with strong acids.
InChIKey
LGQXXHMEBUOXRP-UHFFFAOYSA-N
LogP
1 at 25℃
CAS DataBase Reference
688-74-4(CAS DataBase Reference)
NIST Chemistry Reference
Boric acid, tributyl ester(688-74-4)
EPA Substance Registry System
Tributyl borate (688-74-4)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38-36/38
Safety Statements 
26-36/37/39-37/39
RIDADR 
3272
WGK Germany 
3
RTECS 
ED4900000
F 
21
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29209090
Hazardous Substances Data
688-74-4(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
90795
Product name
Tributyl borate
Purity
≥99.0% (T)
Packaging
100ml
Price
$103
Updated
2024/03/01
Sigma-Aldrich
Product number
90795
Product name
Tributyl borate
Purity
≥99.0% (T)
Packaging
500ml
Price
$158
Updated
2024/03/01
TCI Chemical
Product number
B0518
Product name
Tributyl Borate
Purity
>99.0%(T)
Packaging
25mL
Price
$19
Updated
2024/03/01
TCI Chemical
Product number
B0518
Product name
Tributyl Borate
Purity
>99.0%(T)
Packaging
100mL
Price
$41
Updated
2024/03/01
Alfa Aesar
Product number
A19322
Product name
Tri-n-butyl borate, 98%
Packaging
100ml
Price
$50.65
Updated
2024/03/01
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Tributyl borate Chemical Properties,Usage,Production

Chemical Properties

Water-white liquid. Distillation range, 85% distills between 135C and 140C (40 mm Hg). Hydrolyzes rapidly; miscible with common organic liquids. Combustible.

Uses

Welding fluxes, intermediate in preparation of borohydrides, flame retardant for textiles (with boric acid).

Uses

Tri-n-butyl Borate is used as a catalyst in the formation of dihydropyrimidinones under solvent-free microwave-assisted conditions.

Air & Water Reactions

Rapidly decomposes in water.

Reactivity Profile

Borates behave similarly to esters in that they react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters/borates with alkali metals and hydrides. Reacts vigorously with oxidizing materials. .

Health Hazard

ACUTE/CHRONIC HAZARDS: Toxic; may emit toxic fumes when heated to decomposition or on contact with acid or acid fumes, local irritant.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. An eye irritant. Flammable when exposed to heat, flame, or oxiduers. To fight fire, use foam, CO2, dry chemical. When heated to decomposition or on contact with acid or acid fumes it can emit toxic fumes; on contact with oxidizing materials it can react vigorously. See also BORANES and BORON COMPOUNDS.

Purification Methods

The chief impurities are n-butyl alcohol and boric acid (from hydrolysis). It must be handled in a dry-box and can readily be purified by fractional distillation, under reduced pressure. [O’Brien Aust J Chem 10 91 1957, Gerrard & Lappert J Chem Soc 2545, 2547 1951, Beilstein 1 IV 1544.]

Tributyl borate Preparation Products And Raw materials

Raw materials

Orthoboric acid 1-Butanol

Preparation Products

4-((N,N-DIMETHYLAMINO)METHYL)PHENYLBORONIC ACID PINACOL ESTER HYDROCHLORIDE QUINOLINE-4-BORONIC ACID BENZOFURAN-5-BORONIC ACID 2-Formylthiophene-3-boronic acid 2-ETHOXYPHENYLBORONIC ACID 2-Aminoethoxydiphenyl borate Curcumin 3-Furanboronic acid Indole-4-boronic acid L-Selenomethionine 6-(2-THIENYL)-2-PYRIDINECARBOXALDEHYDE 5-METHYLFURAN-2-BORONIC ACID
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Tributyl borate Suppliers

Americas 1 Belgium 3 China 292 Europe 2 France 1 Germany 6 Hungary 1 India 27 Japan 5 Russia 2 Singapore 1 Switzerland 2 United Kingdom 13 United States 39 Global 395
Suqian nanxiang chemical manufacturing co. LTD
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View Lastest Price from Tributyl borate manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
Tributyl borate 688-74-4
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-09-06
Hebei Longbang Technology Co., Ltd
Product
Tributyl borate 688-74-4
Price
US $5.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20TONS
Release date
2024-05-27
Hebei Saisier Technology Co., LTD
Product
Tributyl borate 688-74-4
Price
US $6.00/KG
Min. Order
1KG
Purity
More than 99%
Supply Ability
2000KG/Month
Release date
2024-04-23

688-74-4, Tributyl borateRelated Search:

Trimethyl borate Triethyl borate 1-TRIBUTYLSTANNYL-2-TRIMETHYLSILYLACETYLENE TRIBUTYL PHOSPHITE TRIBUTYLSILANE Orthoboric acid Trioctyl borate DL-MENTHYL BORATE Tributyl borate Boric acid BORIC ACID TRI-N-HEXYL ESTER TRICYCLOHEXYL BORATE BORIC ACID TRIOCTADECYL ESTER TRI-N-AMYLBORATE BORIC ACID TRI-N-DECYL ESTER TRIBUTYL BORATE-10B, 98 ATOM % 10B BORIC ACID TRI-N-HEXADECYL ESTER BORIC ACID TRI-N-TETRADECYL ESTER

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