1,8-Bis(dimethylamino)naphthalene
- Product Name
- 1,8-Bis(dimethylamino)naphthalene
- CAS No.
- 20734-58-1
- Chemical Name
- 1,8-Bis(dimethylamino)naphthalene
- Synonyms
- PROTON SPONGE;1,8-BIS(DIMETHYLAMINO)NAPHTHALENE;N1,N1,N8,N8-TETRAMETHYLNAPHTHALENE-1,8-DIAMINE;N,N,N',N'-TETRAMETHYL-1,8-DIAMINONAPHTHALENE;PROTON-SPONGE(R);proton-sponge tm;LABOTEST-BB LT00453982;1, 8-dimethylaminonaphthalene;1,8-bis(dimethylamino)naphtalene;4,5-Bis(dimethylamino)naphthalene
- CBNumber
- CB4163778
- Molecular Formula
- C14H18N2
- Formula Weight
- 214.31
- MOL File
- 20734-58-1.mol
1,8-Bis(dimethylamino)naphthalene Property
- Melting point:
- 49-51 °C(lit.)
- Boiling point:
- 144-145°C (3.7505 mmHg)
- Density
- 1.12
- Flash point:
- >230 °F
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Soluble in organic solvents.
- form
- Crystalline Powder
- pka
- 12.1(at 25℃)
- color
- Pale brownish-pink
- Water Solubility
- insoluble
- Sensitive
- Light Sensitive
- Merck
- 14,3388
- BRN
- 396782
- InChIKey
- GJFNRSDCSTVPCJ-UHFFFAOYSA-N
- CAS DataBase Reference
- 20734-58-1(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,8-Naphthalenediamine, N,N,N',N'-tetramethyl-(20734-58-1)
Safety
- Hazard Codes
- Xn,C
- Risk Statements
- 22-36/37/38-34
- Safety Statements
- 26-45-36/37/39
- RIDADR
- 3259
- WGK Germany
- 3
- F
- 8-10-23
- HazardClass
- 8
- HS Code
- 29215900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 14795
- Product name
- N,N,N′,N′-Tetramethyl-1,8-naphthalenediamine
- Purity
- purum, ≥99.0% (NT)
- Packaging
- 10g
- Price
- $58.4
- Updated
- 2024/03/01
- Product number
- 14795
- Product name
- N,N,N′,N′-Tetramethyl-1,8-naphthalenediamine
- Purity
- purum, ≥99.0% (NT)
- Packaging
- 50g
- Price
- $199
- Updated
- 2024/03/01
- Product number
- B1018
- Product name
- 1,8-Bis(dimethylamino)naphthalene [for Dehydrohalogenation]
- Purity
- >98.0%(GC)(T)
- Packaging
- 1g
- Price
- $42
- Updated
- 2024/03/01
- Product number
- B1018
- Product name
- 1,8-Bis(dimethylamino)naphthalene [for Dehydrohalogenation]
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $78
- Updated
- 2024/03/01
- Product number
- L00313
- Product name
- 1,8-Bis(dimethylamino)naphthalene, 98+%
- Packaging
- 10g
- Price
- $42.5
- Updated
- 2024/03/01
1,8-Bis(dimethylamino)naphthalene Chemical Properties,Usage,Production
Chemical Properties
1,8-Bis(dimethylamino)naphtalene is pale brownish-pink crystalline powder
Uses
1,8-Bis(dimethylamino)naphthalene, also referred to as protone sponge, is a lipophilic proton trapping agent. 1,8-Bis(dimethylamino)naphthalene is used in the matrix for mass spectroscopy analysis of lipids and fatty acids.
Uses
Very strong base in organic synthesis and catalysis.
Uses
Very strong base with weak nucleophilic character due to steric effects.
Definition
ChEBI: N1,N1,N8,N8-tetramethylnaphthalene-1,8-diamine is a member of naphthalenes.
General Description
Proton-sponge is also referred as 1,8-dimethylamino naphthalene. It is very strong base with weak nucleophilic character due to steric effects. It also participates in the reactions between arachno-6,9-C2B8H14 and selected acyl chlorides. It has been tested as an effective H+ scavenger.
Solubility in organics
Soluble in most organic solvents, such as methanol and chloroform.
Purification Methods
It is prepared by methylating 1,8-diaminonaphthalene, and likely impurities are methylated products. The tetramethyl compound is a stronger base than the unmethylated, di and trimethylated derivatives. The pKa values are: 1,8-(NH2)2 = 4.61, 1,8-(NHMe)2 = 5.61, 1-NHMe-8-NHMe2 = 6.43 and 1,8-(NMe2)2 = 12.34. The mixture is then treated with H2O at pH 8 (where all but the required base are protonated) and extracted with Et2O or CHCl3. The dried extract (K2CO3) yields the tetramethyldiamine on evaporation which can be distilled. It is a strong base with weak nucleophilic properties, e.g. it could not be alkylated by refluxing with EtI in MeCN for 4 days; and on treatment with methyl fluorosulfonate only the fluorosulfonate salt of the base is obtained. [NMR: Adler et al. J Chem Soc, Chem Commun 723 1968, Brown & Letang J Am Chem Soc 63 358 1941, Brzezinski et al. J Chem Soc Perkin Trans 2 857 1991.] Alternatively, crystallise proton sponge from EtOH and dry it in a vacuum oven. Store it in the dark in a CO2-free atmosphere. [Benoit et al. Can J Chem 65 996 1987, Beilstein 13 IV 344.]
1,8-Bis(dimethylamino)naphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,8-Bis(dimethylamino)naphthalene manufacturers
- Product
- 1,8-Bis(dimethylamino)naphthalene 20734-58-1
- Price
- US $50.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-22
- Product
- 1,8-Bis(dimethylamino)naphtalene 20734-58-1
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1 ton
- Release date
- 2023-11-16
- Product
- 1,8-Bis(dimethylamino)naphtalene 20734-58-1
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000 tons
- Release date
- 2020-01-06