O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide

Product Name: O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
CAS No.: 200132-54-3
Chemical Name: O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
Synonyms: A16450;O-ALLYL-N-(9-ANTHRACENYLMETHYL)CINCHONIDINIUM BROMIDE;O-Allyl-N-[(9-anthracenyl)methyl]cinchonidium bromide;O-Allyl-1-(anthracen-9-ylmethyl)cinchonidinium bromide;O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide 90%;(-)-O-(9)-Allyl-N-(9-anthracenylmethyl) cinchonidiniumbromide;(-)-O-(9)-ALLYL-N-(9-ANTHRACENYLMETHYL) CINCHONIDINIUM BROMIDE;O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide (PTC catalys);Cinchonanium, 1-(9-anthracenylmethyl)-9-(2-propenyloxy)-, bromide, (8α,9R)-;4-((1R)-((1-(Anthracen-9-yl)but-3-en-2-yl)oxy)((2S)-5-vinylquinuclidin-2-yl)methyl)quinolin-1-ium bromide
CBNumber: CB4174541
Molecular Formula: C37H37BrN2O
Formula Weight: 605.61
MOL File: 200132-54-3.mol

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O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Property

Melting point:: 170 °C (dec.)(lit.)
alpha: -340 º (C=0.45 IN CHLOROFORM)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
optical activity: [α]20/D 345±30°, c = 0.45 in chloroform

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 499617
Product name: O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
Purity: 90%
Packaging: 1g
Price: $75
Updated: 2024/03/01

Sigma-Aldrich

Product number: 499617
Product name: O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
Purity: 90%
Packaging: 5g
Price: $196
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: CCH0037407
Product name: (-)-O-(9)-ALLYL-N-(9-ANTHRACENYLMETHYL) CINCHONIDINIUM BROMIDE
Purity: 95.00%
Packaging: 1G
Price: $232.05
Updated: 2021/12/16

ChemScene

Product number: CS-M3023
Product name: O-Allyl-N-[(9-anthracenyl)methyl]cinchonidiumbromide
Purity: ≥97.0%
Packaging: 1g
Price: $50
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA152006
Product name: (-)-O-(9)-Allyl-N-(9-anthracenylmethyl) cinchonidiniumbromide
Packaging: 500mg
Price: $110
Updated: 2021/12/16

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O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Chemical Properties,Usage,Production

Uses

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide can catalyze the asymmetric alkylation of tert-butyl glycinate-benzophenone Schiff base with different arylmethyl bromides in a micellar medium.

General Description

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide is a cinchona-based chiral phase-transfer catalyst (PTC) that can be used in asymmetric synthesis. It can be prepared from N-(9-anthracenylmethyl)cinchonindinium chloride.

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Suppliers

China 63 India 2 Switzerland 1 United Kingdom 2 United States 9 Global 77

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Sigma-Aldrich

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200132-54-3, O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromideRelated Search:

Diallylamine Allyl hexanoate Tetrapropylammonium bromide Sodium bromate Ethidium bromide Allyl chloride Allyl bromide Allyl glycidyl ether Sodium allylsulfonate Rocuronium bromide Benzyl bromide Methyl bromide Benzyltriethylammonium bromide Benzyl tripropyl ammonium bromide C-ANTHRACEN-9-YL-METHYLAMINE 9-(METHYLAMINOMETHYL)ANTHRACENE (1-BENZYL-2-PIPERIDINYL)METHANOL N-BENZYLCINCHONIDINIUM BROMIDE

O-ALLYL-N-(9-ANTHRACENYLMETHYL)CINCHONIDINIUM BROMIDE

(-)-O-(9)-ALLYL-N-(9-ANTHRACENYLMETHYL) CINCHONIDINIUM BROMIDE

A16450

4-((1R)-((1-(Anthracen-9-yl)but-3-en-2-yl)oxy)((2S)-5-vinylquinuclidin-2-yl)methyl)quinolin-1-ium bromide

O-Allyl-N-[(9-anthracenyl)methyl]cinchonidium bromide

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide 90%

O-Allyl-1-(anthracen-9-ylmethyl)cinchonidinium bromide

(1S,2S,4S,5R)-2-((R)-(allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide

4-[[1-(anthracen-9-ylmethyl)-5-ethenyl-1-azoniabicyclo[2.2.2]octan-2-yl]-prop-2-enoxymethyl]quinoline,bromide

(-)-O-(9)-Allyl-N-(9-anthracenylmethyl) cinchonidiniumbromide

4-[(R)-[(2S,4S,5R)-1-(anthracen-9-ylmethyl)-5-ethenyl-1-azoniabicyclo[2.2.2]octan-2-yl]-prop-2-enoxymethyl]quinoline

Cinchonanium, 1-(9-anthracenylmethyl)-9-(2-propenyloxy)-, bromide, (8α,9R)-

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide (PTC catalys)

200132-54-3

BrC37H37N2O

C37H37N2OBr

Phase Transfer Reaction

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

pharmacetical

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Phase Transfer Reaction