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DICHLOROTITANIUM DIISOPROPOXIDE

Product Name
DICHLOROTITANIUM DIISOPROPOXIDE
CAS No.
762-99-2
Chemical Name
DICHLOROTITANIUM DIISOPROPOXIDE
Synonyms
DICHLORO(DIISOPROPOXY)TITANIUM;DICHLOROTITANIUM DIISOPROPOXIDE;Diisopropoxytitanium(IV) Chloride;DichlorotitaniumDiisopropoxide>dichlorobis(propan-2-olato)titanium;Titanium,dichlorobis(2-propanolato)-, (T-4)-
CBNumber
CB4178327
Molecular Formula
C6H14Cl2O2Ti
Formula Weight
236.95
MOL File
762-99-2.mol
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DICHLOROTITANIUM DIISOPROPOXIDE Property

Melting point:
42-43 °C
storage temp. 
Freezer
solubility 
sol CH2Cl2, toluene, and other solvents.
form 
powder to crystal
color 
White to Light yellow
EPA Substance Registry System
Titanium, dichlorobis(2-propanolato)-, (T-4)- (762-99-2)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
2931.90.9051
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D2257
Product name
Dichlorotitanium Diisopropoxide
Purity
>95.0%(T)
Packaging
5g
Price
$112
Updated
2025/07/31
TCI Chemical
Product number
D2257
Product name
Dichlorotitanium Diisopropoxide
Purity
>95.0%(T)
Packaging
25g
Price
$341
Updated
2025/07/31
Usbiological
Product number
274625
Product name
Dichlorotitanium Diisopropoxide
Packaging
5g
Price
$342
Updated
2021/12/16
Chem-Impex
Product number
41278
Product name
Dichlorotitaniumdiisopropoxide,95%(Assaybytitration)
Purity
95%(Assaybytitration)
Packaging
25G
Price
$377.44
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD60920
Product name
Dichlorotitanium Diisopropoxide
Packaging
50g
Price
$391
Updated
2021/12/16
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DICHLOROTITANIUM DIISOPROPOXIDE Chemical Properties,Usage,Production

Uses

Dichlorotitanium diisopropoxide is a Lewis acid frequently used in the preparation of chiral titanium complexes; an efficient catalyst for Diels-Alder reactions, [2 + 2] cycloadditions, and carbonyl-ene reactions, including asymmetric versions of these processes; a reagent for titanium enolate formation; and a catalyst component for the stereoselective addition of cyanide and allyltin nucleophiles to aldehydes.

Preparation

Dichlorotitanium diisopropoxide is prepared by adding slowly at rt an equimolar amount of Titanium(IV) Chloride to a  hexane solution of Titanium Tetraisopropoxide; following mixing, during which heat is evolved, the  mixture is allowed to stand at rt for 6 h and the precipitate is collected and washed with hexane;  dibromotitanium diisopropoxide is prepared similarly.

storage

Corrosive; moisture sensitive; use in a fume hood; can be stored under  nitrogen in pure form or in solution.

DICHLOROTITANIUM DIISOPROPOXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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DICHLOROTITANIUM DIISOPROPOXIDE Suppliers

Americas 1 China 40 Europe 1 Germany 2 India 3 Japan 1 United Kingdom 2 United States 4 Global 54
Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
VWR International
Tel
--
Fax
--
Email
solutions@vwr.com
Country
United Kingdom
ProdList
6548
Advantage
82

762-99-2, DICHLOROTITANIUM DIISOPROPOXIDERelated Search:

(ethyl acetoacetato-O1',O3)(pentane-2,4-dionato-O,O')[propane-1,3-diolato(2-)-O,O']titanium [oxalato(2-)-O,O']bis(propan-2-olato)titanium butoxytris(methylphenolato)titanium dibutoxy[2-methylpentane-2,4-diolato(2-)-O,O']titanium Chromic sulfate Titanium carbide (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT TITANIUM DICHLORIDE DIETHOXIDE TITANIUM(II) CHLORIDE (4R,5R)-(-)-2,2-DIMETHYL-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOLATO[1,2-BIS(DIMETHOXY)ETHANE]TITANIUM(IV) DIC DICHLOROTITANIUM DIISOPROPOXIDE

  • DICHLORO(DIISOPROPOXY)TITANIUM
  • DICHLOROTITANIUM DIISOPROPOXIDE
  • dichlorobis(propan-2-olato)titanium
  • DichlorotitaniumDiisopropoxide&gt
  • Titanium,dichlorobis(2-propanolato)-, (T-4)-
  • Diisopropoxytitanium(IV) Chloride
  • 762-99-2
  • C6H14Cl2O2Ti
  • Transition Metal Compounds
  • Ti (Titanium) Compounds
  • Homogeneous Catalysts
  • Classes of Metal Compounds
  • Titanium Alkoxides, etc. (Homogeneous Catalysts)
  • Catalysts for Organic Synthesis
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Synthetic Organic Chemistry
  • Ti (Titanium) Compounds
  • Titanium Alkoxides, etc. (Homogeneous Catalysts)
  • Transition Metal Compounds