3-bromo-9-phenyl-9H-carbazole

Product Name: 3-bromo-9-phenyl-9H-carbazole
CAS No.: 1153-85-1
Chemical Name: 3-bromo-9-phenyl-9H-carbazole
Synonyms: 3-bromo-9-phenyl-9H-carbazole;3-Bromo-N-phenylcarbazole;PCZ-Br;3-Bromo-N-phenyL;3-BroMo-N-phenylcarbazol;3-Bromo-9-phenylcarbazole;N-Phenyl-3-broMocarbazole;3-Bromo-12-phenylcarbazole;3-Bromo-11-phenylcarbazole;3-Bromo-10-phenylcarbazole
CBNumber: CB41871508
Molecular Formula: C18H12BrN
Formula Weight: 322.2
MOL File: 1153-85-1.mol

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3-bromo-9-phenyl-9H-carbazole Property

Melting point:: 98 ºC
Boiling point:: 461.7±27.0 °C(Predicted)
Density: 1.39
storage temp.: Sealed in dry,Room Temperature
form: Solid
color: White to Almost white
Water Solubility: Slightly soluble in water.
λmax: 352nm(CH3CN)(lit.)
InChI: InChI=1S/C18H12BrN/c19-13-10-11-18-16(12-13)15-8-4-5-9-17(15)20(18)14-6-2-1-3-7-14/h1-12H
InChIKey: KUBSCXXKQGDPPD-UHFFFAOYSA-N
SMILES: N1(C2=CC=CC=C2)C2=C(C=CC=C2)C2=C1C=CC(Br)=C2
CAS DataBase Reference: 1153-85-1(CAS DataBase Reference)

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Safety

HS Code: 2933998090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: B3908
Product name: 3-Bromo-9-phenylcarbazole
Purity: >98.0%(GC)
Packaging: 1g
Price: $20
Updated: 2025/07/31

TCI Chemical

Product number: B3908
Product name: 3-Bromo-9-phenylcarbazole
Purity: >98.0%(GC)
Packaging: 5g
Price: $37
Updated: 2025/07/31

TRC

Product number: B699885
Product name: 3-Bromo-9-phenylcarbazole
Packaging: 2.5g
Price: $75
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB33599
Product name: 3-Bromo-9-phenylcarbazole
Packaging: 10g
Price: $95
Updated: 2021/12/16

Apolloscientific

Product number: OR41026
Product name: 3-Bromo-9-phenyl-9H-carbazole
Packaging: 25g
Price: $142
Updated: 2021/12/16

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3-bromo-9-phenyl-9H-carbazole Chemical Properties,Usage,Production

Description

3-Bromo-9-phenylcarbazole is a chemical compound used as an intermediate in synthesizing organic compounds. It has applications in material science, such as in developing organic semiconductors and optoelectronic devices. It is used in the manufacturing of OLED materials. Also used as an intermediate for pharmaceuticals. This product should be handled with care due to its potential health hazards, including eye and skin irritation. Proper safety equipment, such as gloves and goggles, should be worn when handling this compound. Storage guidelines include keeping it in a cool, dry place away from sources of heat or ignition.

Chemical Properties

off-white powder

Uses

3-bromo-9-phenyl-9H-carbazole is a heterocyclic compound with a bromine functional group that can be used as an organic synthesis intermediate and optoelectronic material. Using 9-phenylcarbazole as the core, it can be used to synthesize starburst carbazoles and their derivatives via a Suzuki cross-coupling reaction. Fluorescence spectroscopy reveals that these compounds exhibit excellent blue fluorescence with a maximum wavelength between 410 and 430 nm.

Synthesis

1592-95-6

591-50-4

1153-85-1

The general procedure for the synthesis of 3-bromo-N-phenylcarbazole using 3-bromocarbazole and iodobenzene as starting materials was as follows: in a dry reaction flask, 3-bromo-9H-carbazole, iodobenzene, 0.03 equiv. of tris(dibenzylideneacetone)di-palladium(0) (Pd2(dba)3), 0.06 equiv. of tributylphosphine, and toluene (0.1 M) were added in sequence. The reaction mixture was stirred at room temperature for about 12 hours. Upon completion of the reaction, the mixture was cooled to ambient temperature, extracted with dichloromethane and the organic phase was washed with distilled water. The organic phase was collected and dried over anhydrous magnesium sulfate (MgSO4) and subsequently concentrated under reduced pressure. The residue was purified by column chromatography to afford the target product 3-bromo-9-phenyl-9H-carbazole in 87.22% yield. The exact mass of the compound was measured as 321 by high resolution mass spectrometry (HRMS) analysis and the molecular formula was confirmed as C18H12BrN.

References

[1] Patent: US2017/162796, 2017, A1. Location in patent: Paragraph 0126; 0127
[2] Patent: KR2015/58973, 2015, A. Location in patent: Paragraph 0106; 0107; 0108
[3] Patent: KR2016/51654, 2016, A. Location in patent: Paragraph 0244-0246
[4] Patent: KR2015/102733, 2015, A. Location in patent: Paragraph 0151-0155
[5] Patent: KR2015/112880, 2015, A. Location in patent: Paragraph 0119; 0120; 0121; 0122; 0123

3-bromo-9-phenyl-9H-carbazole Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-bromo-9-phenyl-9H-carbazole manufacturers

Qingdao RENAS Polymer Material Co., Ltd.

Product: 3-Bromo-N-phenylcarbazole 1153-85-1
Price: US $0.00/kg
Min. Order: 20kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2024-10-29

Henan Aochuang Chemical Co.,Ltd.

Product: 3-Bromo-9-phenylcarbazole 1153-85-1
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-29

airuikechemical co., ltd.

Product: 3-bromo-9-phenylcarbazole 1153-85-1
Price: US $0.00-0.00/Kg
Min. Order: 1Kg
Purity: 99.9%
Supply Ability: 200tons
Release date: 2024-04-08

1153-85-1, 3-bromo-9-phenyl-9H-carbazoleRelated Search:

N-Ethylcarbazole N-PHENYLCARBAZOLE HYDROCHLORIDE 9-Phenyl-9H-carbazol-3-ylboronic acid N-(2-BroMophenyl)-9H-carbazole 9-(3-bromophenyl)carbazole 2-Bromo-9-phenyl-9H-carbazole 3-broMo-9-(naphthalen-1-yl)-9H-carbazole (9-(4-BROMOPHENYL))-9H-CARBAZOLE 3-Iodo-N-phenylcarbazole 3,6-Dibromo-9-phenyl-9H-carbazole ANTHRACENE, 9-BROMO-10-(1-NAPHTHALENYL)- 2-Bromo-9,9-dimethylfluorene 3-(4-bromophenyl)-N-phenylcarbazole

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3-bromo-9-phenyl-9H-carbazole

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3-Bromo-N-phenyL

3-Bromo-9-phenylcarbazole,98%

3-Bromo-9-phenylcarbazole ISO 9001：2015 REACH

PCZ-Br

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1153-85-1

carbazol

OLED materials,pharm chemical,electronic

organic chemicals and derivatives/others

OLED