METHYLMAGNESIUM IODIDE

Product Name: METHYLMAGNESIUM IODIDE
CAS No.: 917-64-6
Chemical Name: METHYLMAGNESIUM IODIDE
Synonyms: CHLOROMETHYLMAGNESIUM;Methylmagnesium iodide solution;nesium iodide;iodomethylmagnesium;iodomethyl-magnesiu;Methyliodomagnesium;METHYLMAGNESIUM IODIDE;Methylmagnesium iodine;MagnesiuM, iodoMethyl-;3.0 M in diethyl ether
CBNumber: CB4248837
Molecular Formula: CH3IMg
Formula Weight: 166.24
MOL File: 917-64-6.mol

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METHYLMAGNESIUM IODIDE Property

Density: 1.26 g/mL at 20 °C
Flash point:: -40 °C
BRN: 1209226
InChIKey: AUPXBVDHVRZMIB-UHFFFAOYSA-M
EPA Substance Registry System: Magnesium, iodomethyl- (917-64-6)

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Safety

Hazard Codes: F+,C,F
Risk Statements: 12-14/15-22-34-66-67-19-11
Safety Statements: 16-26-36/37/39-43-45-7/8
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 1
F: 1-3-10
HazardClass: 4.2
PackingGroup: I
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H314Causes severe skin burns and eye damage

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 254363
Product name: Methylmagnesium iodide solution
Purity: 3.0M in diethyl ether
Packaging: 100ml
Price: $89.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 254363
Product name: Methylmagnesium iodide solution
Purity: 3.0M in diethyl ether
Packaging: 800ml
Price: $349.6
Updated: 2024/03/01

TCI Chemical

Product number: M0364
Product name: Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L)
Packaging: 100G
Price: $62
Updated: 2024/03/01

Sigma-Aldrich

Product number: 257109
Product name: Methylmagnesium iodide solution
Purity: 3.0M in diethyl ether
Packaging: 200ml
Price: $227
Updated: 2021/12/16

TRC

Product number: M316653
Product name: MethylmagnesiumIodide(3.0MinDiethylether)
Packaging: 10ml
Price: $45
Updated: 2021/12/16

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METHYLMAGNESIUM IODIDE Chemical Properties,Usage,Production

Chemical Properties

Dark grey liquid

Uses

Alkylating agent in organic synthesis, Grignardreagent.

Uses

Methylmagnesium iodide solution can be used:

To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

Definition

Available as solution inether.

Hazard

Flammable, dangerous fire and explosionrisk.

METHYLMAGNESIUM IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYLMAGNESIUM IODIDE Suppliers

Americas 1 Belgium 2 China 114 Europe 3 Germany 5 India 24 Italy 1 Japan 4 Switzerland 1 United Kingdom 4 United States 10 Global 169

Aceschem Inc.

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View Lastest Price from METHYLMAGNESIUM IODIDE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: METHYLMAGNESIUM IODIDE 917-64-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000KG
Release date: 2024-08-25

Career Henan Chemical Co

Product: METHYLMAGNESIUM IODIDE 917-64-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-11

917-64-6, METHYLMAGNESIUM IODIDERelated Search:

PHENYLMAGNESIUM IODIDE ethylmagnesium iodide ISOPROPYLMAGNESIUM BROMIDE Vinylmagnesium chloride TERT-BUTYLMAGNESIUM CHLORIDE Methylmagnesium Bromide ISOBUTYLMAGNESIUM CHLORIDE ISOBUTYLMAGNESIUM BROMIDE N-BUTYLMAGNESIUM BROMIDE Butylmagnesium chloride PHENYLMAGNESIUM BROMIDE ALLYLMAGNESIUM BROMIDE Deuterated methyl magnesium iodide Magnesium METHYLMAGNESIUM IODIDE trideutero-methylmagnesium iodide 3-THIENYLMAGNESIUM IODIDE 3-CHLORO-4-METHYLPHENYLMAGNESIUM IODIDE

METHYLMAGNESIUM IODIDE

MAGNESIUM METHYL IODIDE

iodomethyl-magnesiu

methylmagnesiumiodidesol.

Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L)

Methylmagnesium iodide solution

iodomethylmagnesium

METHYLMAGNESIUM IODIDE SOL., ~3 M IN DIE THYL ETHER

METHYLMAGNESIUM IODIDE, 3.0M SOLUTION IN DIETHYL ETHER

nesium iodide

Methylmagnesium bromide [solution in THF]

Methylmagnesium iodide, 2-3M in diethyl ether

Methylmagnesium iodide solution 3.0 M in diethyl ether

Methylmagnesium iodide, 3M solution in diethyl ether, AcroSeal

Methyliodomagnesium

Methylmagnesium iodide,3M solution in diethylether

magnesium carbanide iodide

CHLOROMETHYLMAGNESIUM

Methylmagnesium iodine

Methylmagnesium iodide 3M solution in DEE

MethylMagnesiuM iodide, 3.0M solution in diethyl ether, J&KSeal

MagnesiuM, iodoMethyl-

MethylMagnesiuM iodide, 3.0 M in diethyl ether, SpcSeal

Methyl magnesium iodide 3M ether solution

methylmagnesium iodide 2M in THF

Methylmagnesium Iodide, Diethyl Ether Solution (abt. 1mol/l)

Methylmagnesium Iodide (3.0 M in Diethyl ether)

3.0 M in diethyl ether

Methylmagnesium iodide (6CI)

Methylmagnesium iodide, 3M in diethyl ether

Methyl magnesium iodide 1M in THF

METHYL MAGNESIUM IODIDE IN ETHER

Methyl Magnesium Iodide 3 Molar Solution in Diethyl Ether

Methylmagnesium iodide, 3M in diethyl

Methyl Magnesium Iodide (2.0 M in Diethyl Ether)

917-64-6

CH3IMg

CH3MgI

Alkyl

Organometallic Reagents

Mg (Magnesium) Compounds

Grignard Reagents & Alkyl Metals

Typical Metal Compounds

Grignard Reagents

Classes of Metal Compounds

Grignard Reagent

Alkyl

Chemical Synthesis

Organic Bases

Organometallic Reagents

Synthetic Reagents

AlkylChemical Synthesis

Grignard Reagents

Organic Bases

Organometallic Reagents

Synthetic Reagents

Classes of Metal Compounds

Grignard Reagents