Antitumour Activity Pharmacokinetics
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Cabazitaxel

Antitumour Activity Pharmacokinetics
Product Name
Cabazitaxel
CAS No.
183133-96-2
Chemical Name
Cabazitaxel
Synonyms
Jevtana;Cabazitaxel Injection;CS-877;TXD-258;XRP 6258;Takabasai;Kabatasai;Cabazitaxe;Cabazitaxel;RPR-116258A
CBNumber
CB42517227
Molecular Formula
C45H57NO14
Formula Weight
835.93
MOL File
183133-96-2.mol
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Cabazitaxel Property

Melting point:
180 °C
Boiling point:
870.7±65.0 °C(Predicted)
Density 
1.31
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form 
White solid.
pka
11.20±0.46(Predicted)
color 
White to Off-White
InChIKey
BMQGVNUXMIRLCK-JACFBOAKNA-N
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Safety

Safety Statements 
24/25
HS Code 
29329990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H341Suspected of causing genetic defects

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
SML2487
Product name
Cabazitaxel
Purity
≥95% (HPLC)
Packaging
5MG
Price
$88.8
Updated
2024/03/01
Sigma-Aldrich
Product number
SML2487
Product name
Cabazitaxel
Purity
≥95% (HPLC)
Packaging
25MG
Price
$359
Updated
2024/03/01
TCI Chemical
Product number
C3390
Product name
Cabazitaxel
Packaging
25MG
Price
$104
Updated
2024/03/01
TCI Chemical
Product number
C3390
Product name
Cabazitaxel
Packaging
100MG
Price
$307
Updated
2024/03/01
Cayman Chemical
Product number
22262
Product name
Cabazitaxel
Purity
≥98%
Packaging
5mg
Price
$44
Updated
2024/03/01
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Cabazitaxel Chemical Properties,Usage,Production

Antitumour Activity

Cabazitaxel is a semisynthetic taxane derivative that acts as a microtubule inhibitor. It binds to tubulin, promoting the assembly of tubulin into microtubules and inhibiting their disassembly, which results in microtubule stabilization, the inhibition of cell division, cell cycle arrest and the arrest of tumour proliferation. Cabazitaxel demonstrated antitumour activity against advanced human tumours xenografted in mice. As well as being active in docetaxel-sensitive tumours, cabazitaxel showed activity in tumour models insensitive to chemotherapy, including docetaxel. Cabazitaxel also penetrates the blood-brain barrier to a greater extent than docetaxel.

Pharmacokinetics

The pharmacokinetic data for cabazitaxel demonstrated dose proportionality, with a high plasma clearance and a long terminal half-life. The very large volume of distribution at steady state suggests extensive penetration into tissues. Of interest, cabazitaxel is able to cross the blood-brain barrier in preclinical models. Cabazitaxel is mainly metabolized by the cytochrome P450 (CYP) enzyme 3A4/5 and to a lesser extent by CYP2C8, suggesting that it has the potential to inhibit CYP3A enzymes.

Description

In June 2010, the U.S. FDA approved cabazitaxel (also referred to as XRP6258 and RPR 116258A) in combination with the steroid prednisone for the treatment of metastatic Castration-Resistant Prostate Cancer (mCRPC) for patients who were previously treated with a docetaxelcontaining regimen for late-stage disease.
Cabazitaxel is a semisynthetic analog of the natural product taxol, which is isolated from the bark of the yew tree. Cabazitaxel is a microtubule inhibitor that binds to the taxol-binding site of tubulin. Similar to other tubulin inhibitors of the taxol class, cabazitaxel inhibits microtubule disassembly resulting in mitotic blockade and cell death. Docetaxel, also a semisynthetic taxol analog, was approved by the FDA for the treatment of mCRPC in 2004. However, docetaxel is a substrate for P-gp, which is thought to contribute to the constitutive and acquired resistance of cancer cells to taxanes. Cabazitaxel has poor affinity for P-gp and showed antitumor activity in preclinical in vitro studies and in vivo tumor models that overexpress this protein. Cabazitaxel is synthesized on a commercial scale from 10-deacetylbaccatin .

Chemical Properties

White solid

Originator

Sanofi-Aventis (France)

Uses

Cabazitaxel (Jevtana, XRP6258) is a semi-synthetic derivative of a natural taxoid.

Uses

A novel semi-synthetic taxane with antitumor activity used for the treatment of castration-resistant prostate cancer. A microtubule inhibitor.

Definition

ChEBI: A tetracyclic diterpenoid that is 10-deacetylbaccatin III having O-methyl groups attached at positions 7 and 10 as well as an O-(2R,3S)-3-[(tert-butoxycarbonyl)amino]-2-hy roxy-3-phenylpropanoyl group attached at position 13. Acts as a microtubule inhibitor, binds tubulin and promotes microtubule assembly and simultaneously inhibits disassembly.

brand name

Jevtana

Clinical Use

Cabazitaxel was developed by Sanofi-Aventis as an intravenous injectable drug for the treatment of hormone-refractory metastatic prostate cancer. As a microtubule inhibitor, cabazitaxel differs from docetaxel because it exhibits a much weaker affinity for P-glycoprotein (P-gp), an adenosine triphosphate (ATP)-dependent drug efflux pump. Cancer cells that express P-gp become resistant to taxanes, and the effectiveness of docetaxel can be limited by its high substrate affinity for P-gp. Clinical studies confirmed that cabazitaxel retains activity in docetaxel-resistant tumors. Common adverse events with cabazitaxel include diarrhea and neutropenia. Cabazitaxel in combination with prednisone is an important new treatment option for men with docetaxel-refractory metastatic CRPC (castration-resistant prostate cancer).

Synthesis

The semi-synthesis of cabazitaxel started from 10- deacetylbaccatin III (15) which can be prepared from 7-xylosyl-10-deacetylbaccatin natural product mixture according to a literature process procedure (the Scheme). 10-Deacetylbaccatin III was protected with triethylsilyl chloride (TESCl) in pyridine to afford the corresponding 7,13-bis-silyl ether in 51% yield, which was methylated with MeI and NaH in DMF to give 10-methoxy-7,13-bis silyl ether 16 in 76% yield. After de-silylation of 16 with triethylamine trihydrofluoride complex at room temperature, triol 17 was obtained in 77% yield. Selective methylation of 17 with MeI and NaH in DMF at 0 oC provided 7,10-dimethyl ether 18 in 74% yield. Compound 18 was condensed with commercially available oxazolidinecarboxylic acid 19 in the presence of dicyclohexylcarbodiimide/dimethylaminopyridine (DCC/DMAP) in ethyl acetate at room temperature to generate ester 20 in 76% yield. The oxazolidine moiety of compound 20 was selectively hydrolyzed under mild acidic conditions to yield the hydroxy Boc-amino ester derivative cabazitaxel (III) in 32% yield.

Drug interactions

Potentially hazardous interactions with other drugs
Antibacterials: Avoid with clarithromycin, rifabutin, rifampicin and telithromycin.
Antidepressants: Avoid with St John's wort.
Antiepileptics: Avoid with carbamazepine, fosphenytoin, phenobarbital, phenytoin and primidone.
Antifungals: Avoid with itraconazole, ketoconazole and voriconazole.
Antipsychotics: Avoid with clozapine (increased risk of agranulocytosis).
Antivirals: Avoid with atazanavir, indinavir, ritonavir and saquinavir.

Metabolism

Extensively metabolised in the liver (>95%), mainly by the CYP3A4 isoenzyme (80-90%). Cabazitaxel is the main circulating compound in human plasma. Seven metabolites were detected in plasma (including 3 active metabolites issued form O-demethylations), with the main one accounting for 5% of parent exposure. Excreted as metabolites into the urine (4%) and faeces (76%).

Cabazitaxel Preparation Products And Raw materials

Raw materials

Preparation Products

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Cabazitaxel Suppliers

Chembest Research Laboratories Limited
Tel
+86-21-20908456
Fax
021-58180499
Email
sales@BioChemBest.com
Country
China
ProdList
6005
Advantage
61
Beijing Zhongshuo Pharmaceutical Technology Development Co., Ltd
Tel
010-53679529 13801208576
Fax
010-64215766
Email
sales.2@chinazhongshuo.com
Country
China
ProdList
99
Advantage
65
Shanghai Bioman Pharma Limited
Tel
21-33738120 15000110506
Fax
021-23025272
Email
info@bioman.com.cn
Country
China
ProdList
61
Advantage
62
Nanjing Digger Medical Technology Co. Ltd.
Tel
025-025-51191215 18013836722
Fax
025-51191215
Email
2399235533@qq.com
Country
China
ProdList
4933
Advantage
58
Hubei Chanmol Biotech Co., Ltd.
Tel
0711-3812399 18062309155
Email
156941107@qq.com
Country
China
ProdList
3003
Advantage
58
Hubei Chenxin Pharmaceutical Co., Ltd.
Tel
17362916295 17362916295
Fax
QQ:840947394
Email
w17362916295@163.com
Country
China
ProdList
3022
Advantage
58
SHANDONG OCTAGON CHEMICALS LIMITED
Tel
0535-15589503653 15589503653
Email
2959135512@qq.com
Country
China
ProdList
235
Advantage
58
SICHUAN XIELI PHARMACEUTICAL CO.,LTD.
Tel
028-83188610
Email
info@xielipharm.com
Country
China
ProdList
29
Advantage
58
Shanghai Boyle Chemical Co., Ltd.
Tel
Fax
86-21-57758967
Email
sales@boylechem.com
Country
China
ProdList
2922
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
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View Lastest Price from Cabazitaxel manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Cabazitaxel 183133-96-2
Price
US $0.00/g
Min. Order
1g
Purity
99.5%min HPLC
Supply Ability
1000KGS
Release date
2021-07-27
BEIJING SJAR TECHNOLOGY DEVELOPMENT CO., LTD.
Product
Cabazitaxel 183133-96-2
Price
US $0.00/g
Min. Order
1g
Purity
More Than 99%
Supply Ability
100kg/Month
Release date
2024-09-05
Hebei Chuanghai Biotechnology Co,.LTD
Product
Cabazitaxel 183133-96-2
Price
US $10.70/kg
Min. Order
10kg
Purity
99%
Supply Ability
10000kg
Release date
2024-08-20

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