1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE
- Product Name
- 1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE
- CAS No.
- 21969-32-4
- Chemical Name
- 1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE
- Synonyms
- magnesium,but-1-ene,chloride;chlorure de buten-2 ylmagnesium;1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE;1-Methyl-2-propenylmagnesium chloride solution;1-Methyl-2-propenylmagnesium chloride, 0.25 M in THF;1-Methyl-2-propenylmagnesium chloride, 0.25 M in 2-MeTHF;1-Methyl-2-propenylmagnesium chloride solution 0.5 in THF;1-Methyl-2-propenylmagnesium chloride 0.5M solution in THF;1-Methyl-2-propenylmagnesium chloride solution 0.5 M in THF;1-Methyl-2-propenylmagnesium chloride solution 0.5M solution in THF
- CBNumber
- CB4255349
- Molecular Formula
- C4H7ClMg
- Formula Weight
- 114.86
- MOL File
- 21969-32-4.mol
1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE Property
- Boiling point:
- 67 °C
- Density
- 0.917 g/mL at 25 °C
- Flash point:
- −4 °F
Safety
- Hazard Codes
- F,C,Xn
- Risk Statements
- 11-14-19-20/21/22-34-40-36/37/38-14/15
- Safety Statements
- 16-26-27-36/37/39-45-43-36/37
- RIDADR
- UN 3399 4.3/PG 2
- WGK Germany
- 3
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H261In contact with water releases flammable gas
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232Handle under inert gas. Protect from moisture.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378In case of fire: Use … for extinction.
P402+P404Store in a dry place. Store in a closed container.
P403+P235Store in a well-ventilated place. Keep cool.
N-Bromosuccinimide Price
- Product number
- 420042
- Product name
- 1-Methyl-2-propenylmagnesium chloride solution
- Purity
- 0.5 M in THF
- Packaging
- 100ml
- Price
- $361
- Updated
- 2024/03/01
- Product number
- 121862
- Product name
- 1-Methyl-2-propenylmagnesiumchloride
- Purity
- 0.25Min2-MeTHF97%
- Packaging
- 500ml
- Price
- $737
- Updated
- 2021/12/16
- Product number
- 121864
- Product name
- 1-Methyl-2-propenylmagnesiumchloride
- Purity
- 0.25MinTHF97%
- Packaging
- 500ml
- Price
- $737
- Updated
- 2021/12/16
- Product number
- T0381
- Product name
- 1-Methyl-2-propenylmagnesiumchloride
- Packaging
- 50mL
- Price
- $153
- Updated
- 2021/12/16
- Product number
- 121864
- Product name
- 1-Methyl-2-propenylmagnesiumchloride
- Purity
- 0.25MinTHF97%
- Packaging
- 50ml
- Price
- $232
- Updated
- 2021/12/16
1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE Chemical Properties,Usage,Production
Chemical Properties
Brown liquid
Uses
1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes. It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.