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DIETHYL TERT-BUTYLMALONATE

Product Name
DIETHYL TERT-BUTYLMALONATE
CAS No.
759-24-0
Chemical Name
DIETHYL TERT-BUTYLMALONATE
Synonyms
AURORA KA-6574;Diethyl t-butylmalonate;DIETHYL TERT-BUTYLMALONATE;Diethyl 2-tert-butylmalonate;Diethyl tert-butylmalonate 96%;diethyl 2-tert-butylpropanedioate;diethyl (1,1-dimethylethyl)malonate;2-tert-Butylmalonic acid diethyl ester;N-(4-butylphenyl)-3-pyridinecarboxamide;1,1-dimethylethylpropandioc acid diethyl ester
CBNumber
CB4264123
Molecular Formula
C11H20O4
Formula Weight
216.27
MOL File
759-24-0.mol
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DIETHYL TERT-BUTYLMALONATE Property

Boiling point:
102-104 °C/11 mmHg (lit.)
Density 
1.014 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.425(lit.)
Flash point:
195 °F
pka
13.74±0.46(Predicted)
Water Solubility 
Immiscible with water.
BRN 
1781709
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Safety

Safety Statements 
23-24/25
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
278041
Product name
Diethyl tert-butylmalonate
Purity
96%
Packaging
5g
Price
$132.6
Updated
2024/03/01
Alfa Aesar
Product number
L09131
Product name
Diethyl tert-butylmalonate, 97%
Packaging
5g
Price
$126
Updated
2024/03/01
Alfa Aesar
Product number
L09131
Product name
Diethyl tert-butylmalonate, 97%
Packaging
1g
Price
$33.4
Updated
2021/12/16
Alfa Aesar
Product number
L09131
Product name
Diethyl tert-butylmalonate, 97%
Packaging
25g
Price
$431.65
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0079562
Product name
DIETHYL TERT-BUTYLMALONATE
Purity
95.00%
Packaging
5G
Price
$909.08
Updated
2021/12/16
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DIETHYL TERT-BUTYLMALONATE Chemical Properties,Usage,Production

Uses

Diethyl tert-butylmalonate is used in the preparation of enantiomers of 4-tert-butyl-3-isopropyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane 1-sulfide.

Purification Methods

Dissolve it in Et2O, wash with aqueous NaHCO3, H2O, dry (MgSO4), filter, evaporate and distil the residue. Identify by hydrolysis to the acid and determine the neutralisation equivalent (theor: 80.0). The acid has m 155-157o effervescence [Hauser et al. J Am Chem Soc 64 2715 1942, Bush & Beauchamp J Am Chem Soc 75 2949 1953]. [Beilstein 2 IV 2027.]

DIETHYL TERT-BUTYLMALONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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DIETHYL TERT-BUTYLMALONATE Suppliers

Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Hangzhou Yuhao Chemical Technology Co., Ltd
Tel
0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
9387
Advantage
52
Candia Thamtech Company Limited
Tel
0371-86615086 18203638366 0371-86159066 13526786601
Fax
0371-86159066
Country
China
ProdList
2015
Advantage
60
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Guangzhou Jhd Chemical Reagent Co., Ltd.
Tel
020-84383047
Fax
020-84380294
Email
sales@jhd.com.cn
Country
China
ProdList
9186
Advantage
65
Aikon International Limited
Tel
025-58859352 18068836627
Fax
02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
15084
Advantage
58

759-24-0, DIETHYL TERT-BUTYLMALONATERelated Search:


  • AURORA KA-6574
  • DIETHYL TERT-BUTYLMALONATE
  • Diethyl 2-tert-butylmalonate
  • Diethyl t-butylmalonate
  • Propanedioic acid, (1,1-dimethylethyl)-, diethyl ester
  • diethyl (1,1-dimethylethyl)malonate
  • 1,1-dimethylethylpropandioc acid diethyl ester
  • (1,1-Dimethylethyl)propanedioic acid diethyl ester
  • 2-tert-Butylmalonic acid diethyl ester
  • Propanedioic acid, 2-(1,1-diMethylethyl)-, 1,3-diethyl ester
  • Diethyl tert-butylmalonate 96%
  • N-(4-butylphenyl)-3-pyridinecarboxamide
  • diethyl 2-tert-butylpropanedioate
  • 759-24-0
  • CH33CCHCOOC2H52
  • Building Blocks
  • Carbonyl Compounds
  • C10 to C11
  • Organic Building Blocks
  • Esters
  • C10 to C11
  • Carbonyl Compounds
  • Esters