ChemicalBook > CAS DataBase List > Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate

Product Name
Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate
CAS No.
57834-33-0
Chemical Name
Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate
Synonyms
UV Absorbers;UV Stabilizer UV-1;milestab 1;YISTAB UV-1;LOTSORB UV 1;Runsorb UV-1;Sinosorb? UV-1;Absorbent UV-1;UV absorber UV-1;UvAbsorberUv-1>98.5%
CBNumber
CB4295255
Molecular Formula
C17H18N2O2
Formula Weight
282.34
MOL File
57834-33-0.mol
More
Less

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Property

Boiling point:
188 °C(Press: 0.1 Torr)
Density 
1.05±0.1 g/cm3(Predicted)
vapor pressure 
78Pa at 25℃
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Light Yellow to Yellow Semi-Solid
pka
6.94±0.50(Predicted)
Water Solubility 
34.7mg/L at 20℃
LogP
4.46 at 25℃
CAS DataBase Reference
57834-33-0(CAS DataBase Reference)
EPA Substance Registry System
Benzoic acid, 4-[[(methylphenylamino)methylene]amino]-, ethyl ester (57834-33-0)
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P314Get medical advice/attention if you feel unwell.

P501Dispose of contents/container to..…

More
Less

N-Bromosuccinimide Price

TRC
Product number
E925558
Product name
Ethyl4-[[(methylphenylamino)methylene]amino]benzoate
Packaging
250mg
Price
$155
Updated
2021/12/16
AK Scientific
Product number
P954
Product name
N-(Ethoxycarbonylphenyl)-N'-methyl-N'-phenylformamidine
Packaging
500g
Price
$150
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0079109
Product name
ETHYL 4-[[(METHYLPHENYLAMINO)METHYLENE]AMINO]BENZOATE
Purity
95.00%
Packaging
1G
Price
$903.5
Updated
2021/12/16
Alichem
Product number
57834330
Product name
Ethyl4-(((methyl(phenyl)amino)methylene)amino)benzoate
Packaging
500g
Price
$159
Updated
2021/12/16
Alichem
Product number
57834330
Product name
Ethyl4-(((methyl(phenyl)amino)methylene)amino)benzoate
Packaging
1000g
Price
$242.4
Updated
2021/12/16
More
Less

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Chemical Properties,Usage,Production

Description

UV-1 is highly effective for the light stabilization of PUR in a wide range of applications, including microellular foams and integral skin foams for footwear, conventional rigid and flexible foams, fabric coatings for artificial leather, adhesives, sealants, and elastomers (spray, RIM, etc.). lItis conveniently added to PUR systems as a solution in the polyol component (polyether- or polyester-based).

Physical properties

UV-1(Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate) is a high efficient anti-ultraviolet additive. It is widely used in adhesives, polyurethane, foam and other materials. Because of its excellent absorption property, the ultraviolet radiation in 240-340nm is effectively absorbed and the ultraviolet radiation in the 300-330nm is nearly absorbed completely. Its anti-ultraviolet effect is 1.1-1.4 times as efficient as the UV absorbers of benzophenone or benzotriazole types.

Uses

UV-1(Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate) has good effect on the polymer system and it has good compatibility with the resin. The anti-yellowing effect is excellent. Its effect is superior to the other UV agent for PU. It is widely used in PU foaming, PU coating, PU leather, PU board and resins etc.

Industrial uses

UV absorber UV-1 is a liquid formamidine type ultraviolet absorber, it has a very strong UV absorption spectrum peak between 300-330nm, in this region polyurethane is susceptible to radiation degradation. So it has excellent light stability to microporous polyurethane products such as foam, integral skin foam, traditional foam, semi-rigid, soft foam, fabric coating, some adhesives, sealants and elastomers.It is convenient to use and miscible with polyester polyol and polyether polyols, has high solubility in many solvents, and has good compatibility with isocyanates and other polyurethane additives(such as light stabilizer 292).In polyurethane,normal usage level range is 0.2-1.0%.In adhesives and sealant,concentration level normally range is 0.5-1.0%.

Synthesis


165 g (1 mol) of ethyl p-aminobenzoate, 117.7 g (1.1 mol) of N-methylaniline, 10 g of p-toluenesulfonic acid,200mL with toluene toluene added to the 1000mL reaction flask, stirred and warmed to 50-60 ?? C, 2h dropwise 59.53g (1.1mol) formic acid(Content of 85%),Heating to reflux reaction, continue to separate the generated water, the reaction of about 5h to stop water when there is no water. The reaction solution was distilled off with atmospheric toluene recovery agent, toluene was recovered, the remaining vacuum distillation reaction solution,A pale yellow viscous liquid N- (4-ethoxycarbonylphenyl) -N'-methyl-N'-phenyl formamidine 262g, yield 93%, purity 99.4%.

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Suppliers

Changzhou Sunchem Pharmaceutical Chemical Material Co.,Ltd.
Tel
0519-85269522 13660798926
Fax
013660798926
Email
sunlight68@126.com
Country
China
ProdList
99
Advantage
60
Changzhou Yonghe Fine Chemical Co., Ltd.
Tel
0519-88552298 13921086978
Fax
86-519-88552298
Email
xuxiaosong1972@163.com
Country
China
ProdList
47
Advantage
65
Changzhou josenchem Pharmaceutical Chemical Material Co.,Ltd.
Tel
519-519-85286950 13338194135
Fax
0519-85286950
Email
info@josenchem.com
Country
China
ProdList
75
Advantage
58
Guangdong wengjiang Chemical Reagent Co., Ltd.
Tel
0751-2815688 13927872512
Fax
0751-8963795
Email
3007421951@qq.com
Country
China
ProdList
10057
Advantage
58
Qingdao Jade New Material Technology
Tel
0532-68077006 13658692156
Fax
0532-68077006
Email
zandrew@jadenmtc.com
Country
China
ProdList
310
Advantage
58
Qingdao Truelight functional Materials Technology Co., Ltd.
Tel
0532-81159002 13573844393
Fax
0532-81159002
Email
info@truelightchem.com
Country
China
ProdList
202
Advantage
58
Changzhou Sunlight Pharmaceutical Co., Ltd
Tel
0519-83131668 15995063688
Fax
+86-519-83138041
Email
info@sunlightchem.com
Country
China
ProdList
99
Advantage
69
FUJIAN DISHENG TECHNOLOGY CO.,LTD.
Tel
0571-85890193 15869128402
Fax
0571-88226546
Email
hlf@shinyangchem.com
Country
China
ProdList
41
Advantage
58
Changzhou Sunchem Pharmaceutical Chemical Material Co.,Ltd.
Tel
0519-85195575 15861192208
Fax
85195585
Email
850305@sunkechem.com
Country
China
ProdList
75
Advantage
69
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
More
Less

View Lastest Price from Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Ultraviolet Absorbent UV-1
Price
US $120.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-25
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Absorbent UV-1 57834-33-0
Price
US $200.00-95.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-25
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Ultraviolet absorber UV-1 57834-33-0
Price
US $0.00/Kg/Drum
Min. Order
25KG
Purity
98%min
Supply Ability
50tons/month
Release date
2021-06-02

57834-33-0, Ethyl 4-[[(methylphenylamino)methylene]amino]benzoateRelated Search:


  • N-(Ethoxycarbonylphenyl)-N'-methyl-N'-phenyl formamidine
  • 4-[[(METHYLPHENYLAMINO)METHYLENE]AMINO]-BENZOIC ACID
  • ethyl 4-[[(methylphenylamino)methylene]amino]benzoate
  • 4-[[(methylphenylamino)methylene]amino]-benzoicaciethylester
  • Benzoicacid,4-[[(methylphenylamino)methylene]amino]-,ethylester
  • N-(Ethoxycabonylphenyl)-N'-methyl-N'-phenyl formamidine
  • 4-[[(METHYLPHENYLAMINO)MEHTYLENE]AMINO]-BENZOIC ACID
  • UvAbsorberUv-1>98.5%
  • Ethy14-[[(methylphenylamino)methylene]amino] benzoate
  • UV Stabilizer UV-1
  • 4-[(N-methylanilino)methylideneamino]benzoic acid
  • milestab 1
  • LOTSORB UV 1
  • UV-1 Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate
  • UV absorber UV-1
  • Ethyl-4-[[(methylphenylamino)methylen]amino]benzoat
  • Ultraviolet absorbent UV-1
  • 4-[[(Methylphenylamino)methylene]amino]benzoic acid ethyl ester
  • Ethyl 4-[[(methylphe
  • Runsorb UV-1
  • 4-[[(MethylphenylaMino)Methylene]aMino]benzoate
  • N-(P-Ethoxycarbonylphenyl)-N'-Methyl-N'-phenyl for
  • N-(P-Ethoxycarbonylphenyl)-N'-methyl-N'-phenyl formamidine
  • (E)-Ethyl 4-[[(Methylphenylamino)Methylene]Amino]Benzoate
  • Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate(UV-1)
  • Light Stablizer UV-1
  • UV Absorbers
  • Ultraviolet absorber UV-1
  • ETHYL 4-[[(METHYLPHENYLAMINO)METHYLENE]AMINO]BENZOATE 57834-33-0
  • UV ABSORBER TRUELICHT UV1
  • UV absorber Sunsorb 1
  • YISTAB UV-1
  • Sinosorb? UV-1
  • Absorbent UV-1
  • N-(P-Ethoxycarbonylphenyl)-N'-methyl-N'-phenyl formamidine
  • N- (ethoxycarbonyl phenyl) -N'- methyl -N'- phenyl formamidine
  • 57834-33-0
  • 57843-33-0
  • 1104810-48-2
  • C17H18N2O2
  • C15H14N2O2
  • 57834-33-0