2,2-Dimethyl-1,3-dioxolane-4-methanol

Product Name: 2,2-Dimethyl-1,3-dioxolane-4-methanol
CAS No.: 100-79-8
Chemical Name: 2,2-Dimethyl-1,3-dioxolane-4-methanol
Synonyms: Glycerol acetonide;ISOPROPYLIDENEGLYCEROL;2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL;isopropylidene;glycerolacetonide;AUGEO;1,2-ISOPROPYLIDENEGLYCEROL;GIE;ideneg;idenegL
CBNumber: CB4305646
Molecular Formula: C6H12O3
Formula Weight: 132.16
MOL File: 100-79-8.mol

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2,2-Dimethyl-1,3-dioxolane-4-methanol Property

Melting point:: -27℃
Boiling point:: 189-191 °C
Density: 1.066 g/mL at 20 °C(lit.)
vapor pressure: 34Pa at 20℃
refractive index: n20/D 1.434
Flash point:: 176 °F
storage temp.: Sealed in dry,2-8°C
solubility: 172g/l soluble
form: Liquid
pka: 14.20±0.10(Predicted)
color: Clear colorless
PH: 4.0-7.5 (H2O)
Water Solubility: miscible
Merck: 14,5213
BRN: 104465
InChIKey: RNVYQYLELCKWAN-UHFFFAOYSA-N
LogP: 0.3 at 20℃
CAS DataBase Reference: 100-79-8(CAS DataBase Reference)
NIST Chemistry Reference: 1,3-Dioxolane-4-methanol, 2,2-dimethyl-(100-79-8)
EPA Substance Registry System: 1,3-Dioxolane-4-methanol, 2,2-dimethyl- (100-79-8)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 23-24/25-36-26
WGK Germany: 2
RTECS: JI0400000
F: 10
TSCA: Yes
HS Code: 29329970
Toxicity: LD50 in rats (g/kg): 7 orally; 3 i.p. (Perez)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 122696
Product name: DL-1,2-Isopropylideneglycerol
Purity: ≥97.0%
Packaging: 100g
Price: $41.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 122696
Product name: DL-1,2-Isopropylideneglycerol
Purity: ≥97.0%
Packaging: 3kg
Price: $344
Updated: 2024/03/01

TCI Chemical

Product number: D0710
Product name: 2,2-Dimethyl-1,3-dioxolane-4-methanol
Purity: >98.0%(GC)
Packaging: 25g
Price: $43
Updated: 2024/03/01

TCI Chemical

Product number: D0710
Product name: 2,2-Dimethyl-1,3-dioxolane-4-methanol
Purity: >98.0%(GC)
Packaging: 100g
Price: $95
Updated: 2024/03/01

Alfa Aesar

Product number: L02814
Product name: Solketal, 97%
Packaging: 100g
Price: $40.5
Updated: 2024/03/01

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2,2-Dimethyl-1,3-dioxolane-4-methanol Chemical Properties,Usage,Production

Chemical Properties

clear colourless liquid

Uses

Solketal is useful for synthesis of mono-, di- and triglycerides. It is used as the starting reagent for synthesis of tulipaline derivatives. It acts as a fuel additive in gasoline. It is an inhibitor of Methyl ethyl ketone .

Uses

DL-1,2-Isopropylideneglycerol was used as the starting reagent for synthesis of tulipaline derivatives.

Uses

A MEK inhibitor

Synthesis Reference(s)

Tetrahedron, 52, p. 9387, 1996 DOI: 10.1016/0040-4020(96)00501-7
The Journal of Organic Chemistry, 53, p. 2859, 1988 DOI: 10.1021/jo00247a043

General Description

DL-1,2-Isopropylideneglycerol undergoes effective isopropylidenation and deprotection reaction catalyzed by phosphotungstic acid.

Safety Profile

A poison by intravenous route. An eye irritant. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes.

2,2-Dimethyl-1,3-dioxolane-4-methanol Preparation Products And Raw materials

Raw materials

Glycerol HYDROGEN CYANIDE

Preparation Products

2,3-DIHYDROXYPROPYL METHACRYLATE BENZYL GLYCIDYL ETHER 3-ETHOXY-1,2-PROPANEDIOL 2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE Dropropizine

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2,2-Dimethyl-1,3-dioxolane-4-methanol Suppliers

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View Lastest Price from 2,2-Dimethyl-1,3-dioxolane-4-methanol manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Dl-1, 2-Isopropylideneglycerol 100-79-8
Price: US $100.00-45.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-06

Hebei Weibang Biotechnology Co., Ltd

Product: Solketal 100-79-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-22

HebeiShuoshengImportandExportco.,Ltd

Product: 2,2-Dimethyl-1,3-dioxolane-4-methanol 100-79-8
Price: US $6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000KG/Month
Release date: 2024-08-05

100-79-8, 2,2-Dimethyl-1,3-dioxolane-4-methanolRelated Search:

Dimethyl carbonate Dimethyl disulfide Lithium diisopropylamide Dimethyl fumarate N,N-Diisopropylethylamine Methanol 3-Methyl-2-butanone 1,3-Dioxan-5-ol Dimethyl ether Tris(hydroxymethyl)nitromethane Chloromethyl isopropyl carbonate ISOPROPYLHYDRAZINE HYDROCHLORIDE Dimethyl sulfoxide Allyl glycidyl ether Triisopropylsilane Dacthal ETHANE Glycerol

DL-ALPHA,BETA-ISOPROPYLIDENEGLYCEROL

LABOTEST-BB LT00233172

ISOPROPYLIDENGLYCEROL

ISOPROPYLIDENEGLYCEROL

GLYCEROL DIMETHYLKETAL

2,3-O-ISOPROPYLIDENEGLYCEROL

(+/-)-2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL

2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL

(+/-)-2,2-DIMETHYL-4-HYDROXYMETHYL-1,3-DIOXOLANE

2,2-DIMETHYL-4-HYDROXYMETHYL-1,3-DIOXOLANE

1,2-O-ISOPROPYLIDENEGLYCEROL

1,2-ISOPROPYLIDENEGLYCEROL

1,2-ISOPROPYLIDENE-RAC-GLYCEROL

1,2-Isopropylideneglycerin

1,2-O,O-Isopropylideneglycerin

(+/-)-2,2-Dimethyl-1,3-dioxolane-4-methanol~(+/-)-1,2-O-Isopropylideneglycerol

4-hydroxymethyl-2,2-dimethyl-1,3-dioxolan

glycerol 1,2-isopropylidene ether

DL-1,2-Isopropylideneglycerol, 98%

2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL(SOLKETAL)

Glycerol α,β-isopropylidene ether

Dimethyl-4-hydroxymethyl-1,3-dioxolane

1,3-Dioxolane-4-methanol, 2,2-dimethyl-

(n)-1,2-o-isopropylideneglycerol

(n)-2,2-dimethyl-1,3-dioxolane-4-methanol

ACETONE GLYCERINE KETAL

ACETONE KETAL OF GLYCERINE

SOLKETAL

SOLKETAL(R)

(R,S)-ISOPROPYLIDENE GLYCEROL

2,2-Dimethyl-1,3-dioxolan-4-yl methanol

glycerol,1,2-o-isopropylidene

Glycerolacetone

glycerolacetonide

isopropylidene

dl-α,β-isopropylideneglycerol

DL-1,2-Isopropylideneglycerol 98%

1,2-O-Isopropylideneglycerol for synthesis

Augeo SL191

THCB 200

AUGEO

2,2-dimethyl-3-dioxolane-4-methanol

2,2-Dimethyl-4-(hydroxymethyl)-1,3-dioxacyclopentane

2,2-Dimethyl-4-hydroxymethyldioxolane

2,2-Dimethyl-4-oxymethyl-1,3-dioxolane

2,2-Dimethyl-5-hydroxymethyl-1,3-dioxolane

1,2-isopropylidine glycerol

2,3-(Isopropylidenedioxy)propanol

2,3-Isopropylideneglycerol

4-(Hydroxymethyl)-2,2-dimethyl-1,3-dioxolane

4-Hydroxymethyl-2,2-dimethyl-1,3-dioxolane

Acetone monoglycerol ketal

Acetone, cyclic (hydroxymethyl)ethylene acetal

acetone,cyclic(hydroxymethyl)ethyleneacetal

acetoneglycerol

alpha,beta-Isopropylideneglycerol

GIE

Glycerinisopropylidene ether