3-Chlorobenzylamine
- Product Name
- 3-Chlorobenzylamine
- CAS No.
- 4152-90-3
- Chemical Name
- 3-Chlorobenzylamine
- Synonyms
- TIMTEC-BB SBB004155;RARECHEM AL BW 0019;3-CHLOROBENZYLAMINE;M-CHLOROBENZYL AMINE;3-Chlorobenzylamine 97%;3-Chlorobenzylamine,98%;3-Chlorobenzylamine >3-Chlorobenzylamine, 97+%;3-chloro-benzenemethanamin;m-Chlorobenzenemethanamine
- CBNumber
- CB4362966
- Molecular Formula
- C7H8ClN
- Formula Weight
- 141.6
- MOL File
- 4152-90-3.mol
3-Chlorobenzylamine Property
- Melting point:
- 97-98 °C
- Boiling point:
- 110-112 °C/17 mmHg (lit.)
- Density
- 1.159 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.559(lit.)
- Flash point:
- 209 °F
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 8.77±0.10(Predicted)
- form
- Liquid
- Specific Gravity
- 1.159
- color
- Clear colorless to faint yellow
- Sensitive
- Air Sensitive
- BRN
- 774509
- CAS DataBase Reference
- 4152-90-3(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzenemethanamine, 3-chloro-(4152-90-3)
- EPA Substance Registry System
- Benzenemethanamine, 3-chloro- (4152-90-3)
Safety
- Hazard Codes
- C,Xi
- Risk Statements
- 34-20/21/22-36/37/38
- Safety Statements
- 26-36/37/39-45-36
- RIDADR
- UN 2735 8/PG 2
- WGK Germany
- 3
- Hazard Note
- Corrosive
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29214990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 127167
- Product name
- 3-Chlorobenzylamine
- Purity
- 98%
- Packaging
- 5g
- Price
- $75.7
- Updated
- 2025/07/31
- Product number
- C1089
- Product name
- 3-Chlorobenzylamine
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $35
- Updated
- 2025/07/31
- Product number
- C1089
- Product name
- 3-Chlorobenzylamine
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $96
- Updated
- 2025/07/31
- Product number
- C363585
- Product name
- 3-Chlorobenzylamine
- Packaging
- 500mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- FC37239
- Product name
- 3-Chlorobenzylamine
- Packaging
- 50g
- Price
- $87.5
- Updated
- 2021/12/16
3-Chlorobenzylamine Chemical Properties,Usage,Production
Chemical Properties
clear colorless to faint yellow liquid
Uses
3-Chlorobenzylamine is used as pharmaceutical, pesticide and dye intermediates. It is used in the synthesis of 3-Chlorobenzamide and N-(3-Chlorobenzyl)-4-(2-indolyl)-2-pyrimidinamine.
General Description
3-Chlorobenzylamine undergoes reductive amination during dihydroquinolone synthesis. It is used in the synthesis of N- (3-chlorobenzyl) toluene-p-sulphonamide.
Synthesis
766-84-7
4152-90-3
The general procedure for the synthesis of 3-chlorobenzylamine from 3-chlorobenzonitrile was as follows: in a 25 mL round-bottomed flask, CuNP/WS catalyst was added to a mixed solution containing 5 mL of double-distilled water and 1 mmol of 3-chlorobenzonitrile. Subsequently, 4 mmol NaBH4 was added to the reaction mixture in 4 portions and stirred at room temperature for an appropriate time. The reaction process was monitored by thin layer chromatography (TLC) using ethyl acetate/hexane (1:5) as eluent. After completion of the reaction, the reaction mixture was filtered and the catalyst was rinsed twice with dichloromethane. The organic phase was washed with distilled water, dried over anhydrous MgSO4 and finally the solvent was evaporated under vacuum to give the target product 3-chlorobenzylamine.
References
[1] Journal of Organic Chemistry, 2012, vol. 77, # 1, p. 221 - 228
[2] ChemSusChem, 2017, vol. 10, # 5, p. 842 - 846
[3] Journal of the American Chemical Society, 2017, vol. 139, # 38, p. 13554 - 13561
[4] Journal of Medicinal Chemistry, 2017, vol. 60, # 19, p. 7965 - 7983
[5] Inorganic and Nano-Metal Chemistry, 2018, vol. 48, # 3, p. 176 - 181
3-Chlorobenzylamine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-Chlorobenzylamine manufacturers
- Product
- 3-Chlorobenzylamine 4152-90-3
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100tons
- Release date
- 2023-08-10
- Product
- 3-Chlorobenzylamine 4152-90-3
- Price
- US $8.00-0.40/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-03-22
- Product
- 3-Chlorobenzylamine 4152-90-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 85.0-99.8%
- Supply Ability
- 20tons
- Release date
- 2020-01-08