3-Chlorobenzylamine

Product Name: 3-Chlorobenzylamine
CAS No.: 4152-90-3
Chemical Name: 3-Chlorobenzylamine
Synonyms: TIMTEC-BB SBB004155;RARECHEM AL BW 0019;3-CHLOROBENZYLAMINE;M-CHLOROBENZYL AMINE;3-Chlorobenzylamine 97%;3-Chlorobenzylamine,98%;3-Chlorobenzylamine >3-Chlorobenzylamine, 97+%;3-chloro-benzenemethanamin;m-Chlorobenzenemethanamine
CBNumber: CB4362966
Molecular Formula: C7H8ClN
Formula Weight: 141.6
MOL File: 4152-90-3.mol

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3-Chlorobenzylamine Property

Melting point:: 97-98 °C
Boiling point:: 110-112 °C/17 mmHg (lit.)
Density: 1.159 g/mL at 25 °C (lit.)
refractive index: n20/D 1.559(lit.)
Flash point:: 209 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
pka: 8.77±0.10(Predicted)
form: Liquid
Specific Gravity: 1.159
color: Clear colorless to faint yellow
Sensitive: Air Sensitive
BRN: 774509
CAS DataBase Reference: 4152-90-3(CAS DataBase Reference)
NIST Chemistry Reference: Benzenemethanamine, 3-chloro-(4152-90-3)
EPA Substance Registry System: Benzenemethanamine, 3-chloro- (4152-90-3)

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Safety

Hazard Codes: C,Xi
Risk Statements: 34-20/21/22-36/37/38
Safety Statements: 26-36/37/39-45-36
RIDADR: UN 2735 8/PG 2
WGK Germany: 3
Hazard Note: Corrosive
TSCA: Yes
HazardClass: 8
PackingGroup: III
HS Code: 29214990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 127167
Product name: 3-Chlorobenzylamine
Purity: 98%
Packaging: 5g
Price: $75.7
Updated: 2025/07/31

TCI Chemical

Product number: C1089
Product name: 3-Chlorobenzylamine
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $35
Updated: 2025/07/31

TCI Chemical

Product number: C1089
Product name: 3-Chlorobenzylamine
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $96
Updated: 2025/07/31

TRC

Product number: C363585
Product name: 3-Chlorobenzylamine
Packaging: 500mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC37239
Product name: 3-Chlorobenzylamine
Packaging: 50g
Price: $87.5
Updated: 2021/12/16

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3-Chlorobenzylamine Chemical Properties,Usage,Production

Chemical Properties

clear colorless to faint yellow liquid

Uses

3-Chlorobenzylamine is used as pharmaceutical, pesticide and dye intermediates. It is used in the synthesis of 3-Chlorobenzamide and N-(3-Chlorobenzyl)-4-(2-indolyl)-2-pyrimidinamine.

General Description

3-Chlorobenzylamine undergoes reductive amination during dihydroquinolone synthesis. It is used in the synthesis of N- (3-chlorobenzyl) toluene-p-sulphonamide.

Synthesis

766-84-7

4152-90-3

The general procedure for the synthesis of 3-chlorobenzylamine from 3-chlorobenzonitrile was as follows: in a 25 mL round-bottomed flask, CuNP/WS catalyst was added to a mixed solution containing 5 mL of double-distilled water and 1 mmol of 3-chlorobenzonitrile. Subsequently, 4 mmol NaBH4 was added to the reaction mixture in 4 portions and stirred at room temperature for an appropriate time. The reaction process was monitored by thin layer chromatography (TLC) using ethyl acetate/hexane (1:5) as eluent. After completion of the reaction, the reaction mixture was filtered and the catalyst was rinsed twice with dichloromethane. The organic phase was washed with distilled water, dried over anhydrous MgSO4 and finally the solvent was evaporated under vacuum to give the target product 3-chlorobenzylamine.

References

[1] Journal of Organic Chemistry, 2012, vol. 77, # 1, p. 221 - 228
[2] ChemSusChem, 2017, vol. 10, # 5, p. 842 - 846
[3] Journal of the American Chemical Society, 2017, vol. 139, # 38, p. 13554 - 13561
[4] Journal of Medicinal Chemistry, 2017, vol. 60, # 19, p. 7965 - 7983
[5] Inorganic and Nano-Metal Chemistry, 2018, vol. 48, # 3, p. 176 - 181

3-Chlorobenzylamine Preparation Products And Raw materials

Raw materials

3-Chlorobenzaldehyde ZINC N,N-Dimethylformamide Ammonium formate 3-Chlorobenzyl chloride Glycine Diethyl ether Lithium Aluminum Hydride 3-Chlorobenzonitrile Hydroxylamine hydrochloride Hexamethylenetetramine

Preparation Products

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3-Chlorobenzylamine Suppliers

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View Lastest Price from 3-Chlorobenzylamine manufacturers

Hebei Yanxi Chemical Co., Ltd.

Product: 3-Chlorobenzylamine 4152-90-3
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100tons
Release date: 2023-08-10

Henan Fengda Chemical Co., Ltd

Product: 3-Chlorobenzylamine 4152-90-3
Price: US $8.00-0.40/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-03-22

Career Henan Chemical Co

Product: 3-Chlorobenzylamine 4152-90-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 85.0-99.8%
Supply Ability: 20tons
Release date: 2020-01-08

4152-90-3, 3-ChlorobenzylamineRelated Search:

3-Iodobenzylamine Dibenzylamine 4-Hydroxybenzylamine Phenoxybenzamine hydrochloride 3-Chloroperoxybenzoic acid 3-Chlorobenzyl chloride 3,4-DICHLOROBENZENE-1-CARBOHYDRAZIDE 3,4-Dichlorobenzylamine 2,3-DICHLOROBENZAMIDE Tetrachlorophthalimide 3-CHLOROBENZAMIDE 2-Amino-5-chlorobenzamide 2,5-DICHLOROBENZHYDRAZIDE (3,4-Dichlorobenzyl)methylamine 5-CHLOROSALICYLANILIDE 3-Chloro-4-methylbenzylamine 2-(AMINOMETHYL)-4-CHLOROPHENOL N-(4-AMINO-2-METHYLPHENYL)-4-CHLOROPHTHALIMIDE

M-CHLOROBENZYL AMINE

3-CHLOROBENZYLAMINE

(3-Chlorophenyl)methanamine

3-chloro-benzenemethanamin

Benzenemethanamine,3-chloro-

RARECHEM AL BW 0019

TIMTEC-BB SBB004155

3-Chlorobenzylamine 97%

3-Chlorobenzylamine, 97+%

3-Chlorobenzylamine,98%

3-chloro-benzenemethanamine

3-Chloro-1-(aminomethyl)benzene

m-Chlorobenzenemethanamine

Benzyl aMMoniuM chloride inter-

3-ChlorobenzylaMine, 98% 5GR

(3-Chlorophenyl)methylamine

(3-chlorophenyl)methylammonium

3-Chlorobenzylamine &gt

4152-90-3

ClC6H4CH2NH2

AMINE

C7

Amines

Building Blocks

Nitrogen Compounds

Organic Building Blocks

Anilines, Aromatic Amines and Nitro Compounds

Amines

C7

Nitrogen Compounds