ChemicalBook > CAS DataBase List > 4-FLUORO-3-NITROBENZALDEHYDE

4-FLUORO-3-NITROBENZALDEHYDE

Product Name: 4-FLUORO-3-NITROBENZALDEHYDE
CAS No.: 42564-51-2
Chemical Name: 4-FLUORO-3-NITROBENZALDEHYDE
Synonyms: uoro-3-nitrobenzaL;4-FLUORO-3-NITROBENZALDEHYDE;3-NITRO-4-FLUOROBENZALDEHYDE;2-Fluoro-5-formylnitrobenzene;Benzaldehyde, 4-fluoro-3-nitro-;4-Fluoro-3-nitrobenzaldehyde >4-Fluoro-3-nitrobenzaldehyde,97%;4-Fluoro-3-nitrobenzaldehyde 97%;4-Fluoro-3-nitrobenzaldehyde≥ 98% (GC)
CBNumber: CB4402462
Molecular Formula: C7H4FNO3
Formula Weight: 169.11
MOL File: 42564-51-2.mol

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4-FLUORO-3-NITROBENZALDEHYDE Property

Melting point:: 45-47 °C (lit.)
Boiling point:: 286.0±25.0 °C(Predicted)
Density: 1.443±0.06 g/cm3(Predicted)
Flash point:: >230 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: Crystalline Powder
color: White to tan
Sensitive: Air Sensitive
InChI: InChI=1S/C7H4FNO3/c8-6-2-1-5(4-10)3-7(6)9(11)12/h1-4H
InChIKey: ILKWFRCNNILIJW-UHFFFAOYSA-N
SMILES: C(=O)C1=CC=C(F)C([N+]([O-])=O)=C1
CAS DataBase Reference: 42564-51-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-22
Safety Statements: 26-36/37/39-22
WGK Germany: 3
HS Code: 29130000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 518301
Product name: 4-Fluoro-3-nitrobenzaldehyde
Purity: 97%
Packaging: 1g
Price: $68.6
Updated: 2023/06/20

TCI Chemical

Product number: F0956
Product name: 4-Fluoro-3-nitrobenzaldehyde
Purity: >95.0%(GC)
Packaging: 1g
Price: $23
Updated: 2025/07/31

TCI Chemical

Product number: F0956
Product name: 4-Fluoro-3-nitrobenzaldehyde
Purity: >95.0%(GC)
Packaging: 5g
Price: $64
Updated: 2025/07/31

TRC

Product number: B434838
Product name: 4-Fluoro-3-nitrobenzaldehyde
Packaging: 500mg
Price: $75
Updated: 2021/12/16

AK Scientific

Product number: X2171
Product name: 4-Fluoro-3-nitrobenzaldehyde
Packaging: 1g
Price: $14
Updated: 2021/12/16

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4-FLUORO-3-NITROBENZALDEHYDE Chemical Properties,Usage,Production

Chemical Properties

White to tan crystalline powder

Uses

4-Fluoro-3-nitrobenzaldehyde is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

Synthesis

20274-69-5

42564-51-2

General procedure for the synthesis of 4-fluoro-3-nitrobenzaldehyde from 3-nitro-4-fluorobenzyl alcohol: a dimethyl sulfoxide (12 mL) suspension of the pyridine-sulfur trioxide complex (4.65 g, 29.2 mmol) was added to a solution containing 4-fluoro-3-nitrobenzyl alcohol (1.0 g, 5.84 mmol) and triethylamine (4.07 mL, 29.2 mmol) in a dichloromethane (20 mL) solution. The reaction mixture was stirred at room temperature for 15 minutes. After completion of the reaction, the reaction solution was diluted with ether (150 mL), washed sequentially with water, 5% potassium bisulfate solution and water, and the organic layer was dried with anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure. The residue was purified by silica gel column chromatography [eluent: hexane-ethyl acetate (5:1)] to afford colorless crystalline 4-fluoro-3-nitrobenzaldehyde (0.86 g, 87% yield). The melting point of the product was 37-38 °C. 1H-NMR (CDCl3) δ: 7.51 (1H, t, J = 9.4 Hz), 8.10-8.30 (1H, m), 8.60 (1H, dd, J = 7.4, 2.2 Hz), 10.05 (1H, s).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2015, vol. 25, # 23, p. 5546 - 5550
[2] Patent: US2003/78251, 2003, A1
[3] Patent: WO2015/57938, 2015, A1. Location in patent: Page/Page column 52
[4] Patent: CN107400092, 2017, A. Location in patent: Paragraph 0293; 0295; 0300-0302
[5] Patent: CN108264511, 2018, A. Location in patent: Paragraph 0280; 0283; 0288-0290

4-FLUORO-3-NITROBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-FLUORO-3-NITROBENZALDEHYDE Suppliers

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View Lastest Price from 4-FLUORO-3-NITROBENZALDEHYDE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 4-Fluoro-3-nitrobenzaldehyde 42564-51-2
Price: US $3.00-9.00/KG
Min. Order: 0.1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-06-25

Shaanxi Dideu Medichem Co. Ltd

Product: 4-Fluoro-3-nitrobenzaldehyde 42564-51-2
Price: US $0.00-0.00/g
Min. Order: 10mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-15

Career Henan Chemical Co

Product: 4-FLUORO-3-NITROBENZALDEHYDE 42564-51-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-07-04

42564-51-2, 4-FLUORO-3-NITROBENZALDEHYDERelated Search:

Methyl 4-fluoro-3-nitrobenzoate 2,4-DIFLUORO-5-NITROBENZOIC ACID 7-Fluoro-6-nitro-4-hydroxyquinazoline 2-CHLORO-4-FLUORO-5-NITROBENZOIC ACID 2-CHLORO-4-FLUORO-5-NITROBENZOYL CHLORIDE 4'-Fluoro-3'-nitroacetophenone 4-FLUORO-3-NITRO-5-(TRIFLUOROMETHYL)BENZOIC ACID 4-Fluoro-3-nitrobenzoic acid 4-FLUORO-3-NITROBENZALDEHYDE 2-Fluoro-4-nitrobenzaldehyde 2-Fluoro-5-Nitrobenzaldehyde 5-Nitro-2-Fluorobenzaldehyde,2-FLUORO-5-NITROBENZALDEHYDE 2-FLUORO-6-NITROBENZALDEHYDE 5-Fluoro-2-nitrobenzaldehyde 98%,5-Fluoro-2-nitrobenzaldehyde98%,5-FLUORO-2-NITROBENZALDEHYDE 3-NITRO-4-FLUOROBENZOYL CHLORIDE 2,4,5-TRIFLUORO-3-NITROBENZOIC ACID 4'-CHLORO-4-FLUORO-3-NITROBENZOPHENONE 2,4-DIFLUORO-5-NITROBENZOIC ACID METHYL ESTER 2,3,4-Trifluoro-5-Nitro-Benzoic Acid

4-FLUORO-3-NITROBENZALDEHYDE

4-Fluoro-3-nitrobenzaldehyde≥ 98% (GC)

4-Fluoro-3-nitrobenzaldehyde 97%

3-NITRO-4-FLUOROBENZALDEHYDE

4-Fluoro-3-nitrobenzaldehyde,97%

2-Fluoro-5-formylnitrobenzene

4-Fluoro-3-nitrobenzaldehyde &gt

uoro-3-nitrobenzaL

Benzaldehyde, 4-fluoro-3-nitro-

42564-51-2

42564-51-3

C7H4FO3

Organic Building Blocks

Building Blocks

Aldehydes

Carbonyl Compounds

Halogenated Heterocycles ,Imidazoles ,Imidazolines/Imidazolidines

Fluorine series

Aromatic Aldehydes & Derivatives (substituted)

Aldehydes

Carbonyl Compounds