Methyl trioctyl ammonium chloride

Description Reference

Product Name: Methyl trioctyl ammonium chloride
CAS No.: 5137-55-3
Chemical Name: Methyl trioctyl ammonium chloride
Synonyms: ALIQUAT 336;aliquat;ADOGEN 464;METHYLTRIOCTYLAMMONIUM CHLORIDE;TRICAPRYLYLMETHYLAMMONIUM CHLORIDE;TOMAC;TRIOCTYLMETHYLAMMONIUM CHLORIDE;TRICAPRYLMETHYLAMMONIUM CHLORIDE;METHYLTRI-N-OCTYLAMMONIUM CHLORIDE;trioctylmethylammonium
CBNumber: CB4412612
Molecular Formula: C25H54N.Cl
Formula Weight: 404.16
MOL File: 5137-55-3.mol

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Methyl trioctyl ammonium chloride Property

Melting point:: -20°C
Boiling point:: 240°C
Density: 0.884 g/mL at 25 °C(lit.)
vapor pressure: 0Pa at 25℃
refractive index: n20/D 1.4665(lit.)
Flash point:: >230 °F
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: soluble in Chloroform, Hexanes
form: Viscous Liquid
color: Colourless to pale orange
Odor: Ammonical
Water Solubility: Partially insoluble
Sensitive: Hygroscopic
BRN: 4039255
Stability:: Stable. Incompatible wth strong oxidizing agents. Hygroscopic.
InChIKey: XKBGEWXEAPTVCK-UHFFFAOYSA-M
LogP: 4.5 at 25℃
CAS DataBase Reference: 5137-55-3(CAS DataBase Reference)
EPA Substance Registry System: Methyltrioctylammonium chloride (5137-55-3)

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Safety

Hazard Codes: Xn,N,C
Risk Statements: 22-38-41-50/53-36/37/38-20/21/22-34
Safety Statements: 26-39-60-61-36-45-36/37/39
RIDADR: UN 2810 6.1/PG 3
WGK Germany: 3
RTECS: UZ2997500
F: 3-10
HazardClass: 6.1
PackingGroup: III
HS Code: 29239000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 69485
Product name: Methyltrioctylammonium chloride
Purity: ≥97.0% (AT)
Packaging: 10g
Price: $109
Updated: 2024/03/01

Sigma-Aldrich

Product number: 69485
Product name: Methyltrioctylammonium chloride
Purity: ≥97.0% (AT)
Packaging: 50g
Price: $385
Updated: 2024/03/01

TCI Chemical

Product number: T1365
Product name: Methyltri-n-octylammonium Chloride
Purity: >95.0%(T)
Packaging: 25g
Price: $106
Updated: 2024/03/01

TCI Chemical

Product number: T1365
Product name: Methyltri-n-octylammonium Chloride
Purity: >95.0%(T)
Packaging: 500g
Price: $1189
Updated: 2024/03/01

Usbiological

Product number: 261427
Product name: Tricaprylylmethylammonium chloride
Packaging: 100g
Price: $333
Updated: 2021/12/16

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Methyl trioctyl ammonium chloride Chemical Properties,Usage,Production

Description

Methyltrioctylammonium chloride is a water insoluble quaternary ammonium salt, which is widely used as a counter ion in solvent extraction of anionic metal complexes. It is widely used as a phase transfer catalyst for the catalytic oxidation of cyclohexene to 1,6-hexanedioic acid. In comparison to traditional method of oxidizing cyclohexanol or cyclohexanone with nitric acid or potassium permanganate, the usage of methyltrioctylammonium chloride is a more environmentally friendly reaction.

Reference

N. Pourreza, H. Zavvar Mousavi, Determination of cadmium by flame atomic absorption spectrometry after preconcentration on naphthalene– methyltrioctylammonium chloride adsorbent as tetraiodocadmate (II) ions, Analytica Chimica Acta, 2004, vol. 503, pp. 279-282

Chemical Properties

viscous colourless to pale orange liquid

Uses

Methyltrioctylammonium chloride can be used:

As a catalyst in the synthesis of acridine dione derivatives from aromatic aldehyde, dimedone and amines under ultrasonic irradiations.
As a catalyst in the synthesis of extended π-systems using aromatic aldehydes and methyldiazines.
As a component of a catalytic system used in the Suzuki-Miyaura cross-coupling reaction of a variety of aryl and heteroaryl chlorides in H₂O.

Uses

Mixture of C₈ and C₁₀ chains with C₈ predominating. Used as a metal extraction reagent and a phase-transfer catalyst.

Definition

ChEBI: An organic chloride salt having methyltrioctylammonium as the cation.

Flammability and Explosibility

Not classified

Safety Profile

Poison by ingestion and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl-.

Purification Methods

A 30% (v/v) of Aliquat 336 solution in *benzene is washed twice with an equal volume of 1.5M HBr. [Petrow & Allen, Anal Chem 33 1303 1961.] It is purified by dissolving 50g in CHCl3 (100mL) and shaking with 20% NaOH solution (200mL) for 10minutes, and followed by 20% NaCl (200mL) for 10minutes. It is then washed with a small volume of H2O and filtered through a dry filter paper [Adam & Pribil Talanta 18 733 1971]. n-Alkylammonium chloride n=2,4,6. Recrystallise them from EtOH or an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985, Chu & Thomas J Am Chem Soc 108 6270 1986.] n-Alkyltrimethylammonium bromide n=10,12,16. Recrystallise them from an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985.]

Methyl trioctyl ammonium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

1,3-Dimethyl-2-imidazolidinone 4-Chlorobenzylsulfonyl chloride (2-CHLORO-PHENYL)-METHANESULFONYL CHLORIDE (4-BROMOTHIOPHEN-2-YL)METHANESULFONYL CHLORIDE 3-NITROPHENYLMETHANESULFONYL CHLORIDE 6-BENZYLOXYPURINE (5-BROMOTHIOPHEN-3-YL)METHANESULFONYL CHLORIDE

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Methyl trioctyl ammonium chloride Suppliers

Belgium 2 Canada 1 China 413 Europe 2 France 1 Germany 6 India 22 Japan 8 Slovakia 1 South Korea 1 Switzerland 1 The Netherlands 1 United Kingdom 9 United States 43 Global 511

TOKYO CHEMICAL INDUSTRY CO., LTD.

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Melrob-Chemiplus Limited

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TCI Japan

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FUJIFILM Wako Pure Chemical Corporation

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Kanto Chemical Co., Inc.

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View Lastest Price from Methyl trioctyl ammonium chloride manufacturers

Anhui Royal Chemical Co., Ltd.

Product: METHYL TRIOCTYL AMMONIUM CHLORIDE 5137-55-3
Price: US $2430.00/kg
Min. Order: 900kg
Purity: 90%
Supply Ability: 10 tons
Release date: 2024-05-22

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Methyl trioctyl ammonium chloride 5137-55-3
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-30

HebeiShuoshengImportandExportco.,Ltd

Product: Methyl trioctyl ammonium chloride 5137-55-3
Price: US $6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000KG/Month
Release date: 2024-08-08

5137-55-3, Methyl trioctyl ammonium chlorideRelated Search:

Tetraoctylammonium chloride Ammonium sulfate Potassium chloride Sodium chloride Triethylmethylammonium chloride Polyvinyl chloride Triton X-100 Calcium chloride Ammonium hydroxide Sulfuryl chloride Choline chloride Ammonium acetate Ammonium chloride Ferric chloride Methyltrioctylammonium bromide 4-tert-Octylphenol Methyltriphenylphosphonium bromide Methyltriphenylphosphonium iodide

TRICAPRYLMETHYLAMMONIUM CHLORIDE

TRICAPRYLYLMETHYLAMMONIUM CHLORIDE

TRICAPRYLYL MONOMETHYLAMMONIUM CHLORIDE

TRI-N-OCTYLMETHYLAMMONIUM CHLORIDE

TRIOCTYLMETHYLAMMONIUM CHLORIDE

TOMAC

TricapryL

CAPRIQUAT

METHYLTRIOCTYLAMMONIUM CHLORIDE

METHYLTRIOCTYLAMINE HYDROCHLORIDE

METHYLTRI-N-OCTYLAMMONIUM CHLORIDE

Aliquat(rg 336

METHYLTRICAPRYLAMMONIUM CHLORIDE

Methyltri-n-octylammonium chloride~Tricaprylylmethylammonium chloride

Trictylmethylammonium chloride

METHYLTRI-N-OCTYLAMMONIUM

N-Methyl-N,N,N-trioctylammonium chloride

AliquatÖÖ(rg336

Trioctylmethylammonium Chloride (R=C6-C10) [Phase-transfer Catalyst]

ALIQUAT(R) 336

ALIQUAT(TM) 336

ALIQUAT 336

ADOGEN 464

Aliquat 336, average MW 442

AMMONIUM,METHYLTRIOCTYL-,CHLORIDE

ALIQUAT 336 (TRIOCTYLMETHYLAMMONIUM CHLORIDE)

Trioctylmonomethylammonium chloride

Methyltrioctylammonium chloride ,90%

Aliquat 336N

Aliquat 336-PTC

Methyltri(octyl)aminium

Methyltrioctylaminium

1-Octanaminium,N-methyl-N,N-dioctyl-,chloride

aliquat

methyltricaprylylammoniumchloride

methyltrioctyl-ammoniuchloride

n-methyl-n,n-dioctyl-1-octanaminiuchloride

n-methyl-n,n-dioctyl-1-octanaminiumchloride

trioctylmethylammonium

Methyltrioctylammonium

N-Methyl-N,N,N-trioctylaminium

Trioctylmethylaminium

TRICAPRYLYL MONOMETHYLAMMONIUM CHLORIDE, 75% SOLN

Methyltrioctylammoni

Methyltrioctylammonium chloride purum, >=97.0% (AT)

Nsc61369

Trioctylmethylammonium chloride ,98%

TOMAC 75

N-Methyl-N,N-dioctyloctan-1-aMiniuM chloride

DeMecolcine research grade

1-OctanaMiniuM,N-Methyl-N,N-dioctyl-, chloride (1:1)

MethyltrioctylaMMoniuM chloride >=97.0% (AT)

Three octyl diMethyl aMMoniuM chloride (5137-55-3) Methyl octyl three aMMoniuM chloride

MethyltrioCLylaMMoniuM Chloride

N8,8,8,1Cl

Methyl trioctyl ammonium chloride Liquid

Methyl Trioctylammonum Chloride

Aliquat 336Aliquat 336