ChemicalBook > CAS DataBase List > 2,3,5,6-Tetrachloropyridine

2,3,5,6-Tetrachloropyridine

Product Name
2,3,5,6-Tetrachloropyridine
CAS No.
2402-79-1
Chemical Name
2,3,5,6-Tetrachloropyridine
Synonyms
SYMTET;Tetrapyridine;2.3.5.6-Tetrac;Bifeprunox Impurity 50;2,3,5,6-tetrachlorpyridine;2,3,5,6-TETRACHLOROPYRIDINE;2,3,5,7-tetrachloropyridine;2,3,5,6-tetrachloro-pyridin;Pyridine, 2,3,5,6-tetrachloro-;2,3,5,6-Tetrachloropyridine 98+%
CBNumber
CB4486545
Molecular Formula
C5HCl4N
Formula Weight
216.88
MOL File
2402-79-1.mol
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2,3,5,6-Tetrachloropyridine Property

Melting point:
90.5°C
Boiling point:
251.6°C
Density 
2.0309 (rough estimate)
vapor pressure 
3Pa at 25℃
refractive index 
1.6000 (estimate)
Flash point:
188°C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
very soluble in Ether,Ethanol
form 
Crystalline
pka
-5.50±0.50(Predicted)
color 
White to Almost white
BRN 
129639
InChIKey
FATBKZJZAHWCSL-UHFFFAOYSA-N
LogP
3.87 at 30℃ and pH7
Surface tension
72.4mN/m at 20.7mg/L and 21.3℃
CAS DataBase Reference
2402-79-1(CAS DataBase Reference)
EPA Substance Registry System
2,3,5,6-Tetrachloropyridine (2402-79-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
20/21/22-36/37/38-51/53
Safety Statements 
26-36/37/39-60-61-36
RIDADR 
2811
RTECS 
UT8225000
Hazard Note 
Harmful/Irritant
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
2933392000
Hazardous Substances Data
2402-79-1(Hazardous Substances Data)
Toxicity
mouse,LD50,intraperitoneal,1150mg/kg (1150mg/kg),BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)LIVER: FATTY LIVER DEGERATIONBEHAVIORAL: ANTIPSYCHOTIC,Toxicology and Applied Pharmacology. Vol. 11, Pg. 361, 1967.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H301Toxic if swalloed

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H401Toxic to aquatic life

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
T2331
Product name
2,3,5,6-Tetrachloropyridine
Purity
>98.0%(GC)
Packaging
5g
Price
$70
Updated
2024/03/01
TCI Chemical
Product number
T2331
Product name
2,3,5,6-Tetrachloropyridine
Purity
>98.0%(GC)
Packaging
25g
Price
$218
Updated
2024/03/01
Alfa Aesar
Product number
L19458
Product name
2,3,5,6-Tetrachloropyridine, 98%
Packaging
1g
Price
$23.65
Updated
2024/03/01
TRC
Product number
T889785
Product name
2,3,5,6-Tetrachloropyridine
Packaging
250mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
083829
Product name
2,3,5,6-Tetrachloropyridine
Purity
97%
Packaging
50g
Price
$50
Updated
2021/12/16
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2,3,5,6-Tetrachloropyridine Chemical Properties,Usage,Production

Uses

2,3,5,6-Tetrachloropyridine is used as a chemical intermediate in the production of chlorpyrifos and triclopyr.

Synthesis

2,3,5,6-Tetrachloropyridine is synthesised in three steps by chemical reaction using 2,3,4,5,6-pentachloropyridine as a raw material. The specific synthesis steps are as follows:
Step (1): 2 parts of pentachloropyridine was dissolved in 200 parts of ethanol at 40 ℃ until 0.6 part of metallic manganese powder was added after the raw material was completely dissolved; 1.3 parts of ammonium acetate, 5 parts of water and 10 parts of ethanol were mixed Uniform dropping, dropping time of 2h; After completion of the dropwise addition, the reaction solution was stirred for 4 hours.
Step (2): add ammonia to adjust the pH value of 8~9, heated to 65 , through 3L / min air 1h reaction was oxidized.
Step (3): Oxidation liquid filtration: The resulting solid was filtered and separated by washing with 20 parts of toluene. Ethanol washed twice, washed twice, after dryingproduct. Products tested by the magnetic content of manganese oxide products, the specific surface area of 53m2 / g, Mn content of 70.90%, CaO content0.0012%, K content 0.0005%, Na content 0.0025%, S content 0.0070%. The XRD pattern of manganese tetroxide and the comparison with the standard map is Mn3O44. Figure 5 (a) and (b) are scanning electron micrographs. It can be seen that the product is a hollow spherical structure. (C) and (d) are transmission electron micrographs, and the hollow structure can be seen and the product is from 10 to 25 nm Grain composition. The filtrate was filtered and the organic solution of the solution of manganese tetrachloride was combined and evaporated to recover the toluene solvent. Then, 10 parts of 5% dilute hydrochloric acid was added at a temperature of 65 ℃ and stirred for 1 h to obtain 2,3,5,6-tetrachloropyridine ; The yield was 99.5%.

2,3,5,6-Tetrachloropyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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2,3,5,6-Tetrachloropyridine Suppliers

Shanghai LanRun Chemical Co., Ltd.
Tel
021-69515658 ; 69515628 13701998368
Fax
021-69515998
Email
longrunchem@163.com
Country
China
ProdList
3912
Advantage
50
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
Advantage
65
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9513
Advantage
66
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
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View Lastest Price from 2,3,5,6-Tetrachloropyridine manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
2,3,5,6-Tetrachloropyridine 2402-79-1
Price
US $50.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-12-03
Hebei Weibang Biotechnology Co., Ltd
Product
2,3,5,6-Tetrachloropyridine 2402-79-1
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-29
Shanghai Yongzeng Technology Co.,Ltd
Product
2,3,5,6-Tetrachloropyridine 2402-79-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%min
Supply Ability
100kgs
Release date
2024-09-04

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