Hexylamine Property

Melting point:

−23 °C(lit.)

Boiling point:

131-132 °C(lit.)

Density 

0.766 g/mL at 25 °C(lit.)

vapor pressure 

10.6 hPa (20 °C)

FEMA 

4243 | HEXYLAMINE

refractive index 

n20/D 1.418(lit.)

Flash point:

27 °C

storage temp. 

Store below +30°C.

solubility 

14g/l

pka

10.56(at 25℃)

form 

Liquid

color 

Clear colorless to slightly yellow

PH

11.6 (10g/l, H2O, 20℃)

Odor

at 0.10 % in propylene glycol. ammoniacal musty fishy

Odor Type

fishy

explosive limit

2.1-9.3%(V)

Water Solubility 

14 g/L (20 ºC)

Sensitive 

Air Sensitive

JECFA Number

1588

BRN 

1731298

Dielectric constant

4.0800000000000001

Stability:

Stable. Incompatible with acids, acid anhydrides, acid chlorides, carbon dioxide, strong oxidizing agents.

InChIKey

BMVXCPBXGZKUPN-UHFFFAOYSA-N

LogP

2.06-2.31 at 25℃

CAS DataBase Reference

111-26-2(CAS DataBase Reference)

NIST Chemistry Reference

1-Hexanamine(111-26-2)

EPA Substance Registry System

Hexylamine (111-26-2)

Safety

Hazard Codes 

C,F,Xi,N

Risk Statements 

10-21/22-35-20/21/22-51/53

Safety Statements 

26-36/37/39-45-16-61

RIDADR 

UN 2734 8/PG 1

WGK Germany 

1

RTECS 

MQ4540000

F 

34

Autoignition Temperature

270 °C

Hazard Note 

Irritant/Flammable/Corrosive/Air Sensitive

TSCA 

Yes

HazardClass 

8

PackingGroup 

II

HS Code 

29159020

HS Code 

29211980

Hazardous Substances Data

111-26-2(Hazardous Substances Data)

Toxicity

LD50 orally in Rabbit: 240 mg/kg

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H314Causes severe skin burns and eye damage

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Hexylamine Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Chemical Properties

n-Hexylamine is a colorless, flammable liquid, slightly soluble in water and soluble in alcohol and ether.

Chemical Properties

Colorless to yellow liquid; fishy aroma.

Uses

n-Hexylamine is used in organic syntheses.

Uses

1-Hexylamine is used as corrosion inhibitors, emulsifiers and surfactants. It is used in dyes, rubber and pharmaceutical industries. It is also used to study the modification of alkanethlol monolayers in gas-phase surface reactions. It acts as an initiator in the ring opening polymerization of N-carboxyanhydride.

Uses

Toxic by ingestion, inhalation, and skin absorption. Flammable, moderate fire risk.

Definition

ChEBI: A 6-carbon primary aliphatic amine.

Aroma threshold values

High strength odor; fishy type, recommend smelling in a 0.10% solution or less

Synthesis Reference(s)

The Journal of Organic Chemistry, 55, p. 2271, 1990 DOI: 10.1021/jo00295a002
Synthesis, p. 605, 1981

General Description

A water-white liquid with an amine-like odor. Flash point 85°F. Boiling point 132°F. Less dense than water and poorly soluble in swater. Hence floats on water. May be toxic by inhalation, ingestion or skin absorption.

Air & Water Reactions

Highly flammable. Slightly soluble in water.

Reactivity Profile

HEXYLAMINE neutralize acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Flammability and Explosibility

Flammable

Purification Methods

Dry with, and fractionally distil the hexylamine from, KOH or CaH2. Store away from CO2. [Beilstein 4 IV 709.]