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METHYL 4-PENTENOATE

Product Name
METHYL 4-PENTENOATE
CAS No.
818-57-5
Chemical Name
METHYL 4-PENTENOATE
Synonyms
SKL511;methyl pent-4-enoate;Allylacetic acid methyl ester;Methyl 4-pentenoate >=95.0% (GC);4-Pentenoic acid methyl ester, Allylacetic acid methyl ester, Methyl allylacetate
CBNumber
CB4497651
Molecular Formula
C6H10O2
Formula Weight
114.14
MOL File
818-57-5.mol
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METHYL 4-PENTENOATE Property

Boiling point:
125-126 °C
Density 
0.904±0.06 g/cm3(Predicted)
refractive index 
n20/D 1.415
FEMA 
4353 | METHYL 4-PENTENOATE
Flash point:
29 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Odor
at 10.00 % in dipropylene glycol. green fruit
Odor Type
green
JECFA Number
1616
LogP
1.45
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Safety

Hazard Codes 
Xi
Risk Statements 
10-36
Safety Statements 
26
RIDADR 
UN 3272 3/PG 3
WGK Germany 
3
10-23
HS Code 
2916199590
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
49661
Product name
Methyl 4-pentenoate
Purity
≥95.0%(GC)
Packaging
1g
Price
$51.2
Updated
2024/03/01
Sigma-Aldrich
Product number
49661
Product name
Methyl 4-pentenoate
Purity
≥95.0%(GC)
Packaging
5G
Price
$306
Updated
2024/03/01
TRC
Product number
P227415
Product name
4-PentenoicAcidMethylEster
Packaging
25g
Price
$1175
Updated
2021/12/16
AK Scientific
Product number
0026AQ
Product name
Methyl 4-pentenoate
Packaging
1g
Price
$179
Updated
2021/12/16
Apolloscientific
Product number
OR908012
Product name
Methylpent-4-enoate
Purity
95%
Packaging
1g
Price
$182
Updated
2021/12/16
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METHYL 4-PENTENOATE Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid; green fruity aroma.

Uses

4-Pentenoic Acid Methyl Ester is used in the preparation of 2,4-dienoates.

Definition

ChEBI: Methyl 4-pentenoate is a fatty acid methyl ester.

Aroma threshold values

Medium strength odor; recommend smelling in a 10.00% solution or less

General Description

Methyl 4-pentenoate is an unsaturated methyl ester that is prepared by the esterification of 1-pentenoic acid with methanol. It undergoes amidation with formamide via acetone-initiated photochemical reaction to form a 1:1 adduct. The metathesis of methyl 4-pentenoate with different Mo(VI)alkylidene complexes have been reported. It acts as a chain transfer agent during the polymerization of exo,exo-5,6-bis(methoxymethyl)-7-oxabicyclo[2.2.1]hept-2-ene using RuII(H20)6(tos)2 (tos =p-toluenesulfonate) as a catalyst.

METHYL 4-PENTENOATE Preparation Products And Raw materials

Raw materials

Preparation Products