2-METHOXYETHYL P-TOLUENESULFONATE
- Product Name
- 2-METHOXYETHYL P-TOLUENESULFONATE
- CAS No.
- 17178-10-8
- Chemical Name
- 2-METHOXYETHYL P-TOLUENESULFONATE
- Synonyms
- 2-methoxyethyl-p-toluensulfonate;.beta.-Methoxy-4-ethyl toluene sulfonate;2-Methoxyethyl p-Toluenesulfonate;2-methoxy-ethano 4-methylbenzenesulfonate;2-Methoxyethyl 4-methylbenzenesulfonate, 98+%;Ethanol, 2-methoxy-, 1-(4-methylbenzenesulfonate);4-Methylbenzenesulfonic acid 2-methoxyethyl ester;(8Z)-8-hexa-2,4-diynylidene-4,9-dioxaspiro[4.4]non-6-ene;2-METHOXYETHYL-P-TOLUENESULFONATE (PTS-MC) 4-TOLUENESULFONIC ACID 2-METHOXYETHYL ESTER
- CBNumber
- CB4577205
- Molecular Formula
- C10H14O4S
- Formula Weight
- 230.28
- MOL File
- 17178-10-8.mol
2-METHOXYETHYL P-TOLUENESULFONATE Property
- Melting point:
- 10 °C
- Boiling point:
- 141 °C / 0.2mmHg
- Density
- 1.21
- refractive index
- 1.5100-1.5120
- storage temp.
- Inert atmosphere,Room Temperature
- form
- clear liquid
- color
- Colorless to Almost colorless
- InChI
- InChI=1S/C10H14O4S/c1-9-3-5-10(6-4-9)15(11,12)14-8-7-13-2/h3-6H,7-8H2,1-2H3
- InChIKey
- TZXJJSAQSRHKCZ-UHFFFAOYSA-N
- SMILES
- C(OS(C1=CC=C(C)C=C1)(=O)=O)COC
- EPA Substance Registry System
- Ethanol, 2-methoxy-, 4-methylbenzenesulfonate (17178-10-8)
Safety
- HS Code
- 2909500090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- T286087
- Product name
- 2-METHOXYETHYL 4-METHYLBENZENESULFONATE
- Purity
- Aldrich<sup>CPR</sup>
- Packaging
- 1 unit
- Price
- $185
- Updated
- 2025/07/31
- Product number
- T286087
- Product name
- 2-METHOXYETHYL 4-METHYLBENZENESULFONATE
- Purity
- AldrichCPR
- Packaging
- 100MG
- Price
- $179
- Updated
- 2024/03/01
- Product number
- T1303
- Product name
- 2-Methoxyethyl p-Toluenesulfonate
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $87
- Updated
- 2025/07/31
- Product number
- T1303
- Product name
- 2-Methoxyethyl p-Toluenesulfonate
- Purity
- >98.0%(GC)
- Packaging
- 100g
- Price
- $223
- Updated
- 2025/07/31
- Product number
- T1303
- Product name
- 2-Methoxyethyl p-Toluenesulfonate
- Purity
- >98.0%(GC)
- Packaging
- 500g
- Price
- $674
- Updated
- 2025/07/31
2-METHOXYETHYL P-TOLUENESULFONATE Chemical Properties,Usage,Production
Synthesis
109-86-4
98-59-9
17178-10-8
In a 250 mL round bottom flask, 2-methoxyethanol (7.36 mL, 0.10 mol) and a catalytic amount of tetra-n-butylammonium bromide (TBAB) were dissolved in methylene chloride (50 mL) and mixed with stirring. Subsequently, 30% aqueous sodium hydroxide solution (15 mL) was slowly added. A dichloromethane solution of p-toluenesulfonyl chloride (20 mL) was added dropwise under cooling in an ice water bath. After the dropwise addition was completed, the ice water bath was removed and the reaction mixture was stirred continuously at room temperature for 24 hours. Upon completion of the reaction, the reaction mixture was washed with distilled water (3 × 30 mL) to remove water-soluble impurities. The organic layer was dried with anhydrous sodium sulfate, filtered, and the solvent was removed by rotary evaporator under reduced pressure to give the yellow oily product 2-methoxyethyl p-toluenesulfonate in 95% yield. The product was confirmed by infrared spectroscopy (KBr press), and the main absorption peaks were: 3468 (m), 2938 (s), 2889 (s), 1597 (m), 1455 (m), 1357 (s), 1184 (s), 1130 (m), 1101 (m), 1018 (m), 919 (m), and 821 (m) cm^-1. The NMR hydrogen spectrum ( 400 MHz, acetone-d6) data are as follows: δ 3.20 (s, 3H), 3.48 (t, J = 4.6 Hz, 2H), 4.08 (t, J = 4.6 Hz, 2H), 7.71 (d, J = 8.4 Hz, 2H), 7.28 (d, J = 8.4 Hz, 2H), 2.36 (s, 3H). Elemental analysis results: calculated values for C10H14SO4: C, 52.16; H, 6.13. measured values: C, 52.09; H, 6.17.
References
[1] Dalton Transactions, 2007, # 13, p. 1309 - 1315
[2] Journal of Organometallic Chemistry, 2011, vol. 696, # 8, p. 1687 - 1690
[3] Chemistry of Materials, 2012, vol. 24, # 9, p. 1583 - 1590
[4] Dyes and Pigments, 2013, vol. 97, # 2, p. 278 - 285
[5] New Journal of Chemistry, 2016, vol. 40, # 4, p. 3456 - 3463
2-METHOXYETHYL P-TOLUENESULFONATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-METHOXYETHYL P-TOLUENESULFONATE manufacturers
- Product
- m-PEG2-Tos 17178-10-8
- Price
- US $0.00/g
- Min. Order
- 1000g
- Purity
- >98.00%
- Supply Ability
- 1000g
- Release date
- 2024-03-27
- Product
- 2-METHOXYETHYL P-TOLUENESULFONATE 17178-10-8
- Price
- US $20.00/kg
- Min. Order
- 1kg
- Purity
- 98
- Supply Ability
- 1000kg
- Release date
- 2022-09-19
- Product
- 2-METHOXYETHYL P-TOLUENESULFONATE 17178-10-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2018-08-09