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Ruthenium(III) chloride

Product Name
Ruthenium(III) chloride
CAS No.
10049-08-8
Chemical Name
Ruthenium(III) chloride
Synonyms
RUTHENIUM TRICHLORIDE;RUTHENIUM CHLORIDE;RUTHENIUM(III) CHLORIDE ANHYDROUS;Ruthenic chloride;Ruthenium(III) chL;Ruthenium(III) chlor;Ruthenium triehloride;Ruthenium (Ⅲ) chloride;RUTHENIUM(III) CHLORIDE;Ruthenium sesquichloride
CBNumber
CB4666471
Molecular Formula
Cl3Ru
Formula Weight
207.43
MOL File
10049-08-8.mol
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Ruthenium(III) chloride Property

Melting point:
500 °C
Density 
3.11 g/mL at 25 °C (lit.)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
insoluble in H2O; slightly soluble in ethanol
form 
Powder or Crystals
color 
Black
Water Solubility 
INSOLUBLE
Sensitive 
Hygroscopic
Crystal Structure
AlCl3 type
crystal system
Monoclinic
Merck 
14,8302
Space group
C2/m
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.6061.0360.59890109.2900.355
Stability:
Stable. Incompatible with zinc. Protect from moisture.
InChI
InChI=1S/3ClH.Ru/h3*1H;/q;;;+3/p-3
InChIKey
YBCAZPLXEGKKFM-UHFFFAOYSA-K
SMILES
[Ru](Cl)(Cl)Cl
CAS DataBase Reference
10049-08-8(CAS DataBase Reference)
EPA Substance Registry System
Ruthenium chloride (RuCl3) (10049-08-8)
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Safety

Hazard Codes 
C
Risk Statements 
34-52/53-22
Safety Statements 
26-36/37/39-45-61
RIDADR 
UN 3260 8/PG 2
WGK Germany 
2
RTECS 
VM2650000
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
208523
Product name
Ruthenium(III) chloride
Purity
Ru content 45-55%
Packaging
2g
Price
$124
Updated
2024/03/01
Sigma-Aldrich
Product number
208523
Product name
Ruthenium(III) chloride
Purity
Ru content 45-55%
Packaging
10g
Price
$370
Updated
2024/03/01
TCI Chemical
Product number
R0074
Product name
Ruthenium(III) Chloride
Packaging
1g
Price
$58
Updated
2021/12/16
TCI Chemical
Product number
R0074
Product name
Ruthenium(III) Chloride
Packaging
5g
Price
$149
Updated
2021/12/16
Alfa Aesar
Product number
047182
Product name
Ruthenium(III) chloride, anhydrous, Ru 47.7% min
Packaging
2g
Price
$110
Updated
2024/03/01
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Ruthenium(III) chloride Chemical Properties,Usage,Production

Chemical Properties

The trihydrate, RuCl3·3H2O, is the usual commercial form. Aqueous solutions of the trihydrate are a straw color in dilute solution and red-brown in concentrated solution. Ruthenium (III) chloride in solution apparently forms a variety of aquo- and hydroxy complexes.

Physical properties

Ruthenium(III) chloride is a reddish brown or black leafy crystal, easily deliquescent. It forms a dark red solution. Relative density 3.11, decomposed into monomers when it is higher than 500°C. It is insoluble in cold water and carbon disulfide. Insoluble in cold water and carbon disulfide, decompose in hot water, insoluble in ethanol, soluble in hydrochloric acid.

Uses

Ruthenium(III) chloride is widely used as a starting material of ruthenium complexes. It acts as a catalyst used in the oxidative cyclization of 1,7-dienes to oxepane diols. It is used in the hydroxylation of tertiary hydrocarbons in combination of periodate or bromate. It is involved as a catalyst in the synthesis of 2,3-pyridinedicarboxylic acid-13C3, 15N, where the unlabelled analog is an inhibitor of glucose synthesis.

Application

Ruthenium(III) trichloride is highly toxic and finds application in chemistry laboratories for technical analysis, particularly in the testing of sulfur trioxide. Ruthenium trichloride is by far the best starting material for the synthesis of compounds of the metal. Like osmium, ruthenium exhibits a wide range of oxidation states in its complexes (VIII to —II), and all of these may be reached from RuCl3 since, although it is stable, it can easily be oxidised or reduced. It is most commonly used in the hydrated form, this being soluble in many solvents, but for anhydrous or solid-state reactions β-RuCl3 is the best source.

Production Methods

RuCl3, is made by direct chlorination of the metal at 700 °C (1,292 °F). Two allotropic forms result. The trihydrate is made by evaporating an HCl solution of ruthenium (III) hydroxide to dryness or reducing ruthenium (VIII) oxide in a HCl solution.

Reactions

Ruthenium(III) chloride interacts with potassium iodide to produce an iodide precipitate, precipitates as ruthenium trisulphide when hydrogen sulphide is introduced into the solution, and can form the corresponding ammonia, cyanide, and nitrite complexes with ammonia, potassium cyanide, and potassium nitrite complexes, and is reduced to blue divalent ruthenium ions when interacting with sodium amalgam or titanium trichloride.

Safety Profile

Poison by intraperitoneal route. Incompatible with iron pentacarbonyl and zinc. When heated to decomposition it emits toxic fumes of RuO, and Cl-. See also RUTHENIUM COMPOUNDS.

Ruthenium(III) chloride Preparation Products And Raw materials

Raw materials

Sodium hypochlorite

Preparation Products

(3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one Dichloro(cycloocta-1,5-diene)ruthenium(II) (1R,2R)-N-BOC-1-AMINO-2-PHENYLCYCLOPROPANECARBOXYLIC ACID
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View Lastest Price from Ruthenium(III) chloride manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Ruthenium(III) chloride 10049-08-8
Price
US $990.00-800.00/ton
Min. Order
1ton
Purity
99%
Supply Ability
5000
Release date
2024-08-19
R&D Scientific Inc.
Product
Ruthenium(III) chloride 10049-08-8
Price
US $3600.00/Kg
Min. Order
1Kg
Purity
98
Supply Ability
500 Kg
Release date
2024-07-11
Hebei Weibang Biotechnology Co., Ltd
Product
Ruthenium(III) chloride 10049-08-8
Price
US $10.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100 mt
Release date
2021-08-26

10049-08-8, Ruthenium(III) chlorideRelated Search:

Titanous chloride Chromium(III) chloride Trichlorine nitride Antimony trichloride Ruthenium 2,3,5-Triphenyltetrazolium chloride Boron trichloride Tributyltin chloride Bismuth trichloride Ruthenium(III) chloride hydrate RUTHENIUM (III) IODIDE Ruthenium acetate Dichloro(p-cymene)ruthenium(II) dimer RUTHENIUM TRICHLORIDE TRIHYDRATE pure POTASSIUM CHLORIDE RUTHENATE POTASSIUM PENTACHLORONITROSYLRUTHENATE(II) AMMONIUM HEXACHLORORUTHENATE(IV) POTASSIUM HEXACHLORORUTHENATE(IV) Ruthenium Chloride

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  • anhydrous ruthenium trichloride
  • RUTHENIUM(III) CHLORIDE
  • Ruthenium(III) Chloride,>99.5%,Ru:47%
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  • 10049-08-8
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  • Catalysts for Organic Synthesis
  • Ru (Ruthenium) Compounds
  • Titanium Alkoxides, etc. (Homogeneous Catalysts)
  • Homogeneous Catalysts
  • Transition Metal Compounds
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  • Catalysis and Inorganic Chemistry
  • Classes of Metal Compounds
  • metal halide
  • chemical reaction,pharm,electronic,materials
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  • Homogeneous Catalysts
  • Catalysis and Inorganic Chemistry
  • Ru CatalystsMetal and Ceramic Science
  • Ruthenium
  • Ruthenium Salts
  • Salts
  • Ru (Ruthenium) Compounds