Tris(2-ethylhexyl) phosphate
- Product Name
- Tris(2-ethylhexyl) phosphate
- CAS No.
- 78-42-2
- Chemical Name
- Tris(2-ethylhexyl) phosphate
- Synonyms
- TOP;TRIOCTYL PHOSPHATE;TEHP;TRIS(2-ETHYLHEXYL) PHOSPHATE;TRI(2-;AmgardTOF;flexoltof;Flexol TOF;NCI-C54751;kronitextof
- CBNumber
- CB4670674
- Molecular Formula
- C24H51O4P
- Formula Weight
- 434.63
- MOL File
- 78-42-2.mol
Tris(2-ethylhexyl) phosphate Property
- Melting point:
- -70°C
- Boiling point:
- 215 °C4 mm Hg(lit.)
- Density
- 0.92 g/mL at 20 °C(lit.)
- vapor pressure
- 2.1 mm Hg ( 20 °C)
- refractive index
- n20/D 1.444(lit.)
- Flash point:
- >230 °F
- storage temp.
- Store below +30°C.
- solubility
- <0.001g/l
- form
- Liquid
- Specific Gravity
- 0.93
- color
- Colourless
- PH
- 7 (H2O, 20℃)
- Water Solubility
- <0.1 g/100 mL at 18 ºC
- BRN
- 1715839
- CAS DataBase Reference
- 78-42-2(CAS DataBase Reference)
- NIST Chemistry Reference
- 2-Ethylhexanol phosphate (3:1)(78-42-2)
- EPA Substance Registry System
- Tris(2-ethylhexyl) phosphate (78-42-2)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 38
- Safety Statements
- 23-43-24/25
- WGK Germany
- 2
- RTECS
- MP0770000
- Autoignition Temperature
- 370 °C
- TSCA
- Yes
- HS Code
- 29190090
- Hazardous Substances Data
- 78-42-2(Hazardous Substances Data)
- Toxicity
- LD50 orally in Rabbit: 37000 mg/kg LD50 dermal Rabbit 20000 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 8.21202
- Product name
- Tris(2-ethylhexyl) phosphate
- Purity
- for synthesis
- Packaging
- 100mL
- Price
- $41
- Updated
- 2024/03/01
- Product number
- 8.21202
- Product name
- Tris(2-ethylhexyl) phosphate
- Purity
- for synthesis
- Packaging
- 1L
- Price
- $122
- Updated
- 2024/03/01
- Product number
- 289922
- Product name
- Tris(2-ethylhexyl) phosphate
- Purity
- 97%
- Packaging
- 25ml
- Price
- $77.8
- Updated
- 2024/03/01
- Product number
- 289922
- Product name
- Tris(2-ethylhexyl) phosphate
- Purity
- 97%
- Packaging
- 500ml
- Price
- $87.4
- Updated
- 2024/03/01
- Product number
- P1022
- Product name
- Tris(2-ethylhexyl) Phosphate
- Purity
- >98.0%(GC)
- Packaging
- 25mL
- Price
- $24
- Updated
- 2024/03/01
Tris(2-ethylhexyl) phosphate Chemical Properties,Usage,Production
Chemical Properties
Tris(2-ethylhexyl) phosphate, a clear, viscous liquid, is used as a component of vinyl stabilizers, grease additives, and flame-proofing compositions; however, it is used primarily as a plasticizer for vinyl plastic and synthetic rubber compounds.
Tris(2-ethylhexyl) phosphate has been employed as a specialty flameretardant plasticizer for vinyl compositions where low temperature flexibility is critical, eg, in military tarpaulins. It can be included in blends with general purpose plasticizers such as phthalate esters to improve low temperature flexibility.
Uses
Tris(2-ethylhexyl) Phosphate is used as a phosphorous flame retardant. Used as a plasticizer in the preparation of a new potentiometric membrane sensor.
Uses
Solvent, antifoaming agent, plasticizer.
Definition
ChEBI: Tris(2-ethylhexyl) phosphate is a trialkyl phosphate.
General Description
Clear colorless to pale yellow liquid with a slight sharp odor. Insoluble in water; Soluble in alcohol, acetone, and ether. Combustible.
Reactivity Profile
Tris(2-ethylhexyl) phosphate is incompatible with oxidizing materials. Tris(2-ethylhexyl) phosphate may soften or deteriorate certain plastics and elastomers. Tris(2-ethylhexyl) phosphate is incompatible with cellulose acetate and cellulose acetate butyrate.
Hazard
Toxic by ingestion and inhalation.
Flammability and Explosibility
Not classified
Purification Methods
TEHP, in an equal volume of diethyl ether, is shaken with aqueous 5% HCl, and the organic phase is filtered to remove traces of pyridine (used as a solvent during manufacture) as its hydrochloride. This layer is shaken with aqueous Na2CO3, then water, and the ether is distilled off at room temperature. The ester is then filtered, dried for 12hours at 100o/15mm, and again filtered, then shaken intermittently for 2days with activated alumina (100g/L). It is decanted through a fine sintered-glass disc (with exclusion of moisture), and distilled under vacuum. [French & Muggleton J Chem Soc 5064 1957.] *Benzene can be used as a solvent (to give 0.4M solution) instead of ether. IR ( ): 1702, 1701, 481 and 478cm -1 [Bellamy & Becker J Chem Soc 475 1952]. The uranyl nitrate salt is purified by partial crystallisation from hexane [Siddall & Dukes J Am Chem Soc 81 790 1959, Siddall J Am Chem Soc 81 4176 1959]. [Beilstein 1 IV 1786.]
Tris(2-ethylhexyl) phosphate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Tris(2-ethylhexyl) phosphate manufacturers
- Product
- Trioctyl phosphate TOP 78-42-2
- Price
- US $99.00-35.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-05-10
- Product
- Tris(2-ethylhexyl) phosphate 78-42-2
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-29
- Product
- Tris(2-ethylhexyl) phosphate 78-42-2
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99.00%
- Supply Ability
- 20tons
- Release date
- 2023-09-13