FUSARIC ACID

Product Name: FUSARIC ACID
CAS No.: 536-69-6
Chemical Name: FUSARIC ACID
Synonyms: Fusaric;NSC 135043;FURASIC ACID;FUSARIC ACID;fusarinicacid;Fusarinic acid;FUSARIC ACID 99%;Fusaric acid,99%;Butylpicolinic acid;5-BUTYLPICOLINIC ACID
CBNumber: CB4689029
Molecular Formula: C10H13NO2
Formula Weight: 179.22
MOL File: 536-69-6.mol

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FUSARIC ACID Property

Melting point:: 96-100 °C
Boiling point:: 311.75°C (rough estimate)
Density: 1.1248 (rough estimate)
refractive index: 1.5710 (estimate)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
solubility: ethanol: 50 mg/mL, clear, faintly yellow
pka: 1.11±0.50(Predicted)
form: Crystalline Powder
color: Off-white to faint yellow
Merck: 14,4314
BRN: 125804
CAS DataBase Reference: 536-69-6(CAS DataBase Reference)
EPA Substance Registry System: 2-Pyridinecarboxylic acid, 5-butyl- (536-69-6)

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Safety

Hazard Codes: Xn
Risk Statements: 22
Safety Statements: 24/25
RIDADR: 2811
WGK Germany: 3
RTECS: US5625000
F: 10
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29333999
Hazardous Substances Data: 536-69-6(Hazardous Substances Data)
Toxicity: LD50 orally in mice: 230 mg/kg (Ishii)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: F6513
Product name: Fusaric acid
Purity: from
Packaging: 1g
Price: $258
Updated: 2021/12/16

Sigma-Aldrich

Product number: 55952
Product name: Fusaric acid
Purity: for HPLC derivatization, ≥99.0% (HPLC)
Packaging: 1g
Price: $289
Updated: 2021/12/16

Sigma-Aldrich

Product number: F6513
Product name: Fusaric acid
Purity: from
Packaging: 250mg
Price: $83.2
Updated: 2021/03/22

TCI Chemical

Product number: F0227
Product name: 5-Butylpyridine-2-carboxylic Acid
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $262
Updated: 2021/12/16

Cayman Chemical

Product number: 17876
Product name: Fusaric Acid
Purity: ≥98%
Packaging: 50mg
Price: $25
Updated: 2021/12/16

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FUSARIC ACID Chemical Properties,Usage,Production

Chemical Properties

off-white to faint yellowish crystalline powder

Uses

A medical research tool.

Uses

Fusaric acid may be used as a derivatizing reagent for the quantification of hydroxysteroids and dehydroepiandrosterone (DHEA)?and sulfated DHEA in biological samples using liquid chromatography electrospray-ionization-tandem mass spectrometry (LC/ESI-MS/MS) technique.

Definition

A mycotoxin and picolinic acid, that is an antibiotic and wilting agent that causes yellowing of infected plants.

Synthesis Reference(s)

The Journal of Organic Chemistry, 66, p. 605, 2001 DOI: 10.1021/jo0013554

General Description

Fusaric acid is a novel proton-affinitive derivatizing agent, having an ionization moiety and a hydrophobic moiety. It is commonly used for the derivatization of alcohols and phenols, by liquid chromatography coupled with electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS).

Hazard

Very toxic.

Safety Profile

A poison by ingestion, intraperitoneal, subcutaneous, and intravenous routes. When heated to decomposition it emits toxic fumes of NOx.

Purification Methods

Dissolve it in CHCl3, dry (Na2SO4), filter, evaporate and recrystallise the residue from 50 parts of pet ether (b 40-60o), CHCl3/pet ether or EtOAc, then sublime it in vacuo. The amide crystallises from MeOH with m 128.2-129.0o. The copper salt forms bluish violet crystals from H2O and has m 258-259o. [Hardegger & Nikles Helv Chim Acta 39 505 1956, Schreiber & Adam Chem Ber 93 1848 1960, NMR and MS: Tschesche & Führer Chem Ber 111 3500 1978, Beilstein 22 III/IV 764, 22/2 V 384.]

FUSARIC ACID Preparation Products And Raw materials

Raw materials

1,1-Dimethylhydrazine Acetonitrile Ethanol Potassium hydroxide 2-Chloroacrylonitrile Sodium chloride Formaldehyde Triethylamine Chloroform Sodium phosphate tribasic dodecahydrate Dimethylamine hydrochloride 1,4-Dioxane Diethyl ether Hydrochloric acid Dichloromethane Magnesium sulfate Sulfuric acid Sodium carbonate Hexanal

Preparation Products

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FUSARIC ACID Suppliers

Belgium 1 China 40 Europe 1 France 1 Germany 2 India 4 Japan 4 Slovakia 1 Switzerland 4 United Kingdom 4 United States 15 Global 77

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536-69-6, FUSARIC ACIDRelated Search:

2-Picolinic acid fusaric acid N,N-diethylaminoethylamide 2-Hydrazinopyridine FUSARIC ACID 3-Ethylpyridine PYRIDINIUM FORMATE 5-METHYLPICOLINIC ACID 3-BUTYLPYRIDINE RARECHEM AQ NN 0379 5-ETHYLPYRIDINE-2-CARBOXYLIC ACID 3-PROPYLPYRIDINE 5-BUTYL-2-METHYL-PYRIDINE 2-(Hydroxymethyl)pyridine CHEMBRDG-BB 4011741 2,5-Dimethylpyridine 5-Ethyl-2-methylpyridine 2-FORMYL-5-PICOLINE 2-Pyridinecarboxaldehyde

FUSARIC ACID

FURASIC ACID

5-N-BUTYL-2-PICOLINIC ACID

5-N-BUTYLPICOLINIC ACID

5-BUTYL-2-PYRIDINECARBOXYLIC ACID

5-BUTYLPICOLINIC ACID

5-BUTYLPYRIDINE-2-CARBOXYLIC ACID

5-butyl-2-pyridinecarboxylicaci

5-n-Butylpyridine-2-carboxylic acid

5-n-butylpyridine-2-carboxylicacid

Fusarinic acid

fusarinicacid

Picolinic acid, 5-butyl-

5-butylpyridine-3-carboxylic acid

5-Buthyl picolinic acid

FUSARIC ACID DOPAMINE B-HYDROXYLAS

FUSARIC ACID 99%

Fusaric

Butylpicolinic acid

fusaric acid from gibberella fujikuroi

5-Butylpicolinic acid, 5-Butylpyridine-2-carboxylic acid

5-Butyl-2-pyridinecarboxylic acid, 5-Butylpicolinic acid, 5-Butylpyridine-2-carboxylic acid

Fusaric acid,99%

Fusaric acid, 99% 1GR

Fusaric Acid 5-Butylpicolinic Acid

Fusaric acid≥ 99.9% (assay)

NSC 135043

5-Butylpyridine-2-carboxylicAcid&gt

2-Pyridinecarboxylic acid, 5-butyl-

5-Butylpyridine-2-carboxylicAci

536-69-6

Dopamine beta-hydroxylase inhibitor.

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