Reaction
ChemicalBook > CAS DataBase List > CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)

Reaction
Product Name
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
CAS No.
14871-41-1
Chemical Name
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
Synonyms
IrCl(CO)(PPh3)2;vaska's catalyst;carbonylchlorobis(triphenylphosphine)iridium;iridium(I);chloroiridium;VASKA'S COMPLEX;Carbonylchloro bis(triphenylphosphine);Dicarbonyl (triphenylphosphine) ruthenium;carbonylchlorobis(triphenylphosphine)-iridiu;CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
CBNumber
CB4709064
Molecular Formula
C37H30ClIrOP2
Formula Weight
780.25
MOL File
14871-41-1.mol
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CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Property

Melting point:
215°C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol
form 
crystal
color 
lemon yellow
λmax
385nm(lit.)
InChIKey
KMVALWICXMGTQO-UHFFFAOYSA-M
CAS DataBase Reference
14871-41-1(CAS DataBase Reference)
EPA Substance Registry System
Iridium, carbonylchlorobis(triphenylphosphine)- (14871-41-1)
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Safety

Risk Statements 
20/21/22
Safety Statements 
22-24/25
RIDADR 
UN2811
WGK Germany 
3
TSCA 
Yes
HS Code 
2931.90.6000
HazardClass 
6.1
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
C2252
Product name
Carbonylchlorobis(triphenylphosphine)iridium(I)
Purity
>95.0%(T)
Packaging
1g
Price
$396
Updated
2024/03/01
TCI Chemical
Product number
C2252
Product name
Carbonylchlorobis(triphenylphosphine)iridium(I)
Purity
>95.0%(T)
Packaging
200mg
Price
$112
Updated
2024/03/01
Alfa Aesar
Product number
039413
Product name
Carbonylchlorobis(triphenylphosphine)iridium(I)
Packaging
0.25g
Price
$67.4
Updated
2023/06/20
Alfa Aesar
Product number
039413
Product name
Carbonylchlorobis(triphenylphosphine)iridium(I)
Packaging
1g
Price
$215
Updated
2023/06/20
Strem Chemicals
Product number
77-0300
Product name
Chlorocarbonylbis(triphenylphosphine)iridium(I), 99% VASKA'S COMPLEX
Packaging
250mg
Price
$55
Updated
2024/03/01
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CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the intramolecular carbonylative [2+2+1] cycloaddition of allenynes.
  2. Catalyst for the selective hydrogenation of myrcene.
  3. Catalyst for silylation of ortho-functionalized aryl halides with hydrosilanes.
  4. Catalyst for synthesis of aldenamines from carboxamides by silane-reduction/dehydration under mild conditions.
  5. Hydrogen atom transfer catalyst for radical cyclizations.
  6. Complex for photocatalytic alkane dehydrogenation.
  7. Catalyst for chemoselective reductive nucleophilic addition to N-methoxyamides.
  8. Catalyst for chemoselective reductive alkynylation of tertiary amides.


Chemical Properties

GREEN FINE CRYSTALLINE POWDER

Uses

Carbonylchlorobis(triphenylphosphine)iridium(I) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

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CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
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View Lastest Price from CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) manufacturers

henan kanbei chemical co.,ltd
Product
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) 14871-41-1
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23
Career Henan Chemical Co
Product
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) 14871-41-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-07-02

14871-41-1, CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)Related Search:


  • CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
  • CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)IRIDIUMCARBONYL CHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CARBONYL CHLORIDE
  • IRIDIUM(I)BIS(TRIPHENYLPHOSPHINE)CARBONYL CHLORIDE
  • CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
  • VASKA'S COMPLEX
  • carbonylchlorobis(triphenylphosphine)-iridiu
  • carbonylchlorobis(triphenylphosphine)iridium
  • CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I ) CHLORIDE, 99.99%
  • Chlorocarbonylbis(triphenylphosphine)iridium(I),99%VASKA'SCOMPLEX
  • vaska's catalyst
  • Bis-(triphenylphosphino)-iridium carbonyl chloride
  • Chlorocarbonylbis(triphenylphosphine)iridium(I), Iridium(I)bis(triphenylphosphine)carbonyl chloride
  • Carbonylchlorobis(triphenylphosphine)iridium(Ⅰ)
  • Carbonylchloro bis(triphenylphosphine)iridium(I),99%
  • Carbonylchloro bis(triphenylphosphine)iridiuM(I),98%
  • Carbonylchloro bis(triphenylphosphine)
  • iridium(I)
  • Chlorocarbonylbis(triphenylphosphine)iridiuM(I) VASKA'S COMPLEX
  • IrCl(CO)(PPh3)2
  • Dicarbonyl (triphenylphosphine) ruthenium
  • Carbonylchlorobis(triphenylphosphine)iridium(I) &gt
  • IRIDIUM, CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)-
  • CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) ISO 9001:2015 REACH
  • chloroiridium
  • 14871-41-1
  • IrClCOPC6H532
  • C6H53P2IrClCO
  • C37H30ClIrOP2
  • IrClCOC6H53P2
  • C37H31ClIrOP2
  • Iridium
  • Catalysis and Inorganic Chemistry
  • Ir