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ChemicalBook > CAS DataBase List > CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)

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Product Name
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
CAS No.
14871-41-1
Chemical Name
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
Synonyms
IrCl(CO)(PPh3)2;vaska's catalyst;carbonylchlorobis(triphenylphosphine)iridium;iridium(I);chloroiridium;VASKA'S COMPLEX;Carbonylchloro bis(triphenylphosphine);Dicarbonyl (triphenylphosphine) ruthenium;carbonylchlorobis(triphenylphosphine)-iridiu;CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
CBNumber
CB4709064
Molecular Formula
C37H30ClIrOP2
Formula Weight
780.25
MOL File
14871-41-1.mol
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CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Property

Melting point:
215°C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol
form 
crystal
color 
lemon yellow
λmax
385nm(lit.)
InChIKey
KMVALWICXMGTQO-UHFFFAOYSA-M
CAS DataBase Reference
14871-41-1(CAS DataBase Reference)
EPA Substance Registry System
Iridium, carbonylchlorobis(triphenylphosphine)- (14871-41-1)
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Safety

Risk Statements 
20/21/22
Safety Statements 
22-24/25
RIDADR 
UN2811
WGK Germany 
3
TSCA 
Yes
HS Code 
2931.90.6000
HazardClass 
6.1
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
C2252
Product name
Carbonylchlorobis(triphenylphosphine)iridium(I)
Purity
>95.0%(T)
Packaging
1g
Price
$396
Updated
2024/03/01
TCI Chemical
Product number
C2252
Product name
Carbonylchlorobis(triphenylphosphine)iridium(I)
Purity
>95.0%(T)
Packaging
200mg
Price
$112
Updated
2024/03/01
Alfa Aesar
Product number
039413
Product name
Carbonylchlorobis(triphenylphosphine)iridium(I)
Packaging
0.25g
Price
$67.4
Updated
2023/06/20
Alfa Aesar
Product number
039413
Product name
Carbonylchlorobis(triphenylphosphine)iridium(I)
Packaging
1g
Price
$215
Updated
2023/06/20
Strem Chemicals
Product number
77-0300
Product name
Chlorocarbonylbis(triphenylphosphine)iridium(I), 99% VASKA'S COMPLEX
Packaging
250mg
Price
$55
Updated
2024/03/01
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CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the intramolecular carbonylative [2+2+1] cycloaddition of allenynes.
  2. Catalyst for the selective hydrogenation of myrcene.
  3. Catalyst for silylation of ortho-functionalized aryl halides with hydrosilanes.
  4. Catalyst for synthesis of aldenamines from carboxamides by silane-reduction/dehydration under mild conditions.
  5. Hydrogen atom transfer catalyst for radical cyclizations.
  6. Complex for photocatalytic alkane dehydrogenation.
  7. Catalyst for chemoselective reductive nucleophilic addition to N-methoxyamides.
  8. Catalyst for chemoselective reductive alkynylation of tertiary amides.


Chemical Properties

GREEN FINE CRYSTALLINE POWDER

Uses

Carbonylchlorobis(triphenylphosphine)iridium(I) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

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CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Suppliers

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View Lastest Price from CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) manufacturers

henan kanbei chemical co.,ltd
Product
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) 14871-41-1
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23
Career Henan Chemical Co
Product
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) 14871-41-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-07-02

14871-41-1, CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)Related Search:


  • CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
  • CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)IRIDIUMCARBONYL CHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CARBONYL CHLORIDE
  • IRIDIUM(I)BIS(TRIPHENYLPHOSPHINE)CARBONYL CHLORIDE
  • CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
  • VASKA'S COMPLEX
  • carbonylchlorobis(triphenylphosphine)-iridiu
  • carbonylchlorobis(triphenylphosphine)iridium
  • CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I ) CHLORIDE, 99.99%
  • Chlorocarbonylbis(triphenylphosphine)iridium(I),99%VASKA'SCOMPLEX
  • vaska's catalyst
  • Bis-(triphenylphosphino)-iridium carbonyl chloride
  • Chlorocarbonylbis(triphenylphosphine)iridium(I), Iridium(I)bis(triphenylphosphine)carbonyl chloride
  • Carbonylchlorobis(triphenylphosphine)iridium(Ⅰ)
  • Carbonylchloro bis(triphenylphosphine)iridium(I),99%
  • Carbonylchloro bis(triphenylphosphine)iridiuM(I),98%
  • Carbonylchloro bis(triphenylphosphine)
  • iridium(I)
  • Chlorocarbonylbis(triphenylphosphine)iridiuM(I) VASKA'S COMPLEX
  • IrCl(CO)(PPh3)2
  • Dicarbonyl (triphenylphosphine) ruthenium
  • Carbonylchlorobis(triphenylphosphine)iridium(I) &gt
  • IRIDIUM, CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)-
  • CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) ISO 9001:2015 REACH
  • chloroiridium
  • 14871-41-1
  • IrClCOPC6H532
  • C6H53P2IrClCO
  • C37H30ClIrOP2
  • IrClCOC6H53P2
  • C37H31ClIrOP2
  • Iridium
  • Catalysis and Inorganic Chemistry
  • Ir