ChemicalBook > CAS DataBase List > ISOPROPENYLMAGNESIUM BROMIDE

ISOPROPENYLMAGNESIUM BROMIDE

Product Name
ISOPROPENYLMAGNESIUM BROMIDE
CAS No.
13291-18-4
Chemical Name
ISOPROPENYLMAGNESIUM BROMIDE
Synonyms
IsopropenyL;Bromoisopropenylmagnesium;ISOPROPENYLMAGNESIUM BROMIDE;1-Methylvinylmagnesium bromide;1-Methylethenylmagnesium bromide;bromo(1-methylethenyl)-Magnesium;(1-Methylethenyl)magnesium bromide;IsopropenylMagnesiuM broMide soluti;Isopropenylmagnesium bromide(1M THF);isopropenylmagnesium bromide solution
CBNumber
CB4783309
Molecular Formula
C3H5BrMg
Formula Weight
145.28
MOL File
13291-18-4.mol
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ISOPROPENYLMAGNESIUM BROMIDE Property

Melting point:
102-104 °C
Boiling point:
67 °C
Density 
0.94 g/mL at 20 °C
Flash point:
−36 °F
storage temp. 
2-8°C
form 
Crystalline Powder
color 
White to yellow to orange
BRN 
3587297
InChIKey
LFTYALBVGVNGLI-UHFFFAOYSA-M
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Safety

Hazard Codes 
F,C
Risk Statements 
11-14/15-34-40-37-19-14
Safety Statements 
26-30-36/37/39-43-45-7/8-16
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
1
F 
1-3-10-34
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
419567
Product name
Isopropenylmagnesium bromide solution
Purity
0.5 M in THF
Packaging
100ml
Price
$190
Updated
2024/03/01
Sigma-Aldrich
Product number
419567
Product name
Isopropenylmagnesium bromide solution
Purity
0.5 M in THF
Packaging
800ml
Price
$352
Updated
2024/03/01
Sigma-Aldrich
Product number
772836
Product name
Isopropenylmagnesium bromide solution
Purity
1.0 M in 2-methyltetrahydrofuran
Packaging
25ml
Price
$138
Updated
2024/03/01
Sigma-Aldrich
Product number
772836
Product name
Isopropenylmagnesium bromide solution
Purity
1.0 M in 2-methyltetrahydrofuran
Packaging
100ml
Price
$209
Updated
2024/03/01
GFS CHEMICALS
Product number
17523
Product name
ISOPROPENYLMAGNESIUMBROMIDE,0.5MinTETRAHYDROFURAN
Packaging
1L
Price
$180.6
Updated
2021/12/16
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ISOPROPENYLMAGNESIUM BROMIDE Chemical Properties,Usage,Production

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-(?)-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol.

General Description

This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.

ISOPROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Isopropenylboronic acid pinacol ester
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ISOPROPENYLMAGNESIUM BROMIDE Suppliers

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View Lastest Price from ISOPROPENYLMAGNESIUM BROMIDE manufacturers

Hebei Duling International Trade Co. LTD
Product
Isopropenylmagnesium bromide(1M THF) 13291-18-4
Price
US $43.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000 tons
Release date
2023-01-29
Career Henan Chemical Co
Product
isopropenylmagnesium bromide 13291-18-4
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-25

13291-18-4, ISOPROPENYLMAGNESIUM BROMIDERelated Search:

ISOBUTYLMAGNESIUM CHLORIDE ISOPROPYLMAGNESIUM BROMIDE Vinyl isopropyl ether Isopropenylboronic acid pinacol ester Isopropenyloxytris(triMethylsilyl)silane Isofraxidin Isopropyl alcohol LANTHANUM ISOPROPOXIDE BARIUM ISOPROPOXIDE (-)-DIOP METHYLZINC CHLORIDE Benzylmagnesium chloride 4-FLUOROPHENYLMAGNESIUM BROMIDE Di-n-butylmagnesium 3-FLUOROPHENYLMAGNESIUM BROMIDE Cyclopropylmagnesium bromide CYCLOPENTYLMAGNESIUM BROMIDE SEC-BUTYLMAGNESIUM BROMIDE

  • Isopropenylmagnesium bromide, 0.5 M solution in THF, HySeal
  • ISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURAN
  • ISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURAN
  • ISOPROPENYLMAGNESIUM BROMIDE 0.5 M THF
  • Isopropenylmagnesium bromide( 1.0 M solution in THF)
  • IsopropenyL
  • Isopropenylmagnesium bromide 1M solution in tetrahydrofuran
  • ISOPROPENYLMAGNESIUM BROMIDE
  • isopropenylmagnesium bromide solution
  • ISOPROPENYLMAGNESIUM BROMIDE SOLUTION, ~ 0.5 M IN THF
  • ISOPROPENYLMAGNESIUM BROMIDE, 0.5M SOLUT ION IN TETRAHYDROFURAN
  • ISOPROPENYLMAGNESIUM BROMIDE in ETHYL ETHER
  • ISOPROPENYLMAGNESIUM BROMIDE in TETRAHYDROFURAN
  • (1-Methylethenyl)magnesium bromide
  • 1-Methylethenylmagnesium bromide
  • 1-Methylvinylmagnesium bromide
  • Bromoisopropenylmagnesium
  • Isopropenylmagnesium bromide,0.5M solution inTHF
  • Isopropenylmagnesium bromide, 0.5M solution in THF, AcroSeal§3
  • Isopropenylmagnesium bromide solution 0.5 in THF
  • Isopropenylmagnesium bromide, 0.5M solution in THF, AcroSeal
  • Iso Propenyl MagnesiuM BroMide0.5M In Thf
  • IsopropenylMagnesiuM broMide soluti
  • IsopropenylMagnesiuM broMide, 0.5 M solution in THF, SpcSeal
  • Isopropenylmagnesium bromide, 0.5 M solution in THF, J&KSeal
  • IsopropenylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal
  • Isopropenylmagnesium bromide(1M THF)
  • Bromo(isopropenyl)magnesium Solution (0.5M in THF)
  • Isopropenylmagnesium bromide (0.5M in THF) FandaSeal
  • Magnesium, bromo(1-methylethenyl)- (9CI)
  • bromo(1-methylethenyl)-Magnesium
  • Iso Propenyl Magnesium Bromide .5M in THF
  • Iso Propenyl Magnesium Bromide 1.M in 2-Methyl THF
  • ISOPROPENYL MAGNESIUM BROMIDE 0.5M THF/1.0M &2M THF
  • ISOPROPENYLMAGNESIUM BROMIDE 0.5M IN THF/1.0M IN 2Me THF
  • Iso Propenyl Magnesium Bromide 1.5M in 2-Methyl THF
  • 13291-18-4
  • 13219-18-4
  • CH2CCH3MgBr
  • H2CCCH3MgCl
  • Alkenyl
  • Grignard Reagents
  • Organometallic Reagents
  • Grignard Reagent
  • Alkenyl
  • Grignard Reagents
  • Organometallic Reagents