Dimethyl maleate
- Product Name
- Dimethyl maleate
- CAS No.
- 624-48-6
- Chemical Name
- Dimethyl maleate
- Synonyms
- DMM;METHYL MALEATE;eate;Sipomer DMM;Dimethyl meleate;Dimethyl (Z)-butenedioate;(Z)-Dimethyl 2-butenedioate;sipomerdmm;Sipomer DMM 6;Maleic acid. b
- CBNumber
- CB4854003
- Molecular Formula
- C6H8O4
- Formula Weight
- 144.13
- MOL File
- 624-48-6.mol
Dimethyl maleate Property
- Melting point:
- -19°C
- Boiling point:
- 204-205 °C(lit.)
- Density
- 1.152 g/mL at 25 °C(lit.)
- vapor pressure
- 48Pa at 25℃
- refractive index
- n20/D 1.441(lit.)
- Flash point:
- 196 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- water: soluble77.9g/L at 20°C
- form
- Liquid
- color
- Clear
- Odor
- mild char. odor
- Water Solubility
- Miscible with water.
- BRN
- 471705
- Stability:
- Stable. Combustible. Incompatible with acids, bases, reducing agents, strong oxidizing agents.
- LogP
- 0.52 at 35℃
- CAS DataBase Reference
- 624-48-6(CAS DataBase Reference)
- NIST Chemistry Reference
- 2-Butenedioic acid (Z)-, dimethyl ester(624-48-6)
- EPA Substance Registry System
- 2-Butenedioic acid (2Z)-, dimethyl ester (624-48-6)
Safety
- Hazard Codes
- Xn,C
- Risk Statements
- 21/22-36/37/38-43-37-34-22
- Safety Statements
- 26-36/37-23-45-36/37/39
- RIDADR
- UN 2810 6.1/PG 3
- WGK Germany
- 1
- RTECS
- EM6300000
- TSCA
- Yes
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 29171990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H335May cause respiratory irritation
H373May cause damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P314Get medical advice/attention if you feel unwell.
N-Bromosuccinimide Price
- Product number
- 238198
- Product name
- Dimethyl maleate
- Purity
- 96%
- Packaging
- 100g
- Price
- $33.5
- Updated
- 2024/03/01
- Product number
- 238198
- Product name
- Dimethyl maleate
- Purity
- 96%
- Packaging
- 1kg
- Price
- $165
- Updated
- 2024/03/01
- Product number
- M0012
- Product name
- Dimethyl Maleate
- Purity
- >97.0%(GC)
- Packaging
- 25mL
- Price
- $31
- Updated
- 2024/03/01
- Product number
- M0012
- Product name
- Dimethyl Maleate
- Purity
- >97.0%(GC)
- Packaging
- 500mL
- Price
- $61
- Updated
- 2024/03/01
- Product number
- A18944
- Product name
- Dimethyl maleate, 96%
- Packaging
- 100g
- Price
- $29.2
- Updated
- 2024/03/01
Dimethyl maleate Chemical Properties,Usage,Production
Chemical Properties
colourless liquid
Uses
Dimethyl maleate is widely used in the plastics and chemical industries and as a vaporization retardant of insecticides.
Uses
Dimethyl maleate is acts as a dienophile involved in ultrasonic irradiation promoted Diels-Alder reaction with substituted furans. It is widely used as an intermediate and additive for pharmaceuticals, copolymers, pigments, plastics, paints, adhesives and agrochemicals. As an internal modifier, it increases the glass transition temperature of styrene or vinyl chloride polymer. It plays a vital role to improve the hardness and toughness of polymer films such as copolymers of vinyl acetate.
Definition
ChEBI: Dimethyl maleate is a maleate ester resulting from the formal condensation of both carboxy groups of maleic acid with methanol. It is commonly used as a dienophile for Diels-Alder-type cycloaddition reactions in organic synthesis. It is a maleate ester, a diester and a methyl ester. It derives from a methanol.
Preparation
Dimethyl maleate can be synthesized from maleic anhydride and methanol, with sulfuric acid acting as acid catalyst, via a nucleophilic acyl substitution for the monomethyl ester, followed by a Fischer esterification reaction for the dimethyl ester.
General Description
Dimethyl maleate (DMM) is a reactive dienophile and undergoes ultrasonic irradiation promoted Diels-Alder reaction with substituted furans. Mesoporous siliceous SBA-15-supported Cu catalyzed gas phase hydrogenolysis of DMM to 1,4-butanediol (BDO) has been reported. Aluminium chloride has been reported to accelerate the Diels-Alder reaction of DMM and anthracene. DMM can be synthesized by the esterification of maleic anhydride with sulfuric acid and methanol.
Flammability and Explosibility
Non flammable
Dimethyl maleate Preparation Products And Raw materials
Raw materials
Preparation Products
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- ProdList
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View Lastest Price from Dimethyl maleate manufacturers
- Product
- Dimethyl maleate 624-48-6
- Price
- US $50.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 5000kg/week
- Release date
- 2024-05-20
- Product
- Dimethyl maleate 624-48-6
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99.8%
- Supply Ability
- 50000KG/month
- Release date
- 2024-10-23
- Product
- Dimethyl maleate 624-48-6
- Price
- US $9.10/KG
- Min. Order
- 1KG
- Purity
- 99.%
- Supply Ability
- 10 ton
- Release date
- 2024-08-20