Acryloyl chloride

Product Name: Acryloyl chloride
CAS No.: 814-68-6
Chemical Name: Acryloyl chloride
Synonyms: prop-2-enoyl chloride;oyL;2-PROPENOYL CHLORIDE;acrylyl chloride;ACRYLIC ACID CHLORIDE;Propenoyl chloride;chloridkyselinyakrylove;Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole;propenoylchloride;ACRYLOYL CHLORIDE
CBNumber: CB4854427
Molecular Formula: C3H3ClO
Formula Weight: 90.51
MOL File: 814-68-6.mol

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Acryloyl chloride Property

Melting point:: 76 °C(Solv: isopropyl ether (108-20-3))
Boiling point:: 72-76 °C (lit.)
Density: 1.114 g/mL at 25 °C (lit.)
vapor density: >1 (vs air)
vapor pressure: 1.93 psi ( 20 °C)
refractive index: n20/D 1.435(lit.)
Flash point:: 61 °F
storage temp.: 2-8°C
solubility: Chloroform (Soluble), Methanol (Slightly)
form: Oil
color: Colourless to Pale Yellow
Water Solubility: Miscible with water.
Sensitive: Moisture & Light Sensitive
BRN: 635744
Exposure limits: ACGIH: TWA 5 mg/m3 (Skin)
NIOSH: TWA 5 mg/m3
Stability:: Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.
InChIKey: HFBMWMNUJJDEQZ-UHFFFAOYSA-N
CAS DataBase Reference: 814-68-6(CAS DataBase Reference)
NIST Chemistry Reference: 2-Propenoyl chloride(814-68-6)
EPA Substance Registry System: Acrylyl chloride (814-68-6)

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Safety

Hazard Codes: F,T+
Risk Statements: 11-14-26-34
Safety Statements: 16-26-28-36/37/39-45-7/9
RIDADR: UN 3383 6.1/PG 1
WGK Germany: 3
RTECS: AT7350000
F: 8-10
TSCA: Yes
HazardClass: 3
PackingGroup: II
HS Code: 29161980
Hazardous Substances Data: 814-68-6(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H290May be corrosive to metals

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 549797
Product name: Acryloyl chloride
Purity: 97.0%, contains <210ppm MEHQ as stabilizer
Packaging: 5g
Price: $76.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 549797
Product name: Acryloyl chloride
Purity: 97.0%, contains <210ppm MEHQ as stabilizer
Packaging: 500g
Price: $646
Updated: 2024/03/01

Alfa Aesar

Product number: L10363
Product name: Acryloyl chloride, 96%, stab. with 400ppm phenothiazine
Packaging: 10g
Price: $40.5
Updated: 2021/12/16

Alfa Aesar

Product number: L10363
Product name: Acryloyl chloride, 96%, stab. with 400ppm phenothiazine
Packaging: 50g
Price: $60.6
Updated: 2021/12/16

Sigma-Aldrich

Product number: A24109
Product name: Acryloyl chloride
Purity: ≥97%, contains ~400ppm phenothiazine as stabilizer
Packaging: 5g
Price: $66.7
Updated: 2024/03/01

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Acryloyl chloride Chemical Properties,Usage,Production

Chemical Properties

Acryloyl chloride is a highly flammable, polymerizable, and toxic (inhalation), light yellow liquid. A lacrimator.

Uses

Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 72, 1950 DOI: 10.1021/ja01157a020

General Description

A liquid. Boiling point 75°C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture.

Air & Water Reactions

Polymerizes readily upon exposure to oxygen in the air. Reacts exothermically with water to give hydrochloric acid and acrylic acid.

Reactivity Profile

Acrylyl chloride is incompatible with strong oxidizing agents, alcohols, amines, alkali. Polymerizes readily upon exposure to oxygen. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Fire Hazard

When heated to decomposition, Acrylyl chloride emits toxic fumes of chlorides. Decomposes in water.

Potential Exposure

May be used as a monomer in preparation of specialty polymers or as a chemical intermediate

Shipping

UN3383 Poisonous Toxic by inhalation liquid, flammable, n.o.s. with an LC50 # 200 mL/m3 and saturated vapor concentration ≥500 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone A. UN2924 Flammable liquids, corrosive, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 8-Corrosive material, Technical Name Required

Incompatibilities

Use MEHQ (monomethyl ether of hydroquinone) as an inhibitor. Incompatible with oxidizers, polymerizes on contact with oxygen; alcohols, amines, alkalis. Reacts violently with water, releasing hydrochloric acid and acrylic acid. Attacks some metals.

Acryloyl chloride Preparation Products And Raw materials

Raw materials

Copper(I) chloride

Preparation Products

N-Isopropylacrylamide N-ACRYLOXYSUCCINIMIDE N-NONYL ACRYLATE 1,4-Diacryloylpiperazine 1,4-BUTANEDIOL DIACRYLATE Atracurium besylate

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Acryloyl chloride Suppliers

China 370 Europe 4 France 2 Germany 4 India 17 Japan 4 Slovakia 1 Switzerland 1 United Kingdom 8 United States 24 Global 435

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View Lastest Price from Acryloyl chloride manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: Acryloyl chloride 814-68-6
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-21

Hebei Chuanghai Biotechnology Co,.LTD

Product: Acryloyl Chloride 814-68-6
Price: US $10.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 10 ton
Release date: 2024-08-21

Hebei Kingfiner Technology Development Co.Ltd

Product: Acryloyl chloride 814-68-6
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 500000kg
Release date: 2023-08-03

814-68-6, Acryloyl chlorideRelated Search:

Choline chloride Ammonium chloride Benzyl chloride Acrylamide Calcium chloride Mepiquat chloride Sodium chloride Polyvinyl chloride Tetramethyl Ibandronate methyl N-(3-methoxy-3-oxopropyl)-N-methyl-beta-alaninate Ibandronate sodium monohydrate Trisodium phosphate N-Methylpentylamine b-Alanine, N-methyl-N-pentyl- Phosphonic acid, disodium salt N-Methyl-N-pentyl-beta-alanine methyl ester Ibandronate Impurity 1(Ibandronate EP Impurity B) Pamidronic acid Acrylic Acid Chloride Propenoyl Chloride

chloridkyselinyakrylove

Propenoyl chloride

propenoylchloride

Acryloyl chloride, stabilized with 400 ppM phenothiazine

Acryloyl chloride, 97%, stabilized with p-Hydroxyanisole

Acryloyl chloride, 97%, stabilized with 400 ppm phenothiazine

Acryloyl chloride, 97%, stabilized with 400 ppm p-Hydroxyanisole

Acrylyl chloride manufacturer kf-wang(at)kf-chem.com

oyL

ACRYLOYL CHLORIDE, 96%, STABILIZED

ACRYLOYL CHLORIDE STAB. WITH 2 6-DI-TER

ACRYLOYL CHLORIDE, STAB.

Acryloylchloride,96%

Acryloyl chloride, 96%, stab. with 400ppm phenothiazine

Acryloyl Chloride (stabilized with MEHQ)

Acryloyl Chloride (stabilized with Phenothiazine)

Acryloyl Chloride, Stab. With 400Ppm Phenothiazine

ACRYLOYL CHLORIDE, 97.0%

Acryloyl chloride,2-Propenoyl chloride

acrylyl chloride

ACRYLOYL CHLORIDE

ACRYLIC ACID CHLORIDE

ACRYLOYL CHLORIDE (STABILISED WITH PHENO

2-PROPENOYL CHLORIDE

Chlorid kyseliny akrylove

Acryloyl Chloride (stabilized with Phenothiazine)&gt

Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole

Ibandronate Sodium Impurity J

prop-2-enoyl chloride

Ibandronate Impurity 17

Acryloyl chloride ISO 9001：2015 REACH

Acrylonyl chloride,

HYPERICUM PERFORATUM OIL 68917-49-7

Acryloyl chloride (6CI, 8CI)

Acryloyl chloride,99.5%

Acryloyl Chloride, stabilized with Phenothiazine), ≥ 95.0%

814-68-6

CH2CHCOCl

C3H3OCl

Building Blocks

Carbonyl Compounds

Acid Halides

Organic Building Blocks

ACID CHLORIDES

Industrial/Fine Chemicals

Halogen compounds

814-68-6