N,N'-Di-(4-methyl-phenyl)-benzidine

Uses

Product Name: N,N'-Di-(4-methyl-phenyl)-benzidine
CAS No.: 10311-61-2
Chemical Name: N,N'-Di-(4-methyl-phenyl)-benzidine
Synonyms: K0067;]-4,4'-diamine;N4,N4'-Di-p-toL;N,N'-Di-p-tolylbenzidine;N,N'-Di-p-tolylbenzidine>N,N'-Bis(4-methylphenyl)benzidine;N'-Di-(4-methyl-phenyl)-benzidine;N,N'-Di-(4-methyl-phenyl)-benzidine;N,N′-Di-p-tolylbenzidine, CAS 10311-61-2;N4,N4'-Di-p-tolyl-[1,1'-biphenyl]-4,4'-diamine
CBNumber: CB4972039
Molecular Formula: C26H24N2
Formula Weight: 364.48
MOL File: 10311-61-2.mol

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N,N'-Di-(4-methyl-phenyl)-benzidine Property

Melting point:: 240 °C
Boiling point:: 562.5±45.0 °C(Predicted)
Density: 1.141
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: powder to crystal
pka: 1.83±0.50(Predicted)
color: White to Light yellow

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Safety

HS Code: 2921.59.8090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TCI Chemical

Product number: D3567
Product name: N,N'-Di-p-tolylbenzidine
Purity: >98.0%(GC)
Packaging: 1g
Price: $28
Updated: 2025/07/31

TCI Chemical

Product number: D3567
Product name: N,N'-Di-p-tolylbenzidine
Purity: >98.0%(GC)
Packaging: 5g
Price: $47
Updated: 2025/07/31

TRC

Product number: D494758
Product name: N,N''-Di-p-tolylbenzidine
Packaging: 50mg
Price: $60
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD62303
Product name: N,N'-Di-p-tolylbenzidine
Packaging: 250mg
Price: $57.5
Updated: 2021/12/16

AK Scientific

Product number: 7215AJ
Product name: N4,N4'-Di-p-tolyl-[1,1'-biphenyl]-4,4'-diamine
Packaging: 250mg
Price: $79
Updated: 2021/12/16

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N,N'-Di-(4-methyl-phenyl)-benzidine Chemical Properties,Usage,Production

Uses

N,N'-di-p-tolylbenzidine is used as a research compound and is a commonly used hole transport layer material in organic electroluminescent devices.

Synthesis

3001-15-8

106-49-0

10311-61-2

Example 2 The target compound N,N'-di-p-tolylbenzidine (structural formula (2)-p) was synthesized according to the following reaction scheme. The steps were as follows:(c1) 4,4'-diiodo-1,1'-biphenyl (35 g, 86 mmol), p-toluidine (92 g, 86 mmol), copper powder (2.7 g, 43 mmol) and potassium carbonate (12 g, 86 mmol) were added to a reactor, and the reaction was stirred for 24 hours at 170 °C. After completion of the reaction, tetrahydrofuran (400 ml) was added to the reaction mixture and the insoluble material was removed by filtration. The filtrate was concentrated under reduced pressure and the residue obtained was washed sequentially with ethyl acetate, hexane and acetonitrile. Finally, the resulting crystals were dried to give (c2) N,N'-bis(4-methylphenyl)benzidine (13 g, 40% yield).

References

[1] Organometallics, 2018, vol. 37, # 6, p. 989 - 1000
[2] Patent: US2007/149815, 2007, A1. Location in patent: Page/Page column 10

N,N'-Di-(4-methyl-phenyl)-benzidine Preparation Products And Raw materials

Raw materials

Preparation Products

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N,N'-Di-(4-methyl-phenyl)-benzidine Suppliers

Americas 1 China 106 Europe 1 India 2 Japan 1 United Kingdom 1 United States 8 Global 120

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

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View Lastest Price from N,N'-Di-(4-methyl-phenyl)-benzidine manufacturers

Career Henan Chemical Co

Product: N,N'-Di-(4-methyl-phenyl)-benzidine 10311-61-2
Price: US $2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: ask
Release date: 2018-12-20

10311-61-2, N,N'-Di-(4-methyl-phenyl)-benzidineRelated Search:

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N,N'-Bis(4-methylphenyl)benzidine

N,N'-Di-p-tolylbenzidine

N,N'-Bis(4-methylphenyl)-[1,1'-biphenyl]-4,4'-diamine

N,N'-Di-(4-methyl-phenyl)-benzidine

N'-Di-(4-methyl-phenyl)-benzidine

K0067

N,N'-Di-p-tolylbenzidine&gt

N4,N4'-Di-p-toL

[1,1'-Biphenyl]-4,4'-diamine, N4,N4'-bis(4-methylphenyl)-

]-4,4'-diamine

N4,N4'-Di-p-tolyl-[1,1'-biphenyl]-4,4'-diamine

N,N′-Di-p-tolylbenzidine, CAS 10311-61-2

10311-61-2

C26H24N2