ChemicalBook > CAS DataBase List > 2-Chloro-1-methylpyridinium iodide

2-Chloro-1-methylpyridinium iodide

Product Name
2-Chloro-1-methylpyridinium iodide
CAS No.
14338-32-0
Chemical Name
2-Chloro-1-methylpyridinium iodide
Synonyms
CMPI;Mukaiyama Reagent;2-chloro-1-Methylpyridin-1-iuM iodide;2-CHLORO-N-METHYLPYRIDINIUM IODIDE;2-Chloro-1-methylpyridinium iodide,97%;2-CHLORO-1-METHYLPYRIDINIUM IODIDE FOR S;2-Chloro-1-methylpyr;Epinastine Impurity 26 Iodide;Epinastine Impurity 17 Iodide;Tributyl Phosphate Impurity 10
CBNumber
CB5102028
Molecular Formula
C6H7ClIN
Formula Weight
255.48
MOL File
14338-32-0.mol
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2-Chloro-1-methylpyridinium iodide Property

Melting point:
200 °C (dec.) (lit.)
Density 
1.7949 (estimate)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Crystalline Powder and/or Chunks
color 
Yellow
Water Solubility 
soluble
Sensitive 
Moisture & Light Sensitive
Merck 
14,6301
BRN 
3572320
Exposure limits
ACGIH: TWA 0.01 ppm
InChIKey
ABFPKTQEQNICFT-UHFFFAOYSA-M
CAS DataBase Reference
14338-32-0(CAS DataBase Reference)
EPA Substance Registry System
2-Chloro-1-methylpyridinium iodide (14338-32-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-24/25-36
RIDADR 
1759
WGK Germany 
3
F 
8-21
HazardClass 
8
PackingGroup 
III
HS Code 
29333999
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
198005
Product name
2-Chloro-1-methylpyridinium iodide
Purity
97%
Packaging
10g
Price
$37.8
Updated
2024/03/01
Sigma-Aldrich
Product number
198005
Product name
2-Chloro-1-methylpyridinium iodide
Purity
97%
Packaging
25g
Price
$59.3
Updated
2024/03/01
TCI Chemical
Product number
C0903
Product name
2-Chloro-1-methylpyridinium Iodide
Purity
>98.0%(T)
Packaging
25g
Price
$93
Updated
2024/03/01
Alfa Aesar
Product number
A12820
Product name
2-Chloro-1-methylpyridinium iodide, 97%
Packaging
25g
Price
$53.3
Updated
2024/03/01
Alfa Aesar
Product number
A12820
Product name
2-Chloro-1-methylpyridinium iodide, 97%
Packaging
100g
Price
$150
Updated
2024/03/01
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2-Chloro-1-methylpyridinium iodide Chemical Properties,Usage,Production

Chemical Properties

yellow crystalline solid

Uses

2-Chloro-1-methylpyridinium iodide is a reagent in a wide variety of dehydrative coupling reactions. It is also used to form carboxylate esters from acids and alcohols, carboxamides from acids and amines, lactones from -hydroxy acids and carbodiimides from N,N-disubstituted thioureas.

Uses

Condensation reagent for the synthesis of esters and ketenes, and for the kinetic resolution of carboxylic acids and alcohols.

General Description

2-Chloro-1-methylpyridinium iodide (Mukaiyama reagent), is a commonly used reagent in organic synthesis for the activation of the hydroxy group of alcohols and carboxylic acids. It is used to synthesize derivatives of esters, lactones, amides, lactams, and ketenes from the corresponding carboxylic acids. It is also used as an efficient coupling reagent in the synthesis of peptides because of its low toxicity, simple reaction conditions, and also less expensive than EDC.

Purification Methods

Purify it by dissolving in EtOH and adding dry Et2O. The solid is washed with Me2CO and dried at 20o/0.35mm. Store it in the dark. Attempted recrystallisation from Me2CO/EtOH/pet ether (b 40-60o) causes some exchange of the Cl substituent by I. The picrate has m 106-107o, and the perchlorate has m 212-213o. [Jones et al. J Am Chem Soc 111 1157 1989, UV and solvolysis: Barlin & Benbow J Chem Soc, Perkin Trans 2 790 1974, Beilstein 20/5 V 405.]

2-Chloro-1-methylpyridinium iodide Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Chloro-1-methylpyridinium iodide Suppliers

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View Lastest Price from 2-Chloro-1-methylpyridinium iodide manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
2-Chloro-1-methylpyridinium iodide 14338-32-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-05
Hebei Yanxi Chemical Co., Ltd.
Product
2-Chloro-1-methylpyridinium iodide 14338-32-0
Price
US $20.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-24
Hebei Mojin Biotechnology Co., Ltd
Product
2-Chloro-1-methylpyridinium iodide 14338-32-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-12

14338-32-0, 2-Chloro-1-methylpyridinium iodideRelated Search:

2,4,6-Collidine Methyl propyl carbonate 2-Chloro-5-chloromethylpyridine Cetylpyridinium chloride monohydrate 2,6-Lutidine Azamethiphos Propidium iodide BISMUTH(III) IODIDE Potassium iodide 2,5-Dimethylpyridine 5-HYDROXY-2(1H)-QUINOLINONE 6-BROMO-BENZO[B]THIOPHENE 1,3-DIMETHYLIMIDAZOLIUM METHYLSULFATE 1,3-DIMETHYLIMIDAZOLIUM DIMETHYL PHOSPHATE 1-Ethyl-3-methylimidazolium bromide 1-ETHYL-3-METHYLIMIDAZOLIUM IODIDE 1,3-diMethyliMidazoliuM bis((trifluoroMethyl)sulfonyl)iMide EPINASTINE HYDROCHLORIDE

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  • 14338-32-0
  • C6H7CllN
  • C6H7ClIN
  • C6H7ClNI
  • C6H7NClI
  • Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Pyridines
  • Building Blocks
  • Pyridinium Compounds
  • Condensation & Active Esterification
  • Reagents for Oligosaccharide Synthesis
  • Coupling Reactions (Peptide Synthesis)
  • Peptide Synthesis
  • Pyridinium Compounds
  • Reagents for Oligosaccharide Synthesis
  • Synthetic Organic Chemistry
  • C6Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Pyridines
  • Heterocyclic Compounds
  • Biochemistry
  • Condensation & Active Esterification