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5-Fluoro-2-Methoxybenzyl alcohol

Product Name
5-Fluoro-2-Methoxybenzyl alcohol
CAS No.
426831-32-5
Chemical Name
5-Fluoro-2-Methoxybenzyl alcohol
Synonyms
(5-Fluoro-2-methoxyphenyl);5-Fluoro-3-methoxybenzyl alcohol;5-FLUORO-2-METHOXYBENZYL ALCOHOL;Benzenemethanol, 5-fluoro-2-methoxy-;Benzenemethanol, 5-fluoro-2-methoxy- (9CI)
CBNumber
CB51065694
Molecular Formula
C8H9FO2
Formula Weight
156.15
MOL File
426831-32-5.mol
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5-Fluoro-2-Methoxybenzyl alcohol Property

Boiling point:
242℃
Density 
1.187
Flash point:
119℃
storage temp. 
Sealed in dry,Room Temperature
pka
14.09±0.10(Predicted)
Appearance
White to off-white Solid
InChI
InChI=1S/C8H9FO2/c1-11-8-3-2-7(9)4-6(8)5-10/h2-4,10H,5H2,1H3
InChIKey
NJDNHGOIOZXFCB-UHFFFAOYSA-N
SMILES
C1(CO)=CC(F)=CC=C1OC
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Safety

HS Code 
2909498090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
F597470
Product name
5-Fluoro-2-methoxybenzyl alcohol
Packaging
100mg
Price
$45
Updated
2021/12/16
Apolloscientific
Product number
PC7735
Product name
5-Fluoro-2-methoxybenzyl alcohol
Packaging
1g
Price
$12
Updated
2021/12/16
SynQuest Laboratories
Product number
2607-3-52
Product name
5-Fluoro-2-methoxybenzyl alcohol
Packaging
1g
Price
$20
Updated
2021/12/16
Apolloscientific
Product number
PC7735
Product name
5-Fluoro-2-methoxybenzyl alcohol
Packaging
5g
Price
$38
Updated
2021/12/16
SynQuest Laboratories
Product number
2607-3-52
Product name
5-Fluoro-2-methoxybenzyl alcohol
Packaging
5G
Price
$61
Updated
2021/12/16
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5-Fluoro-2-Methoxybenzyl alcohol Chemical Properties,Usage,Production

Synthesis

19415-51-1

426831-32-5

To a methanolic solution of 5-fluoro-2-methoxybenzaldehyde (11.093 g, 1 eq., purchased from Aldrich Chemical Company) was added sodium borohydride (7.515 g, 2.7 eq.) in batches at -10 °C and under nitrogen protection. The reaction solution was slowly warmed to room temperature and stirred for 30 minutes before the methanol solvent was removed by reduced pressure distillation and replaced with dichloromethane. The reaction mixture was poured into ice water and extracted with dichloromethane. The organic phases were combined, dried with magnesium sulfate and concentrated under reduced pressure to remove the solvent to give 5-fluoro-2-methoxybenzyl alcohol as a colorless oil (9.794 g, 87% yield).1H NMR (300 MHz, CDCl3) δ: 2.58 (m, 1H), 3.81 (s, 3H), 4.63 (d, 2H, J=6.3 Hz), 6.78 (dd, 1H J=8.9 and 4.3 Hz), 6.94 (td, 1H, J=8.5 and 3.1 Hz), 7.04 (dd, 1H, J=8.7 and 3.1 Hz).

References

[1] Patent: EP1216225, 2005, B1. Location in patent: Page/Page column 39
[2] Patent: WO2004/18441, 2004, A1. Location in patent: Page 22
[3] Patent: WO2005/20975, 2005, A2. Location in patent: Page/Page column 126
[4] Patent: WO2005/20976, 2005, A2. Location in patent: Page/Page column 129
[5] Patent: WO2005/60949, 2005, A2. Location in patent: Page/Page column 132; 277

5-Fluoro-2-Methoxybenzyl alcohol Preparation Products And Raw materials

Raw materials

Preparation Products

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5-Fluoro-2-Methoxybenzyl alcohol Suppliers

China 60 Europe 1 India 3 Switzerland 1 United Kingdom 5 United States 6 Global 76
Achemica
Tel
--
Fax
--
Email
contact@achemica.com
Country
Switzerland
ProdList
6155
Advantage
50
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View Lastest Price from 5-Fluoro-2-Methoxybenzyl alcohol manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Benzenemethanol, 5-fluoro-2-methoxy- (9CI) 426831-32-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
Benzenemethanol, 5-fluoro-2-methoxy- (9CI) 426831-32-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09
Career Henan Chemical Co
Product
Benzenemethanol, 5-fluoro-2-methoxy- (9CI) 426831-32-5
Price
US $6.60/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg -1000kg
Release date
2020-01-02

426831-32-5, 5-Fluoro-2-Methoxybenzyl alcoholRelated Search:

5-FLUORO-2-METHOXYBENZONITRILE 2,3-DIFLUORO-4-METHOXYBENZOIC ACID 5-FLUORO-2-METHOXYBENZOIC ACID 6-Fluoro-4H-1,3-benzodioxine-8-carbaldehyde 6-FLUORO-4H-1,3-BENZODIOXIN-8-YL ISOCYANATE 8-(CHLOROMETHYL)-6-FLUORO-4H-1,3-BENZODIOXINE 2-ACETOXY-5-FLUOROBENZYLACETATE 2',7'-DIFLUOROFLUORESCEIN 6-FLUORO-4-HYDROXY-2-OXO-2H-CHROMENE-3-CARBALDEHYDE 6-FLUORO-4H-1,3-BENZODIOXINE-8-CARBOXYLIC ACID (6-FLUORO-4H-1,3-BENZODIOXIN-8-YL)METHANOL 4-ETHOXY-6-FLUOROCOUMARIN 6-FLUORO-4-HYDROXYCOUMARIN 8-(CHLOROMETHYL)-6-FLUORO-2-PHENYL-4H-1,3-BENZODIOXINE 5-Fluoro-2-Methoxybenzyl alcohol 2,3-DIFLUORO-6-METHOXYBENZYL ALCOHOL (6-FLUORO-4H-1,3-BENZODIOXIN-8-YL)METHYLAMINE, 97 CARBOXY-DFFDA, SE

  • Benzenemethanol, 5-fluoro-2-methoxy- (9CI)
  • (5-Fluoro-2-methoxyphenyl)
  • Benzenemethanol, 5-fluoro-2-methoxy-
  • 5-FLUORO-2-METHOXYBENZYL ALCOHOL
  • 5-Fluoro-3-methoxybenzyl alcohol
  • 426831-32-5
  • HALIDE
  • Alcohols
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Fluorine Compounds