TERT-BUTYLMAGNESIUM CHLORIDE Property

Melting point:

-108℃ (Tetrahydrofuran)

Density 

0.931 g/mL at 25 °C

Flash point:

34 °F

storage temp. 

2-8°C

form 

Liquid

color 

Clear brown to dark brown

Water Solubility 

Miscible with alcohol and water.

Sensitive 

Air & Moisture Sensitive

BRN 

3535403

InChIKey

ZDRJSYVHDMFHSC-UHFFFAOYSA-M

CAS DataBase Reference

677-22-5(CAS DataBase Reference)

Safety

Hazard Codes 

F+,C,F

Risk Statements 

12-14/15-19-22-34-66-67-15-11-14-37-17-40

Safety Statements 

9-16-26-29-33-36/37/39-43-45

RIDADR 

UN 3399 4.3/PG 1

WGK Germany 

1

F 

1-3-10

HazardClass 

4.3

PackingGroup 

I

HS Code 

29319090

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H224Extremely flammable liquid and vapour

H225Highly Flammable liquid and vapour

H250Catches fire spontaneously if exposed to air

H260In contact with water releases flammable gases which may ignite spontaneously

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H351Suspected of causing cancer

H361Suspected of damaging fertility or the unborn child

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

P335+P334Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P405Store locked up.

P422Store contents under …

TERT-BUTYLMAGNESIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

clear faint grey to grey, grey-brown or light

Uses

tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides.