ChemicalBook > CAS DataBase List > TERT-BUTYLMAGNESIUM CHLORIDE

TERT-BUTYLMAGNESIUM CHLORIDE

Product Name
TERT-BUTYLMAGNESIUM CHLORIDE
CAS No.
677-22-5
Chemical Name
TERT-BUTYLMAGNESIUM CHLORIDE
Synonyms
tert-butylmagnesium chloride solution;tert-Butylmagnesium chloride [1.0 M solution in THF];solution~1MinTHF;tert-butylMagnesiuM;tert-Butylchloromagnesium;T-BUTYLMAGNESIUM CHLORIDE;ert-Butylmagnesiumchloride;TERT-BUTYLMAGNESIUM CHLORIDE;tert-Butylmagnesium chloride, 2M;Tertiary butyl MagnesiuM chloride
CBNumber
CB5116195
Molecular Formula
C4H9ClMg
Formula Weight
116.87
MOL File
677-22-5.mol
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TERT-BUTYLMAGNESIUM CHLORIDE Property

Melting point:
-108℃ (Tetrahydrofuran)
Density 
0.931 g/mL at 25 °C
Flash point:
34 °F
storage temp. 
2-8°C
form 
Liquid
color 
Clear brown to dark brown
Water Solubility 
Miscible with alcohol and water.
Sensitive 
Air & Moisture Sensitive
BRN 
3535403
InChIKey
ZDRJSYVHDMFHSC-UHFFFAOYSA-M
CAS DataBase Reference
677-22-5(CAS DataBase Reference)
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Safety

Hazard Codes 
F+,C,F
Risk Statements 
12-14/15-19-22-34-66-67-15-11-14-37-17-40
Safety Statements 
9-16-26-29-33-36/37/39-43-45
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
1
F 
1-3-10
HazardClass 
4.3
PackingGroup 
I
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H224Extremely flammable liquid and vapour

H225Highly Flammable liquid and vapour

H250Catches fire spontaneously if exposed to air

H260In contact with water releases flammable gases which may ignite spontaneously

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H351Suspected of causing cancer

H361Suspected of damaging fertility or the unborn child

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

P335+P334Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P405Store locked up.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
364649
Product name
tert-Butylmagnesium chloride solution
Purity
1.0?M in THF
Packaging
4X25ML
Price
$105
Updated
2024/03/01
Sigma-Aldrich
Product number
224499
Product name
tert-Butylmagnesium chloride solution
Purity
2.0M in diethyl ether
Packaging
100ml
Price
$75.9
Updated
2024/03/01
Sigma-Aldrich
Product number
224499
Product name
tert-Butylmagnesium chloride solution
Purity
2.0M in diethyl ether
Packaging
800ml
Price
$364
Updated
2024/03/01
TCI Chemical
Product number
B1147
Product name
tert-Butylmagnesium Chloride (26% in Ethyl Ether, ca. 2mol/L)
Packaging
250g
Price
$157
Updated
2024/03/01
TCI Chemical
Product number
B1148
Product name
tert-Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L)
Packaging
250g
Price
$94
Updated
2024/03/01
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TERT-BUTYLMAGNESIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

clear faint grey to grey, grey-brown or light

Uses

tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides.

TERT-BUTYLMAGNESIUM CHLORIDE Preparation Products And Raw materials

Raw materials

2-Chloro-2-methylpropane Tetrahydrofuran Magnesium

Preparation Products

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TERT-BUTYLMAGNESIUM CHLORIDE Suppliers

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View Lastest Price from TERT-BUTYLMAGNESIUM CHLORIDE manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
TERT-BUTYLMAGNESIUM CHLORIDE 677-22-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99.91%
Supply Ability
200000
Release date
2024-04-15
Hebei Mojin Biotechnology Co., Ltd
Product
TERT-BUTYLMAGNESIUM CHLORIDE 677-22-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-06-20
Hebei Guanlang Biotechnology Co., Ltd.
Product
TERT-BUTYLMAGNESIUM CHLORIDE 677-22-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100
Release date
2023-03-24

677-22-5, TERT-BUTYLMAGNESIUM CHLORIDERelated Search:

Butylmagnesium chloride 3-FLUOROPHENYLMAGNESIUM BROMIDE ISOBUTYLMAGNESIUM BROMIDE SEC-BUTYLMAGNESIUM CHLORIDE Isopropylmagnesium chloride lithium chloride complex CYCLOPENTYLMAGNESIUM CHLORIDE ISOBUTYLMAGNESIUM CHLORIDE PENTYLMAGNESIUM CHLORIDE Di-n-butylmagnesium O-TOLYLMAGNESIUM BROMIDE Diethyl ether Magnesium chloride hydrochloric acid in ethanol ISOPROPYLMAGNESIUM CHLORIDE TERT-BUTYLMAGNESIUM CHLORIDE Magnesium hydride Magnesium nitrate hexahydrate Methylmagnesium chloride

  • tert-Butylmagnesium chloride, 1M in MeTHF
  • tert-Butylmagnesium chloride [1.0 M solution in THF]
  • tert-Butylmagnesium chloride, 1,7M solution in diethyl ether, AcroSeal§3
  • tert-Butylmagnesium chloride, 1.7M solution in THF, AcroSeal
  • tert-Butylmagnesium chloride, 1.7M solution in diethyl ether, AcroSeal
  • tert-ButylMagnesiuM chloride ,1.0 M in tetrahydrofuran
  • tert-butylMagnesiuM
  • (1,1-Dimethylethyl)magnesium chloride
  • Magnesium, chloro(1,1-dimethylethyl)-
  • tert-butylmagnesium chloride solution
  • TERT-BUTYLMAGNESIUM CHLORIDE: (26% IN ETHYL ETHER, CA. 2MOL/L)
  • TERT-BUTYLMAGNESIUM CHLORIDE: (26% IN TETRAHYDROFURAN, CA. 2MOL/L
  • tert-Butylmagnesium chloride, 1,7M solution in diethyl ether
  • tert-Butylmagnesium chloride, 1.7M solution in THF
  • tert-BUTYL MAGNESIUM CHLORIDE, 1 M in TETRAHYDROFURAN
  • tert-Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L)
  • tert-Butylmagnesium chloride1.7M solution in THFAcroSeal§3
  • Chloro(1,1-dimethylethyl)magnesium
  • tert-Butylchloromagnesium
  • Tert-butylmagnesium chloride, 2.0 M solution in 2-MeTHF, J&KSeal
  • t-Butylmagnesium Chloride 1.0 M In Tetrahydrofuran
  • solution~1MinTHF
  • tert-Butylmagnesium chloride, 1.7 M solution in THF, J&KSeal
  • tert-Butylmagnesium chloride solution(1.0 M solution in THF)
  • tert-BUTYLMAGNESIUM CHLORIDE, 1 M, in TETRAHYDROFURANtert-BUTYLMAGNESIUM CHLORIDE, 1 M, in TETRAHYDROFURANtert-BUTYLMAGNESIUM CHLORIDE, 1 M, in TETRAHYDROFURANtert-BUTYLMAGNESIUM CHLORIDE, 1 M, in TETRAHYDROFURAN
  • tert-ButylmagnesiumChloride(inTetrahydrofuran)
  • t-Butylmagnesium chloride 1M solution in THF
  • t-Butylmagnesium chloride 2M solution in DEE
  • t-Butylmagnesium chloride 1.5M solution in DEE
  • tert-ButylMagnesiuM chloride, 1.0 M solution in THF, J&KSeal
  • tert-ButylMagnesiuM chloride solution 1.0 M in THF
  • tert-ButylMagnesiuM chloride solution 2.0 M in diethyl ether
  • tert-ButylMagnesiuM chloride, 1.0 M solution in THF, SpcSeal
  • tert-ButylMagnesiuM chloride, 1.7 M solution in 2-Methyltetrahydrofuran, SpcSeal
  • Tertiary butyl MagnesiuM chloride
  • Tert Butylmagnesium chloride tetrahydrofuran 1M
  • TERT-BUTYLMAGNESIUM CHLORIDE 2.0M &
  • TERT-BUTYLMAGNESIUM CHLORIDE, 1.0M SOLUT ION IN TETRAHYDROFURAN
  • TERT-BUTYLMAGNESIUM CHLORIDE, 2.0M SOLUT ION IN DIETHYL ETHER
  • TERT-BUTYLMAGNESIUM CHLORIDE SOLUTION, ~1 M IN THF
  • TERT-BUTYLMAGNESIUM CHLORIDE SOLUTION, ~ 2 M IN DIETHYL ETH.
  • TERT-BUTYLMAGNESIUM CHLORIDE SOLUTION, ~ 20% IN THF
  • t-Butylmagnesium Chloride 1.0 M In Butyl Diglyme
  • tert-Butylmagnesium chloride, 1.0 M in 2-MeTHF
  • tert-Butylmagnesium chloride, 1.0 M in THF
  • T-BUTYLMAGNESIUM CHLORIDE
  • TERT-BUTYLMAGNESIUM CHLORIDE
  • t-Butylmagnesium Chloride, Tetrahydrofuran Solution (abt. 1mol/l)
  • t-Butylmagnesium Chloride Tetrahydrofuran Solution
  • tert-Butylmagnesium Chloride (2.0 M in Diethyl Ether)
  • tert-Butylmagnesium chloride solution 2.0 M in THF
  • tert-Butylmagnesium chloride tetrahydrofuran solution
  • tert-Butylmagnesium chloride (6CI)
  • Tert-BUTYLMAGNESIUM CHLORIDE 2.0M IN THF
  • tert-butylmagnesiumchloride 2% (in THF)
  • tert-butylmagnesiumchloride 2% (in Diethylether)
  • n-Butylmagnesiumbromide 2% (in THF)
  • n-Butylmagnesiumbromide 2% (in Diethylether)