ChemicalBook > CAS DataBase List > (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
Reaction- Product Name
- (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
- CAS No.
- 246231-79-8
- Chemical Name
- (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
- Synonyms
- JOSIPHOS SL-J011-2;JOSIPHOS SL-J011-1;(S)-1-[(R)-2-[BIS[4-(TRIFLUO;(R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-C...;(R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-CF3-phenyl)phosphine;(R)-1-{(S)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}-ethyldi-tert.-;(R)-1-{(R)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine;(R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosph;(R)-1-[(S)-2-Di-(4-trifluoromethylphenylphos-phino)ferrocenyl]-ethyl-di-tert-butylphosphine;(R)-(-)-1-[(S)-2-(BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYL-DI-T-BUTYLPHOSPHINE
- CBNumber
- CB5120257
- Molecular Formula
- C34H32F6FeP2
- Formula Weight
- 672.41
- MOL File
- 246231-79-8.mol
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(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Property
- alpha
- -352° ±10° (c 0.5, CHCl3)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- orange
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 26-0650
- Product name
- (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
- Packaging
- 100mg
- Price
- $107
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 26-0650
- Product name
- (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
- Packaging
- 500mg
- Price
- $375
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 26-0650
- Product name
- (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
- Packaging
- 2g
- Price
- $1031
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 26-0650
- Product name
- (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
- Packaging
- 10g
- Price
- $4379
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- ING0001274
- Product name
- (R)-(-)-1-[(S)-2-(BIS(4-TRIFLUOROMETHYLPHENYL) PHOSPHINO]FERROCENYL]ETHYL-DI-TERT-BUTYLPHOSPHINE
- Purity
- 95.00%
- Packaging
- 500MG
- Price
- $914.17
- Updated
- 2021/12/16
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(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties,Usage,Production
Reaction
- Ferrocenylphosphine ligands of the type cpFecp(PR2)(*CH(CH3)PR'2) are a class of asymmetric ligands developed at Solvias in Basel, Switzerland. Ligands of this type are currently used industrially in the stereoselective synthesis of commercial products. A unique feature of these bidentate ligands is the presence of a fixed phosphine moiety and a stereogenic, functionalized side chain, which can be easily modified to accommodate electronic and steric requirements. Based on a versatile synthetic procedure starting with optically active ferrocenes of the type cpFecp(PR2)(*CH(CH3)X) [X = OAc or NR2], a variety of donor atoms can be introduced into the side chain. These ferrocene based phosphine ligands have wide application in the stereoselective hydrogenation of substituted acetamidoacrylates, enol acetates, β-ketoesters and simple alkenes.
- Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.
- Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides.
- Asymmetric hydrogenation of ketones and phosphinylketimines.
- Michael addition of Grignard reagents to α,α-unsaturated esters and thioesters.
- Boration of α,α-unsaturated esters and nitriles.
- Reaction of aryl halides with ammonia.
- Cu-catalyzed reduction of activated C=C bonds with PMHS.
- Regio- and enantioselective hydroboration of vinyl arenes.
- Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.
- 1,2-Migrations in Pd-catalyzed Negishi couplings with JosiPhos ligands.
- Catalyst for the homodimerization of ketoketenes.
- Ligand for the Rh catalyzed synthesis of lactones.
- Ligand for the Cu-catalyzed synthesis of syn and anti γ-amino alcohols.
Chemical Properties
Orange powder
General Description
sold in collaboration with Solvias AG
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials
Raw materials
Preparation Products
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(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Suppliers
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View Lastest Price from (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE manufacturers
XINXIANG RUNYU MATERIAL CO., LTD.
- Product
- (R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosphine 246231-79-8
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500kg
- Release date
- 2023-11-01
Career Henan Chemical Co
- Product
- (R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosphine 246231-79-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- Min98%
- Supply Ability
- g/kg/ton
- Release date
- 2020-01-08
246231-79-8, (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINERelated Search:
(S)-1-{(R)-2-[DI(2-FURYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT.-BUTYLPHOSPHINE
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
(R)-(S)-JOSIPHOS
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
Ferrocene
Phosphine
1,3-Cyclopentadiene
T-BUTYLPHOSPHINE
Di-tert-butylphosphine
DI-T-BUTYL(I-PROPYL)PHOSPHINE
TERT-BUTYLDIISOPROPYLPHOSPHINE
BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE
(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE