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ChemicalBook > CAS DataBase List > (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE

(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE

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Product Name
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
CAS No.
246231-79-8
Chemical Name
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
Synonyms
JOSIPHOS SL-J011-2;JOSIPHOS SL-J011-1;(S)-1-[(R)-2-[BIS[4-(TRIFLUO;(R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-C...;(R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-CF3-phenyl)phosphine;(R)-1-{(S)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}-ethyldi-tert.-;(R)-1-{(R)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine;(R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosph;(R)-1-[(S)-2-Di-(4-trifluoromethylphenylphos-phino)ferrocenyl]-ethyl-di-tert-butylphosphine;(R)-(-)-1-[(S)-2-(BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYL-DI-T-BUTYLPHOSPHINE
CBNumber
CB5120257
Molecular Formula
C34H32F6FeP2
Formula Weight
672.41
MOL File
246231-79-8.mol
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(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Property

alpha 
-352° ±10° (c 0.5, CHCl3)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
orange
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Safety

Risk Statements 
36/37/38
Safety Statements 
24/25
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
26-0650
Product name
(R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
Packaging
100mg
Price
$107
Updated
2024/03/01
Strem Chemicals
Product number
26-0650
Product name
(R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
Packaging
500mg
Price
$375
Updated
2024/03/01
Strem Chemicals
Product number
26-0650
Product name
(R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
Packaging
2g
Price
$1031
Updated
2024/03/01
Strem Chemicals
Product number
26-0650
Product name
(R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
Packaging
10g
Price
$4379
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0001274
Product name
(R)-(-)-1-[(S)-2-(BIS(4-TRIFLUOROMETHYLPHENYL) PHOSPHINO]FERROCENYL]ETHYL-DI-TERT-BUTYLPHOSPHINE
Purity
95.00%
Packaging
500MG
Price
$914.17
Updated
2021/12/16
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(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties,Usage,Production

Reaction

  1. Ferrocenylphosphine ligands of the type cpFecp(PR2)(*CH(CH3)PR'2) are a class of asymmetric ligands developed at Solvias in Basel, Switzerland. Ligands of this type are currently used industrially in the stereoselective synthesis of commercial products. A unique feature of these bidentate ligands is the presence of a fixed phosphine moiety and a stereogenic, functionalized side chain, which can be easily modified to accommodate electronic and steric requirements. Based on a versatile synthetic procedure starting with optically active ferrocenes of the type cpFecp(PR2)(*CH(CH3)X) [X = OAc or NR2], a variety of donor atoms can be introduced into the side chain. These ferrocene based phosphine ligands have wide application in the stereoselective hydrogenation of substituted acetamidoacrylates, enol acetates, β-ketoesters and simple alkenes.
  2. Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.
  3. Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides.
  4. Asymmetric hydrogenation of ketones and phosphinylketimines.
  5. Michael addition of Grignard reagents to α,α-unsaturated esters and thioesters.
  6. Boration of α,α-unsaturated esters and nitriles.
  7. Reaction of aryl halides with ammonia.
  8. Cu-catalyzed reduction of activated C=C bonds with PMHS.
  9. Regio- and enantioselective hydroboration of vinyl arenes.
  10. Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.
  11. 1,2-Migrations in Pd-catalyzed Negishi couplings with JosiPhos ligands.
  12. Catalyst for the homodimerization of ketoketenes.
  13. Ligand for the Rh catalyzed synthesis of lactones.
  14. Ligand for the Cu-catalyzed synthesis of syn and anti γ-amino alcohols.


Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Suppliers

J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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China
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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Daicel Chiral Technologies (China)CO.,LTD
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Xinxiang Runyu Material Co., Ltd.
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Sigma-Aldrich
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View Lastest Price from (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.
Product
(R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosphine 246231-79-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500kg
Release date
2023-11-01
Career Henan Chemical Co
Product
(R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosphine 246231-79-8
Price
US $1.00/KG
Min. Order
1KG
Purity
Min98%
Supply Ability
g/kg/ton
Release date
2020-01-08

246231-79-8, (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINERelated Search:


  • JOSIPHOS SL-J011-1
  • JOSIPHOS SL-J011-2
  • (S,S)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
  • (S)-1-[(R)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
  • (R,R)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
  • (R)-(-)-1-[(S)-2-(BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYL-DI-T-BUTYLPHOSPHINE
  • (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
  • (R)-(-)-1-[(S)-(2-DI-TERT-BUTYLPHOSPHINO)FERROCENYL]ETHYLDI-(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE
  • "Josiphos SL-J011-1/ (R)-1-{(SP)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldi-tert-butylphosphine"
  • Josiphos SL-J011-1 / (R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosphine
  • (R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-CF3-phenyl)phosphine
  • (R)-1-{(S)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}-ethyldi-tert.-
  • (R)-(-)-1-{(S)-2-(Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-<br />di-t-butylphosphine, min. 97%
  • (R)-(-)-1-{(S)-2-(Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine,min.97%
  • (r,r)-1-[1-(di-tert-butylphosphino)ethyl]-2-{bis[4-(trifluoromethyl)phenyl]phosphino}ferrocene (acc to cas)
  • (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl) phosphino]ferrocenyl} ethyl-di-t-butylphosphine, min. 97%
  • (R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosph
  • (R)-1-[(S)-2-Di-(4-trifluoromethylphenylphos-phino)ferrocenyl]-ethyl-di-tert-butylphosphine
  • (R)-1-[(S)-2-Di-(4-trifluoroMethylphenylphos-phino)ferrocenyl]-ethyl-di-tert-butylphosphine, Manufactured by Solvias AG
  • (R)-1-{(SP)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldi-tert-butylphosphine >=97%
  • (R)-(-)-1-{(SP)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldi-tert-butylphosphine
  • (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-[bis[4-(trifluoromethyl)phenyl]phosphino]ferrocene
  • (S)-1-[(R)-2-[BIS[4-(TRIFLUO
  • Ferrocene, 1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-[bis[4-(trifluoromethyl)phenyl]phosphino]-, (2R)-
  • (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%,99%ee
  • (R)-1-{(R)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine
  • (R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-C...
  • (R)-(-)-1-{(Sp)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldi-t-butylphosphine
  • (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-[bis[4-(trifluoromethyl)phenyl]phosphino]ferrocene (ACI)
  • 246231-79-8
  • C34H38F6FeP2
  • Solvias Ligands
  • Privileged Ligands
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Josiphos Series
  • Chiral Phosphine
  • Ferrocene Series
  • metallocene