ChemicalBook > CAS DataBase List > (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
Reaction- Product Name
- (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
- CAS No.
- 155830-69-6
- Chemical Name
- (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
- Synonyms
- Josiphos SL-J002;(R)-(-)-[(S)-2-(D;JOSIPHOS SL-J002-1;(R)-(S)-PPF-P(tBu)2;-2-(Diphenylphosphino);ferrocenyl]ethyldi-tert-butylphosphine;(R)1 (1S)2(DIPHENYLPHOSPHINO)FERROCENYL&;(R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph;(R)-(-)-[(S)-2-(Diphenylphosphino(ferrocenyl]ethyldi-t-butyl...;-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
- CBNumber
- CB7229824
- Molecular Formula
- C32H40FeP2
- Formula Weight
- 542.45
- MOL File
- 155830-69-6.mol
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(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Property
- Melting point:
- 218-220°C (dec.)
- alpha
- -412° ±15° (c 0.5, CHCl3)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Chloroform, Methanol
- form
- Powder
- color
- Orange
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Safety
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 24/25
- WGK Germany
- 3
- F
- 10
- HS Code
- 29319090
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 88719
- Product name
- (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
- Purity
- ≥97%
- Packaging
- 1g
- Price
- $264.8
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 88719
- Product name
- (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
- Purity
- ≥97%
- Packaging
- 5g
- Price
- $1112
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 26-1200
- Product name
- (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
- Packaging
- 100mg
- Price
- $107
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 26-1200
- Product name
- (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
- Packaging
- 500mg
- Price
- $375
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 88719
- Product name
- (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
- Purity
- ≥97%
- Packaging
- 100mg
- Price
- $120
- Updated
- 2024/03/01
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(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties,Usage,Production
Reaction
- Ligand for Palladium-catalyzed amination of aryl halides
- Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene
- Ligand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids
- Ligand for Copper-catalyzed asymmetric 1,4-hydrosilylations of α,β-unsaturated esters
- Ligand for Ruthenium-catalyzed asymmetric hydrogenation of N-sulfonated-α-dehydroamino acids
- Ligand for Rhodium-catalyzed asymmetric hydrogenation of enamines
- Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates
- Ligand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides
- Ligand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a C-C bond
Chemical Properties
Orange powder
Uses
It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.
General Description
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-tBu) is a chiral ferrocenyl diphosphine ligand.
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials
Raw materials
Acetic anhydride
2-Chloro-2-methylpropane
Potassium carbonate
Chlorodiphenylphosphine
Phosphorus trichloride
(R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE
Ethyl acetate
Lithium Aluminum Hydride
Hydrochloric acid
Dichloromethane
Acetic acid
Magnesium
n-Butyllithium
Preparation Products
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(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Suppliers
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- 166-166-37336996 15690792173
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View Lastest Price from (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE manufacturers
XINXIANG RUNYU MATERIAL CO., LTD.
- Product
- (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE 155830-69-6
- Price
- US $0.00-0.00/g
- Min. Order
- 1KG
- Purity
- 0.97
- Supply Ability
- 500kg
- Release date
- 2021-11-30
Zhengzhou HQ Material CO.,LTD.
- Product
- (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine 155830-69-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99
- Supply Ability
- 10
- Release date
- 2021-09-22
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine 155830-69-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
155830-69-6, (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINERelated Search:
(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
(R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
(R)-(S)-JOSIPHOS
1,3-BIS(DIMETHYLPHOSPHINO)PROPANE
T-BUTYLPHOSPHINE
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
Di-tert-butylphosphine
(S)-1-[(1R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
TRIISOPROPYLPHOSPHINE
Ferrocene
DI-T-BUTYL(I-PROPYL)PHOSPHINE
(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
TERT-BUTYLDIISOPROPYLPHOSPHINE
(R)-1-[(S)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-1-[(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE