Reaction
ChemicalBook > CAS DataBase List > (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE

Reaction
Product Name
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
CAS No.
155830-69-6
Chemical Name
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
Synonyms
Josiphos SL-J002;(R)-(-)-[(S)-2-(D;JOSIPHOS SL-J002-1;(R)-(S)-PPF-P(tBu)2;-2-(Diphenylphosphino);ferrocenyl]ethyldi-tert-butylphosphine;(R)1 (1S)2(DIPHENYLPHOSPHINO)FERROCENYL&;(R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph;(R)-(-)-[(S)-2-(Diphenylphosphino(ferrocenyl]ethyldi-t-butyl...;2-(1-(Di-tert-Butylphosphino)ethyl)-1-(diphenylphosphino)ferrocene
CBNumber
CB7229824
Molecular Formula
C32H40FeP2
Formula Weight
542.45
MOL File
155830-69-6.mol
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(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Property

Melting point:
218-220°C (dec.)
alpha 
-412° ±15° (c 0.5, CHCl3)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform, Methanol
form 
Powder
color 
Orange
InChI
InChI=1/C27H35P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-21H,1-7H3;1-5H;/t21-;;/s3
InChIKey
STAGMXYQPGLLTD-MGIYCFTINA-N
SMILES
P(C1=CC=CC=C1)(C1=CC=CC=C1)[C]1[CH][CH][CH][C]1[C@@H](C)P(C(C)(C)C)C(C)(C)C.[CH]1[CH][CH][CH][CH]1.[Fe] |&1:18,r,^1:13,14,15,16,17,29,30,31,32,33|
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Safety

Risk Statements 
20/21/22-36/37/38
Safety Statements 
24/25
WGK Germany 
3
F 
10
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
88719
Product name
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Purity
≥97%
Packaging
1g
Price
$341
Updated
2025/07/31
Sigma-Aldrich
Product number
88719
Product name
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Purity
≥97%
Packaging
5g
Price
$2009
Updated
2025/07/31
TCI Chemical
Product number
D5438
Product name
(2R)-1-[(1R)-1-[Bis-tert-butylphosphino]ethyl]-2-(diphenylphosphino)ferrocene
Packaging
200MG
Price
$99
Updated
2025/07/31
Strem Chemicals
Product number
26-1200
Product name
(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
Packaging
100mg
Price
$107
Updated
2024/03/01
Strem Chemicals
Product number
26-1200
Product name
(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
Packaging
500mg
Price
$375
Updated
2024/03/01
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(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties,Usage,Production

Reaction

  1. Ligand for Palladium-catalyzed amination of aryl halides
  2. Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene
  3. Ligand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids
  4. Ligand for Copper-catalyzed asymmetric 1,4-hydrosilylations of α,β-unsaturated esters
  5. Ligand for Ruthenium-catalyzed asymmetric hydrogenation of N-sulfonated-α-dehydroamino acids
  6. Ligand for Rhodium-catalyzed asymmetric hydrogenation of enamines
  7. Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates
  8. Ligand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides
  9. Ligand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a C-C bond


Chemical Properties

Orange powder

Uses

It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.

General Description

(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-tBu) is a chiral ferrocenyl diphosphine ligand.

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Acetic anhydride 2-Chloro-2-methylpropane Potassium carbonate Chlorodiphenylphosphine Phosphorus trichloride (R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE Ethyl acetate Lithium Aluminum Hydride Hydrochloric acid Dichloromethane Acetic acid Magnesium n-Butyllithium

Preparation Products

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(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Suppliers

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View Lastest Price from (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
(R)-(-)-[(S)-2-(Diphenylphosphino(ferrocenyl]ethyldi-tert-butylphosphine 155830-69-6
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-19
XINXIANG RUNYU MATERIAL CO., LTD.
Product
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE 155830-69-6
Price
US $0.00-0.00/g
Min. Order
1KG
Purity
0.97
Supply Ability
500kg
Release date
2021-11-30
Zhuozhou Wenxi import and Export Co., Ltd
Product
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine 155830-69-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

155830-69-6, (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINERelated Search:

(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE (R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-(S)-JOSIPHOS 1,3-BIS(DIMETHYLPHOSPHINO)PROPANE T-BUTYLPHOSPHINE (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Di-tert-butylphosphine (S)-1-[(1R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE TRIISOPROPYLPHOSPHINE Ferrocene DI-T-BUTYL(I-PROPYL)PHOSPHINE (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine TERT-BUTYLDIISOPROPYLPHOSPHINE (R)-1-[(S)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE (R)-1-[(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE

  • (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]-ethyl-di-tert-butylphosphine, Manufactured by Solvias AG
  • (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%
  • -2-(Diphenylphosphino)
  • ferrocenyl]ethyldi-tert-butylphosphine
  • "Josiphos SL-J002-1/ (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine"
  • Josiphos SL-J002
  • Josiphos SL-J002-1 / (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
  • (R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph
  • (R)1 (1S)2(DIPHENYLPHOSPHINO)FERROCENYL&
  • (R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine, 95+%
  • JOSIPHOS SL-J002-1
  • (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
  • (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
  • (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
  • (R)-(-)-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
  • (R,R)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-(DIPHENYLPHOSPHINO)FERROCENE
  • (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine,min.97%
  • (r,r)-1-[1-(di-tert-butylphosphino)ethyl]-2-(diphenylphosphino)ferrocene (acc to cas)
  • (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE 97+%
  • (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
  • Josiphos SL-J002-1, (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS)
  • (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
  • (R)-(-)-[(S)-2-(D
  • (R)-1-1[(S) -2-(Diphenylphospino)ferrocenyl]ethylbis-t-butylphosphine
  • (R)-(S)-PPF-P(tBu)2
  • (R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine, 95+% 500MG
  • Ferrocene, 1-[(1R)-1-[bis(1,1-diMethylethyl)phosphino]ethyl]-2-(diphenylphosphino)-, (2R)-
  • (R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ,97%
  • -1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
  • (R)-(-)-1-[(Sp)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine
  • (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene
  • (2R)-1-[(1R)-1-[Bis-tert-butylphosphino]ethyl]-2-(diphenylphosphino)ferrocene
  • (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphin
  • (R)-(-)-[(S)-2-(Diphenylphosphino(ferrocenyl]ethyldi-tert-butylphosphine
  • (R)-(-)-[(S)-2-(Diphenylphosphino(ferrocenyl]ethyldi-t-butyl...
  • (R)-1-[(S)-3-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
  • (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (Josiphos SL-J002-1)
  • (R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene
  • (2Sp)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene
  • (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (ACI)
  • (<i>R</i>)-1-[(<i>S</i><sub>P</sub>)-2-(Diphenylphosphino)ferrocenyl]ethyldi-<i>tert</i>-butylphosphine
  • (R)-(-)-1-[(S)-2-Diphenylphosphinothiopheneethyl-di-tert-butylphosphinothiophene]
  • 2-(1-(Di-tert-Butylphosphino)ethyl)-1-(diphenylphosphino)ferrocene
  • 155830-69-6
  • C32H34FeP2
  • C32H40FeP2
  • Solvias Ligands
  • Privileged Ligands
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Chiral Phosphine
  • Ferrocene Series
  • Josiphos Series
  • organophosphine ligand