ChemicalBook > CAS DataBase List > (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
Reaction- Product Name
- (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
- CAS No.
- 155830-69-6
- Chemical Name
- (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
- Synonyms
- Josiphos SL-J002;(R)-(-)-[(S)-2-(D;JOSIPHOS SL-J002-1;(R)-(S)-PPF-P(tBu)2;-2-(Diphenylphosphino);ferrocenyl]ethyldi-tert-butylphosphine;(R)1 (1S)2(DIPHENYLPHOSPHINO)FERROCENYL&;(R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph;(R)-(-)-[(S)-2-(Diphenylphosphino(ferrocenyl]ethyldi-t-butyl...;-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
- CBNumber
- CB7229824
- Molecular Formula
- C32H40FeP2
- Formula Weight
- 542.45
- MOL File
- 155830-69-6.mol
More
Less
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Property
- Melting point:
- 218-220°C (dec.)
- alpha
- -412° ±15° (c 0.5, CHCl3)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Chloroform, Methanol
- form
- Powder
- color
- Orange
More
Less
Safety
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 24/25
- WGK Germany
- 3
- F
- 10
- HS Code
- 29319090
More
Less
N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 88719
- Product name
- (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
- Purity
- ≥97%
- Packaging
- 1g
- Price
- $264.8
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 88719
- Product name
- (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
- Purity
- ≥97%
- Packaging
- 5g
- Price
- $1112
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 26-1200
- Product name
- (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
- Packaging
- 100mg
- Price
- $107
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 26-1200
- Product name
- (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
- Packaging
- 500mg
- Price
- $375
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 88719
- Product name
- (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
- Purity
- ≥97%
- Packaging
- 100mg
- Price
- $120
- Updated
- 2024/03/01
More
Less
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties,Usage,Production
Reaction
- Ligand for Palladium-catalyzed amination of aryl halides
- Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene
- Ligand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids
- Ligand for Copper-catalyzed asymmetric 1,4-hydrosilylations of α,β-unsaturated esters
- Ligand for Ruthenium-catalyzed asymmetric hydrogenation of N-sulfonated-α-dehydroamino acids
- Ligand for Rhodium-catalyzed asymmetric hydrogenation of enamines
- Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates
- Ligand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides
- Ligand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a C-C bond
Chemical Properties
Orange powder
Uses
It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.
General Description
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-tBu) is a chiral ferrocenyl diphosphine ligand.
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials
Raw materials
Acetic anhydride
2-Chloro-2-methylpropane
Potassium carbonate
Chlorodiphenylphosphine
Phosphorus trichloride
(R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE
Ethyl acetate
Lithium Aluminum Hydride
Hydrochloric acid
Dichloromethane
Acetic acid
Magnesium
n-Butyllithium
Preparation Products
More
Less
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Suppliers
- Tel
- 166-166-37336996 15690792173
- Fax
- 0373-7759608
- chenxi.song@runvmat.com
- Country
- China
- ProdList
- 441
- Advantage
- 55
- Tel
- 0371-67759225 13526468238
- Fax
- 0371-55919558
- sales@hqmat.com
- Country
- China
- ProdList
- 471
- Advantage
- 55
- Tel
- 010-57794770 13552605092
- Fax
- 010-60593781
- tianyukanghong@163.com
- Country
- China
- ProdList
- 343
- Advantage
- 55
- Tel
- 0371-0371-65511006 18625597674
- sales@kingorgchem.com
- Country
- China
- ProdList
- 950
- Advantage
- 55
- Tel
- 010-68862197 13810598707
- Fax
- 010-68882204
- sales@huikangchem.com
- Country
- China
- ProdList
- 111
- Advantage
- 61
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 4006608290; 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40241
- Advantage
- 62
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44751
- Advantage
- 61
- Tel
- 010-82967028 13552068683
- Fax
- +86-10-82967029
- 2355560935@qq.com
- Country
- China
- ProdList
- 12458
- Advantage
- 60
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9551
- Advantage
- 66
- Tel
- 025-83697070
- Fax
- +86-25-83453306
- info@chemlin.com.cn
- Country
- China
- ProdList
- 17987
- Advantage
- 64
- Tel
- 021-50135380
- shchemsky@sina.com
- Country
- China
- ProdList
- 32344
- Advantage
- 50
- Tel
- 021-50460086-9 15921403865
- Fax
- +86-21-50462321
- han_yajun@dctc.daicel.com
- Country
- China
- ProdList
- 6854
- Advantage
- 65
- Tel
- 021-61551100
- Fax
- 021-61551100
- Country
- China
- ProdList
- 444
- Advantage
- 57
- Tel
- +86 (573) 82222445 (0)18006601000 452520369
- Fax
- +86 (573) 82222643
- sales@maya-r.com
- Country
- China
- ProdList
- 11714
- Advantage
- 57
- Tel
- 800-810-5118
- Fax
- +86-10-84193589
- cnchemical@thermofisher.com
- Country
- China
- ProdList
- 17779
- Advantage
- 75
- Tel
- 400-810-7969 010-59572699
- Fax
- 010-59572688
- ningzi.li@inno-chem.com.cn
- Country
- China
- ProdList
- 6139
- Advantage
- 55
- Tel
- 021-58950125
- Fax
- (86) 21-58955996
- info@chemexpress.com
- Country
- China
- ProdList
- 7553
- Advantage
- 61
- Tel
- 021-57603038 13601791340
- Fax
- 021-57603057
- 307593986@qq.com
- Country
- China
- ProdList
- 475
- Advantage
- 58
- Tel
- 4009209199
- Fax
- 86-021-52271987
- sales@9dingchem.com
- Country
- China
- ProdList
- 22519
- Advantage
- 55
- Tel
- 180000000
- 3755454181@qq.com
- Country
- China
- ProdList
- 419
- Advantage
- 55
- Tel
- 0371-67759225 13526468238
- Fax
- +86-37155919558
- sales@hqmat.com
- Country
- China
- ProdList
- 525
- Advantage
- 60
- Tel
- 400-1647117 15221909166
- Fax
- +86-21-61629029
- product02@bidepharm.com
- Country
- China
- ProdList
- 41438
- Advantage
- 60
- Tel
- 027-60707801 13628634921
- sunny.w@boronicgroup.com
- Country
- China
- ProdList
- 175
- Advantage
- 56
- Tel
- 917-917-8888777 18691746767
- zhaoting@bjrock.com
- Country
- China
- ProdList
- 302
- Advantage
- 62
- Tel
- 021-60455363 18019463053
- Fax
- 50966098
- sales@coolpharm.com
- Country
- China
- ProdList
- 12357
- Advantage
- 58
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com
- Country
- China
- ProdList
- 51471
- Advantage
- 80
- Tel
- 021-5068 3667/17749785980/1029026415; 17749785980
- Fax
- 021-50683667
- 1029026415@qq.com
- Country
- China
- ProdList
- 2790
- Advantage
- 58
- Tel
- 0371-63769919 18530983798
- Fax
- 0371-55057218
- sales5@changkuantech.com
- Country
- China
- ProdList
- 223
- Advantage
- 55
- Tel
- 025-87193546 18652950785
- Fax
- 025-87193546
- chemweiao@163.com
- Country
- China
- ProdList
- 9030
- Advantage
- 60
- Tel
- 025-83453382-8005
- Fax
- 025-83453382
- sale@parabiochem.com
- Country
- China
- ProdList
- 9604
- Advantage
- 55
- Tel
- 13391486464
- Fax
- QQ:14748090
- samwjf@163.com
- Country
- China
- ProdList
- 3090
- Advantage
- 55
- Tel
- 021-2022843681 15618226720
- Fax
- +86-21-51601218
- chaolaichem@foxmail.com
- Country
- China
- ProdList
- 7565
- Advantage
- 58
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131981
- Advantage
- 58
- Tel
- 0751-2886750 13927877953
- Fax
- 0751-2886750
- 3005811397@qq.com
- Country
- China
- ProdList
- 13360
- Advantage
- 58
- Tel
- 021-60702684 18516024827
- huang.jiayi@sinocompound.com
- Country
- China
- ProdList
- 2654
- Advantage
- 58
- Tel
- 13127280945
- 285424065@qq.com
- Country
- China
- ProdList
- 9980
- Advantage
- 55
- Tel
- 010-61136123
- Fax
- +86 (10) 8857-9127
- pub02@greenherbs.com.cn
- Country
- China
- ProdList
- 4049
- Advantage
- 58
- Tel
- 10106090
- jjlchem2@163.com
- Country
- China
- ProdList
- 9986
- Advantage
- 58
- Tel
- +86-0571-81953185; 15381198709 +86-15381198709
- Fax
- 0571-89086206
- jasonyao@beyond-pharma.com
- Country
- China
- ProdList
- 829
- Advantage
- 60
- Tel
- 025-66028182 18112977050
- Fax
- (3)02557626880
- cfzhang@aikonchem.com
- Country
- China
- ProdList
- 15820
- Advantage
- 58
- Tel
- 400-400-1332688 18019345275
- Fax
- 400-133-2688
- amy@rhawn.cn
- Country
- China
- ProdList
- 15503
- Advantage
- 58
- Tel
- 17368696818
- Country
- China
- ProdList
- 1986
- Advantage
- 58
- Tel
- 021-60345187 13917602471
- Fax
- 021-60345187
- lzz841106@aliyun.com
- Country
- China
- ProdList
- 9908
- Advantage
- 58
- Tel
- 400-8210725 4008210725
- Fax
- 021-58955996
- malulu@leyan.com
- Country
- China
- ProdList
- 24971
- Advantage
- 58
- Tel
- 021-54338626 18017892860
- Fax
- 021-54338626
- sales@tubepharm.com
- Country
- China
- ProdList
- 2329
- Advantage
- 58
- Tel
- 025-83453353
- Fax
- 025-83453353
- nj.chemlin@chemlin.com.cn
- Country
- CHINA
- ProdList
- 853
- Advantage
- 58
- Tel
- 021-34625901
- 420970979@qq.com
- Country
- China
- ProdList
- 5711
- Advantage
- 58
- Tel
- 18367600069
- Fax
- QQ3388371646
- pinghushizy@163.com
- Country
- China
- ProdList
- 7813
- Advantage
- 58
- Tel
- 400-400-400-9004166 18616739031
- 3007523370@qq.com
- Country
- China
- ProdList
- 52712
- Advantage
- 58
More
Less
View Lastest Price from (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE manufacturers
XINXIANG RUNYU MATERIAL CO., LTD.
- Product
- (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE 155830-69-6
- Price
- US $0.00-0.00/g
- Min. Order
- 1KG
- Purity
- 0.97
- Supply Ability
- 500kg
- Release date
- 2021-11-30
Zhengzhou HQ Material CO.,LTD.
- Product
- (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine 155830-69-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99
- Supply Ability
- 10
- Release date
- 2021-09-22
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine 155830-69-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
155830-69-6, (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINERelated Search:
(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
(R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
(R)-(S)-JOSIPHOS
1,3-BIS(DIMETHYLPHOSPHINO)PROPANE
T-BUTYLPHOSPHINE
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
Di-tert-butylphosphine
(S)-1-[(1R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
TRIISOPROPYLPHOSPHINE
Ferrocene
DI-T-BUTYL(I-PROPYL)PHOSPHINE
(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
TERT-BUTYLDIISOPROPYLPHOSPHINE
(R)-1-[(S)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-1-[(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE