(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE

ChemicalBook > CAS DataBase List > (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE

(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE

Reaction

Product Name: (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
CAS No.: 246231-79-8
Chemical Name: (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
Synonyms: JOSIPHOS SL-J011-2;JOSIPHOS SL-J011-1;(S)-1-[(R)-2-[BIS[4-(TRIFLUO;(R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-C...;(R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-CF3-phenyl)phosphine;(R)-1-{(S)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}-ethyldi-tert.-;(R)-1-{(R)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine;(R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosph;(R)-1-[(S)-2-Di-(4-trifluoromethylphenylphos-phino)ferrocenyl]-ethyl-di-tert-butylphosphine;(R)-(-)-1-[(S)-2-(BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYL-DI-T-BUTYLPHOSPHINE
CBNumber: CB5120257
Molecular Formula: C34H32F6FeP2
Formula Weight: 672.41
MOL File: 246231-79-8.mol

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(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Property

alpha: -352° ±10° (c 0.5, CHCl3)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: orange

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Safety

Risk Statements: 36/37/38
Safety Statements: 24/25
WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 26-0650
Product name: (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
Packaging: 100mg
Price: $107
Updated: 2024/03/01

Strem Chemicals

Product number: 26-0650
Product name: (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
Packaging: 500mg
Price: $375
Updated: 2024/03/01

Strem Chemicals

Product number: 26-0650
Product name: (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
Packaging: 2g
Price: $1031
Updated: 2024/03/01

Strem Chemicals

Product number: 26-0650
Product name: (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%
Packaging: 10g
Price: $4379
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: ING0001274
Product name: (R)-(-)-1-[(S)-2-(BIS(4-TRIFLUOROMETHYLPHENYL) PHOSPHINO]FERROCENYL]ETHYL-DI-TERT-BUTYLPHOSPHINE
Purity: 95.00%
Packaging: 500MG
Price: $914.17
Updated: 2021/12/16

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(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties,Usage,Production

Reaction

Ferrocenylphosphine ligands of the type cpFecp(PR2)(*CH(CH3)PR'2) are a class of asymmetric ligands developed at Solvias in Basel, Switzerland. Ligands of this type are currently used industrially in the stereoselective synthesis of commercial products. A unique feature of these bidentate ligands is the presence of a fixed phosphine moiety and a stereogenic, functionalized side chain, which can be easily modified to accommodate electronic and steric requirements. Based on a versatile synthetic procedure starting with optically active ferrocenes of the type cpFecp(PR2)(*CH(CH3)X) [X = OAc or NR2], a variety of donor atoms can be introduced into the side chain. These ferrocene based phosphine ligands have wide application in the stereoselective hydrogenation of substituted acetamidoacrylates, enol acetates, β-ketoesters and simple alkenes.
Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.
Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides.
Asymmetric hydrogenation of ketones and phosphinylketimines.
Michael addition of Grignard reagents to α,α-unsaturated esters and thioesters.
Boration of α,α-unsaturated esters and nitriles.
Reaction of aryl halides with ammonia.
Cu-catalyzed reduction of activated C=C bonds with PMHS.
Regio- and enantioselective hydroboration of vinyl arenes.
Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.
1,2-Migrations in Pd-catalyzed Negishi couplings with JosiPhos ligands.
Catalyst for the homodimerization of ketoketenes.
Ligand for the Rh catalyzed synthesis of lactones.
Ligand for the Cu-catalyzed synthesis of syn and anti γ-amino alcohols.

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.

Product: (R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosphine 246231-79-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500kg
Release date: 2023-11-01

Career Henan Chemical Co

Product: (R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosphine 246231-79-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: Min98%
Supply Ability: g/kg/ton
Release date: 2020-01-08

246231-79-8, (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINERelated Search:

(S)-1-{(R)-2-[DI(2-FURYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT.-BUTYLPHOSPHINE (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-(S)-JOSIPHOS (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Ferrocene Phosphine 1,3-Cyclopentadiene T-BUTYLPHOSPHINE Di-tert-butylphosphine DI-T-BUTYL(I-PROPYL)PHOSPHINE TERT-BUTYLDIISOPROPYLPHOSPHINE BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE (4-TRIFLUOROMETHYLPHENYL)PHOSPHINE

JOSIPHOS SL-J011-1

JOSIPHOS SL-J011-2

(S,S)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

(S)-1-[(R)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE

(R,R)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

(R)-(-)-1-[(S)-2-(BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYL-DI-T-BUTYLPHOSPHINE

(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE

(R)-(-)-1-[(S)-(2-DI-TERT-BUTYLPHOSPHINO)FERROCENYL]ETHYLDI-(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE

"Josiphos SL-J011-1/ (R)-1-{(SP)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldi-tert-butylphosphine"

Josiphos SL-J011-1 / (R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosphine

(R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-CF3-phenyl)phosphine

(R)-1-{(S)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}-ethyldi-tert.-

(R)-(-)-1-{(S)-2-(Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-<br />di-t-butylphosphine, min. 97%

(R)-(-)-1-{(S)-2-(Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine,min.97%

(r,r)-1-[1-(di-tert-butylphosphino)ethyl]-2-{bis[4-(trifluoromethyl)phenyl]phosphino}ferrocene (acc to cas)

(R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl) phosphino]ferrocenyl} ethyl-di-t-butylphosphine, min. 97%

(R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosph

(R)-1-[(S)-2-Di-(4-trifluoromethylphenylphos-phino)ferrocenyl]-ethyl-di-tert-butylphosphine

(R)-1-[(S)-2-Di-(4-trifluoroMethylphenylphos-phino)ferrocenyl]-ethyl-di-tert-butylphosphine, Manufactured by Solvias AG

(R)-1-{(SP)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldi-tert-butylphosphine >=97%

(R)-(-)-1-{(SP)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldi-tert-butylphosphine

(2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-[bis[4-(trifluoromethyl)phenyl]phosphino]ferrocene

(S)-1-[(R)-2-[BIS[4-(TRIFLUO

Ferrocene, 1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-[bis[4-(trifluoromethyl)phenyl]phosphino]-, (2R)-

(R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%,99%ee

(R)-1-{(R)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine

(R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-C...

(R)-(-)-1-{(Sp)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldi-t-butylphosphine

246231-79-8

C34H38F6FeP2

Solvias Ligands

Privileged Ligands

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Josiphos Series

Chiral Phosphine

Ferrocene Series

metallocene