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2-BROMO-5-IODOANISOLE

Product Name
2-BROMO-5-IODOANISOLE
CAS No.
755027-18-0
Chemical Name
2-BROMO-5-IODOANISOLE
Synonyms
2-BROMO-5-IODOANISOLE;2-Bromo-5-iodoanisole 98%;2-bromo-5-iodophenyl ether;2-iodine-5-bromophenyl ether;2-BroMo-5-iodophenyl Methyl ether;Benzene, 1-broMo-4-iodo-2-Methoxy-;1-Bromo-4-iodo-2-methoxybenzene, 2-Bromo-5-iodophenyl methyl ether
CBNumber
CB5125368
Molecular Formula
C7H6BrIO
Formula Weight
312.93
MOL File
755027-18-0.mol
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2-BROMO-5-IODOANISOLE Property

Boiling point:
293.7±20.0 °C(Predicted)
Density 
2.062
storage temp. 
Keep in dark place,Sealed in dry,2-8°C
form 
crystalline needles
color 
Faint yellow
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Safety

Hazard Codes 
Xi
Hazard Note 
Irritant
HS Code 
2909309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
B688943
Product name
1-Bromo-4-iodo-2-methoxybenzene
Packaging
500mg
Price
$65
Updated
2021/12/16
Oakwood
Product number
062593
Product name
2-Bromo-5-iodoanisole
Packaging
250mg
Price
$9
Updated
2021/12/16
AK Scientific
Product number
V2185
Product name
2-Bromo-5-iodoanisole
Packaging
10g
Price
$90
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB64625
Product name
2-bromo-5-iodoanisole
Packaging
25g
Price
$106.25
Updated
2021/12/16
Ark Pharm
Product number
AK-72575
Product name
1-Bromo-4-iodo-2-methoxybenzene
Purity
97%
Packaging
25g
Price
$109
Updated
2021/12/16
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2-BROMO-5-IODOANISOLE Chemical Properties,Usage,Production

Synthesis

19056-40-7

755027-18-0

4-Bromo-3-methoxyaniline (102 mg, 0.50 mmol) was used as starting material and dissolved in concentrated hydrochloric acid (10 mL) at 0 °C. Subsequently, an aqueous solution of sodium nitrite (NaNO2, 45 mg, 0.65 mmol) (5 mL) was slowly added, the reaction temperature was maintained at 0 °C and the reaction was stirred for 1 hour. Next, an aqueous solution of potassium iodide (KI, 249 mg, 1.5 mmol) (5 mL) was added, and the reaction mixture was gradually warmed to room temperature and stirred overnight. After completion of the reaction, the product was extracted with ethyl acetate. The organic phase was washed sequentially with water and 10% sodium thiosulfate (Na2S2O3) solution, dried over anhydrous magnesium sulfate (MgSO4), filtered and concentrated to give 147 mg of 2-bromo-5-iodoanisole in 94% yield. The product was analyzed by mass spectrometry (ESI), m/e 332 (M + 20)+; nuclear magnetic resonance hydrogen spectrum (1H NMR, 300 MHz, DMSO-d6) δ 7.39 (d, J = 1.87 Hz, 1H), 7.34 (d, J = 8.11 Hz, 1H), 7.24 (dd, J = 8.11, 1.87 Hz, 1H), 3.86 (s 3H).

References

[1] European Journal of Organic Chemistry, 2018, vol. 2018, # 38, p. 5312 - 5322
[2] Patent: WO2004/76424, 2004, A1. Location in patent: Page 79
[3] Journal of the American Chemical Society, 2018,
[4] Patent: WO2007/37187, 2007, A1. Location in patent: Page/Page column 127-128
[5] Patent: WO2008/57208, 2008, A2. Location in patent: Page/Page column 50

2-BROMO-5-IODOANISOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-5-IODOANISOLE Suppliers

China 112 India 4 Switzerland 1 United Kingdom 5 United States 8 Global 130
Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
Apin Chemicals Limited (UK)
Tel
--
Fax
--
Email
info@apinchemicals.com
Country
United Kingdom
ProdList
6184
Advantage
60
Wychem Ltd.
Tel
--
Fax
--
Email
terry.robinson@wychem.co.uk
Country
United Kingdom
ProdList
1995
Advantage
47
Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
Fluorochem Ltd.
Tel
--
Fax
--
Email
enquiries@fluorochem.co.uk
Country
United Kingdom
ProdList
6401
Advantage
74
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View Lastest Price from 2-BROMO-5-IODOANISOLE manufacturers

Career Henan Chemical Co
Product
2-BROMO-5-IODOANISOLE 755027-18-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11

755027-18-0, 2-BROMO-5-IODOANISOLERelated Search:

2-Bromo-3-iodoanisole 4-Bromo-2-iodoanisole 4-BROMO-3-IODOANISOLE 3-Bromo-2-iodoanisole 2-Bromo-4-iodoanisole 2-BROMO-5-IODOPHENOL 2-BROMO-5-IODOANISOLE

  • 2-BROMO-5-IODOANISOLE
  • Benzene, 1-broMo-4-iodo-2-Methoxy-
  • 1-Bromo-4-iodo-2-methoxybenzene, 2-Bromo-5-iodophenyl methyl ether
  • 2-BroMo-5-iodophenyl Methyl ether
  • 2-Bromo-5-iodoanisole 98%
  • 2-bromo-5-iodophenyl ether
  • 2-iodine-5-bromophenyl ether
  • 755027-18-0
  • 55027-18-0
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Bromine Compounds
  • Iodine Compounds
  • Aromatic Halides (substituted)