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ZIRCONIUM IODIDE

Product Name
ZIRCONIUM IODIDE
CAS No.
13986-26-0
Chemical Name
ZIRCONIUM IODIDE
Synonyms
ZrI4;ZIRCONIUM IODIDE;Einecs 237-780-9;ZIRCONIUM(IV) IODIDE;ZIRCONIUM TETRAIODIDE;zirconiumiodide(zri4);Zirconium iodide (ZrI4);Zirconium(IV) tetraiodide;zirconium(4+),tetraiodide;ZIRCONIUM(IV) IODIDE: 99.5%
CBNumber
CB5134410
Molecular Formula
I4Zr
Formula Weight
598.84
MOL File
13986-26-0.mol
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ZIRCONIUM IODIDE Property

Melting point:
499°C
Boiling point:
431°C (estimate)
Density 
4.85
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
very soluble in H2O
form 
powder
color 
Yellow
Specific Gravity
4.914
Water Solubility 
Insoluble in water.
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Merck 
14,10178
Exposure limits
ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference
13986-26-0(CAS DataBase Reference)
EPA Substance Registry System
Zirconium iodide (ZrI4) (13986-26-0)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
22-26-27-36/37/39-45
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
TSCA 
No
HazardClass 
8
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
017400
Product name
Zirconium(IV) iodide
Purity
99%
Packaging
25g
Price
$615
Updated
2023/06/20
Strem Chemicals
Product number
93-4025
Product name
Zirconium(IV) iodide (99.5%-Zr)
Packaging
1g
Price
$68
Updated
2024/03/01
Strem Chemicals
Product number
93-4025
Product name
Zirconium(IV) iodide (99.5%-Zr)
Packaging
5g
Price
$178
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0007364
Product name
ZIRCONIUM(IV) IODIDE
Purity
95.00%
Packaging
1G
Price
$673.68
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0007364
Product name
ZIRCONIUM(IV) IODIDE
Purity
95.00%
Packaging
5G
Price
$957.46
Updated
2021/12/16
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ZIRCONIUM IODIDE Chemical Properties,Usage,Production

Description

Zirconium(IV) iodide, ZrI4, is the most readily available iodide of zirconium. It is an orange-colored solid that degrades in the presence of water. The compound was once renowned as an intermediate in the purification of zirconium metal. This compound is volatile, subliming as intact tetrahedral ZrI4 molecules.

Chemical Properties

orange crystal(s); fumes heavily in air; cub, a=1.179nm [KIR84] [MER06]

Uses

Used in the van Arkel-de Boer refining process.

Preparation

It is prepared by the direct reaction of powdered zirconium metal and iodine. Pyrolysis of zirconium(IV) iodide gas by contact of hot wire was the first industrial process for the commercial production of pure ductile metallic zirconium.

Structure and conformation

Like most binary metal halides, it has a polymeric structure. The compound exists as a polymer consisting of octahedral Zr(IV) centers, each with a pair of terminal iodide ligands and four doubly bridging iodide ligands. The Zr-I distances are 2.692 (terminal) and 3.030 A? .

ZIRCONIUM IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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ZIRCONIUM IODIDE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Spectrum Chemical Manufacturing Corp.
Tel
021-021-021-67601398-809-809-809 15221380277
Fax
021-57711696
Email
marketing_china@spectrumchemical.com
Country
China
ProdList
9658
Advantage
60
Suzhou yacoo science co.,Ltd
Tel
0512-87182056 18013166090
Fax
0512-87182056
Email
lingling.qi@yacoo.com.cn
Country
China
ProdList
7295
Advantage
60
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939 15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
16166
Advantage
55
Hubei Jusheng Technology Co.,Ltd
Tel
027-59599241 18871490274
Fax
027-59599241
Email
1400878000@qq.com
Country
China
ProdList
9958
Advantage
58
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60

13986-26-0, ZIRCONIUM IODIDERelated Search:


  • Zirconium(IV)iodide(99.5%-Zr)
  • ZIRCONIUM(IV) IODIDE: 99.5%
  • Zirconium iodide (ZrI4)
  • zirconiumiodide(zri4)
  • ZrI4
  • ZIRCONIUM IODIDE
  • ZIRCONIUM(IV) IODIDE
  • ZIRCONIUM TETRAIODIDE
  • Zirconiumiodidereddishbrownpowder
  • zirconium(4+),tetraiodide
  • Zirconium(IV) tetraiodide
  • Einecs 237-780-9
  • Zirconium(IV) iodide anhydrous
  • ZirconiuM (IV) Iodide, Powder
  • Zirconium(IV) iodide anhydrous, powder, 99.9% trace metals basis
  • ZIRCONIUM IODIDE ISO 9001:2015 REACH
  • 13986-26-0
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  • Zirconium
  • Catalysis and Inorganic Chemistry
  • ZirconiumMetal and Ceramic Science
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Crystal Grade Inorganics
  • Salts
  • Zirconium Salts
  • metal halide