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ZIRCONIUM IODIDE

Product Name
ZIRCONIUM IODIDE
CAS No.
13986-26-0
Chemical Name
ZIRCONIUM IODIDE
Synonyms
ZrI4;ZIRCONIUM IODIDE;Einecs 237-780-9;ZIRCONIUM(IV) IODIDE;ZIRCONIUM TETRAIODIDE;zirconiumiodide(zri4);Zirconium iodide (ZrI4);Zirconium(IV) tetraiodide;zirconium(4+),tetraiodide;ZIRCONIUM(IV) IODIDE: 99.5%
CBNumber
CB5134410
Molecular Formula
I4Zr
Formula Weight
598.84
MOL File
13986-26-0.mol
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ZIRCONIUM IODIDE Property

Melting point:
499°C
Boiling point:
431°C (estimate)
Density 
4.85
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
very soluble in H2O
form 
powder
color 
Yellow
Specific Gravity
4.914
Water Solubility 
Insoluble in water.
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Merck 
14,10178
Exposure limits
ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference
13986-26-0(CAS DataBase Reference)
EPA Substance Registry System
Zirconium iodide (ZrI4) (13986-26-0)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
22-26-27-36/37/39-45
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
TSCA 
No
HazardClass 
8
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
017400
Product name
Zirconium(IV) iodide
Purity
99%
Packaging
25g
Price
$615
Updated
2023/06/20
Strem Chemicals
Product number
93-4025
Product name
Zirconium(IV) iodide (99.5%-Zr)
Packaging
1g
Price
$68
Updated
2024/03/01
Strem Chemicals
Product number
93-4025
Product name
Zirconium(IV) iodide (99.5%-Zr)
Packaging
5g
Price
$178
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0007364
Product name
ZIRCONIUM(IV) IODIDE
Purity
95.00%
Packaging
1G
Price
$673.68
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0007364
Product name
ZIRCONIUM(IV) IODIDE
Purity
95.00%
Packaging
5G
Price
$957.46
Updated
2021/12/16
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ZIRCONIUM IODIDE Chemical Properties,Usage,Production

Description

Zirconium(IV) iodide, ZrI4, is the most readily available iodide of zirconium. It is an orange-colored solid that degrades in the presence of water. The compound was once renowned as an intermediate in the purification of zirconium metal. This compound is volatile, subliming as intact tetrahedral ZrI4 molecules.

Chemical Properties

orange crystal(s); fumes heavily in air; cub, a=1.179nm [KIR84] [MER06]

Uses

Used in the van Arkel-de Boer refining process.

Preparation

It is prepared by the direct reaction of powdered zirconium metal and iodine. Pyrolysis of zirconium(IV) iodide gas by contact of hot wire was the first industrial process for the commercial production of pure ductile metallic zirconium.

Structure and conformation

Like most binary metal halides, it has a polymeric structure. The compound exists as a polymer consisting of octahedral Zr(IV) centers, each with a pair of terminal iodide ligands and four doubly bridging iodide ligands. The Zr-I distances are 2.692 (terminal) and 3.030 A? .

ZIRCONIUM IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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ZIRCONIUM IODIDE Suppliers

China 53 Germany 2 Japan 1 Singapore 1 Switzerland 1 United Kingdom 4 United States 14 Global 76
Leancare Ltd.
Tel
--
Fax
--
Email
enquiry@leancare.co.uk
Country
United Kingdom
ProdList
6446
Advantage
42
ABSCO Materials
Tel
--
Fax
--
Email
enquiries@abscomaterials.com
Country
United Kingdom
ProdList
911
Advantage
55
ABSCO Ltd
Tel
--
Fax
--
Email
enquiries@abscomaterials.com
Country
United Kingdom
ProdList
911
Advantage
66
VWR International
Tel
--
Fax
--
Email
solutions@vwr.com
Country
United Kingdom
ProdList
6548
Advantage
82

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  • Zirconium(IV)iodide(99.5%-Zr)
  • ZIRCONIUM(IV) IODIDE: 99.5%
  • Zirconium iodide (ZrI4)
  • zirconiumiodide(zri4)
  • ZrI4
  • ZIRCONIUM IODIDE
  • ZIRCONIUM(IV) IODIDE
  • ZIRCONIUM TETRAIODIDE
  • Zirconiumiodidereddishbrownpowder
  • zirconium(4+),tetraiodide
  • Zirconium(IV) tetraiodide
  • Einecs 237-780-9
  • Zirconium(IV) iodide anhydrous
  • ZirconiuM (IV) Iodide, Powder
  • Zirconium(IV) iodide anhydrous, powder, 99.9% trace metals basis
  • ZIRCONIUM IODIDE ISO 9001：2015 REACH
  • 13986-26-0
  • 13985-26-0
  • Zrl4
  • Zirconium
  • Catalysis and Inorganic Chemistry
  • ZirconiumMetal and Ceramic Science
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Crystal Grade Inorganics
  • Salts
  • Zirconium Salts
  • metal halide