6-(Hydroxymethyl)pyridine-2-carboxaldehyde
- Product Name
- 6-(Hydroxymethyl)pyridine-2-carboxaldehyde
- CAS No.
- 39621-11-9
- Chemical Name
- 6-(Hydroxymethyl)pyridine-2-carboxaldehyde
- Synonyms
- 6-(hydroxymethyl)picolinaldehyde;2-Formyl-6-(hydroxymethyl)pyridine;6- (hydroxymethyl) pyridine formaldehyde;6-HYDROXYMETHYL-2-PYRIDINECARBOXALDEHYDE;6-(hydroxyMethyl)pyridine-2-carbaldehyde;6-(Hydroxymethyl)pyridine-2-carboxaldehyde;2-Pyridinecarboxaldehyde, 6-(hydroxymethyl)-;2-Formyl-6-(hydroxymethyl)pyridine, (6-Formylpyridin-2-yl)methanol
- CBNumber
- CB51563428
- Molecular Formula
- C7H7NO2
- Formula Weight
- 137.14
- MOL File
- 39621-11-9.mol
6-(Hydroxymethyl)pyridine-2-carboxaldehyde Property
- Melting point:
- 73-74 °C
- Boiling point:
- 113-115 °C(Press: 0.5 Torr)
- Density
- 1.268±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- solid
- pka
- 13.05±0.10(Predicted)
- color
- Pale yellow
Safety
- Hazard Codes
- Xi
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- H948823
- Product name
- 6-(hydroxymethyl)pyridine-2-carbaldehyde
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 4H15-1-G5
- Product name
- 6-(Hydroxymethyl)pyridine-2-carboxaldehyde
- Packaging
- 100mg
- Price
- $82
- Updated
- 2021/12/16
- Product number
- 4H15-1-G5
- Product name
- 6-(Hydroxymethyl)pyridine-2-carboxaldehyde
- Packaging
- 250mg
- Price
- $125
- Updated
- 2021/12/16
- Product number
- 188574
- Product name
- 6-(Hydroxymethyl)pyridine-2-carbaldehyde
- Packaging
- 1g
- Price
- $300
- Updated
- 2021/12/16
- Product number
- 4H15-1-G5
- Product name
- 6-(Hydroxymethyl)pyridine-2-carboxaldehyde
- Packaging
- 1g
- Price
- $348
- Updated
- 2021/12/16
6-(Hydroxymethyl)pyridine-2-carboxaldehyde Chemical Properties,Usage,Production
Synthesis
1195-59-1
39621-11-9
GENERAL STEPS: The reaction was carried out in the presence of a base using complex 1 as a catalyst. This was done as follows: in a round-bottomed flask, 1 mmol of 2,6-pyridinedimethanol, 0.005 mmol of catalyst (3.6 mg) and 0.010 mmol of tBuOK (1.1 mg) were dissolved in 10 mL of toluene. The reaction mixture was placed in an aerobic environment and stirred continuously at 50 °C for 6 hours. Upon completion of the reaction, the solvent was removed by evaporation under reduced pressure using a rotary evaporator. The resulting crude product was purified by preparative silica gel GF-254 thin layer chromatography (TLC) with the eluent being a solvent mixture of ethyl acetate: hexane (1:10). The structure of the final product, 6-(hydroxymethyl)pyridinecarboxaldehyde, was confirmed by NMR spectroscopy (for the relevant spectra, see Figures S4-S32).
References
[1] Advanced Synthesis and Catalysis, 2011, vol. 353, # 16, p. 3023 - 3030
[2] Organic Letters, 2004, vol. 6, # 17, p. 2865 - 2868
[3] Synthesis, 2005, # 2, p. 223 - 232
[4] Organic and Biomolecular Chemistry, 2007, vol. 5, # 15, p. 2441 - 2447
[5] New Journal of Chemistry, 2009, vol. 33, # 2, p. 271 - 292
6-(Hydroxymethyl)pyridine-2-carboxaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
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