4-(METHOXYMETHYL)ANILINE
- Product Name
- 4-(METHOXYMETHYL)ANILINE
- CAS No.
- 80936-82-9
- Chemical Name
- 4-(METHOXYMETHYL)ANILINE
- Synonyms
- AKOS MSC-0184;4-(Methoxymethyl);4-(METHOXYMETHYL)ANILINE;4-(Methoxymethyl)benzenamine;Benzenamine,4-(methoxymethyl)-
- CBNumber
- CB5168871
- Molecular Formula
- C8H11NO
- Formula Weight
- 137.18
- MOL File
- 80936-82-9.mol
4-(METHOXYMETHYL)ANILINE Property
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- Appearance
- Light brown to brown Solid
- InChI
- InChI=1S/C8H11NO/c1-10-6-7-2-4-8(9)5-3-7/h2-5H,6,9H2,1H3
- InChIKey
- URSADVDNUKPSIK-UHFFFAOYSA-N
- SMILES
- C1(N)=CC=C(COC)C=C1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P330Rinse mouth.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M269548
- Product name
- 4-(Methoxymethyl)aniline
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- V7837
- Product name
- 4-(Methoxymethyl)aniline
- Packaging
- 5g
- Price
- $264
- Updated
- 2021/12/16
- Product number
- 098494
- Product name
- 4-(Methoxymethyl)aniline
- Packaging
- 25g
- Price
- $490
- Updated
- 2021/12/16
- Product number
- V7837
- Product name
- 4-(Methoxymethyl)aniline
- Packaging
- 25g
- Price
- $624
- Updated
- 2021/12/16
- Product number
- A202742
- Product name
- 4-(Methoxymethyl)aniline
- Purity
- 97%
- Packaging
- 250mg
- Price
- $23
- Updated
- 2021/12/16
4-(METHOXYMETHYL)ANILINE Chemical Properties,Usage,Production
Synthesis
1515-83-9
80936-82-9
General procedure for the synthesis of 4-methoxymethylaniline from 1-(methoxymethyl)-4-nitrobenzene: a mixture of 1-(methoxymethyl)-4-nitrobenzene (243 mg, 1 mmol) with 1% Pd/Ni bimetallic catalyst (73 mg, 30 wt%) in methanol (10 mL) was placed in an atmospheric pressure hydrogenation unit and stirred at room temperature and atmospheric pressure until hydrogen absorption ceased (about 90 min). Upon completion of the reaction, the catalyst was removed by means of a magnetic stirring bar and the solution was subsequently evaporated using a rotary evaporator to afford the target product, 4-methoxymethylaniline (1a), as a yellow oil (210 mg, 98% yield), which was sufficiently pure to be analyzed by 1H and 13C NMR. νmax by IR (KBr): 3372, 1623, 1519, 1233 cm?1; 1H NMR (CDCl3, 400 MHz) δ: 7.26-7.20 (m, 2H), 7.06 (d, 2H, J = 11.0 Hz), 6.87 (d, 2H, J = 11.0 Hz), 6.69 (d, 2H, J = 11.0 Hz), 4.90 (s, 2H), 3.69 (s, 2H) 2.28 (s, 3H); 13C NMR (CDCl3, 100 MHz) δ: 156.8, 146.3, 129.7 (2C), 126.8, 115.0 (2C), 114.6 (2C), 70.1, 20.4. HRMS (ESI-TOF) m/z: [M + Na]+ calcd for C14H15NO, 236.1046; found, 236.1044.
References
[1] Tetrahedron, 2015, vol. 71, # 49, p. 9240 - 9244
[2] Synlett, 1998, # 9, p. 1028 - 1028
[3] Journal of the Chemical Society. Perkin Transactions 1, 2001, # 9, p. 955 - 977
[4] Chemistry - A European Journal, 2007, vol. 13, # 4, p. 1291 - 1299
[5] Journal of the Chemical Society, 1954, p. 4127,4132
4-(METHOXYMETHYL)ANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-(METHOXYMETHYL)ANILINE manufacturers
- Product
- 4-(METHOXYMETHYL)ANILINE 80936-82-9
- Price
- US $0.01/KG
- Min. Order
- 500g
- Purity
- 98%; 99%
- Supply Ability
- 500g；1kg； 10kg; 25kg
- Release date
- 2020-01-08