TRIS(TRIMETHYLSILYL)SILANE
- Product Name
- TRIS(TRIMETHYLSILYL)SILANE
- CAS No.
- 1873-77-4
- Chemical Name
- TRIS(TRIMETHYLSILYL)SILANE
- Synonyms
- TTMSS;1,1,1,3,3,3-HEXAMETHYL-2-(TRIMETHYLSILYL)TRISILANE;Tri(trimethylsilyl)silane;TRIS(TRIMETHYLSILYL)SILANE;TRIS(TRIMETHYLSILYL)SILANE-D;Tris(trimethylsilyl)silane,96%;TRIS(TRIMETHYLSILYL)SILANE 97+%;TRIS(TRIMETHYLSILYL)SILANE 96%;T**Tris(trimethylsilyl)silane 97%;Tris(trimethylsilyl)silane [Reducing Reagent]
- CBNumber
- CB5176173
- Molecular Formula
- C9H28Si4
- Formula Weight
- 248.66
- MOL File
- 1873-77-4.mol
TRIS(TRIMETHYLSILYL)SILANE Property
- Boiling point:
- 73 °C/5 mmHg (lit.)
- Density
- 0.806 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.489(lit.)
- Flash point:
- 55 °C
- storage temp.
- Flammables area
- form
- liquid
- color
- Clear, colourless
- Specific Gravity
- 0.806
- Water Solubility
- Miscible with pentane, ether, toluene and tetrahydrofuran. Sparingly miscible with acetone and acetonitrile. Immiscible with water.
- Sensitive
- Light Sensitive
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- Merck
- 14,9757
- BRN
- 1923953
- CAS DataBase Reference
- 1873-77-4(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 10-36/37/38
- Safety Statements
- 16-26-36
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 3
- F
- 10-23
- TSCA
- No
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29319090
N-Bromosuccinimide Price
- Product number
- 360716
- Product name
- Tris(trimethylsilyl)silane
- Purity
- 97%
- Packaging
- 5g
- Price
- $130
- Updated
- 2024/03/01
- Product number
- 360716
- Product name
- Tris(trimethylsilyl)silane
- Purity
- 97%
- Packaging
- 25g
- Price
- $323
- Updated
- 2024/03/01
- Product number
- B22457
- Product name
- Tris(trimethylsilyl)silane
- Purity
- 97%
- Packaging
- 1g
- Price
- $31.65
- Updated
- 2024/03/01
- Product number
- B22457
- Product name
- Tris(trimethylsilyl)silane
- Purity
- 97%
- Packaging
- 5g
- Price
- $108
- Updated
- 2024/03/01
- Product number
- B22457
- Product name
- Tris(trimethylsilyl)silane
- Purity
- 97%
- Packaging
- 25g
- Price
- $296
- Updated
- 2024/03/01
TRIS(TRIMETHYLSILYL)SILANE Chemical Properties,Usage,Production
Chemical Properties
clear colorless to pale yellow liquid
Uses
Tris(trimethylsilyl)silane is used in hydrosilylations of carbonyls, radical reactions, reductions of acid chlorides, and carbon-halogen bonds. It acts a mediator of radical reactions and considered to be a nontoxic substitute for tri-n-butylstannane in radical reactions. It forms complexes with transition metals and main group elements. Further, it is utilized in carbon-carbon bond forming reactions.
Uses
Tris(trimethylsilyl)silane) is used in the synthesis of silated alkenes and alkynes. Also used in the preparation of fused quinolines.
Uses
Reducing and hydrosilyating agent.
Application
Undergoes exothermic decomposition at >100 °C. Radical-based reducing agent for organic halides, selenides, xanthates and isocyanides and ketones in high yields. Can provide complementary stereoselectivity to tri-n-butyltin hydride in the reduction of gem dihalides. Mild reducing agent in nucleoside chemistry.
General Description
Tris(trimethylsilyl)silane is an organosilicon generally used as a radical reducing agent for xanthates, organic halides, isocyanides, selenides, and acid chlorides. It is also used for hydrosilylation of alkenes, alkynes, and dialkyl ketones.
Purification Methods
Purify it by fractional distillation and taking the middle cut. Store it under N2 or Ar as it is PYROPHORIC and is an IRRITANT. [Chatgilialoglu et al. J Org Chem 53 3641 1988, Balestri et al. J Org Chem 56 678 1991, Chatgilialoglu Acc Chem Res 25 188 1992, NMR: Gilman et al. J Organomet Chem 4 163 1965.]
TRIS(TRIMETHYLSILYL)SILANE Preparation Products And Raw materials
Raw materials
Preparation Products
TRIS(TRIMETHYLSILYL)SILANE Suppliers
View Lastest Price from TRIS(TRIMETHYLSILYL)SILANE manufacturers
- Product
- Tris(trimethylsilyl)silane 1873-77-4
- Price
- US $0.00-0.00/KG
- Min. Order
- 50g
- Purity
- 97%
- Supply Ability
- 10kg
- Release date
- 2021-03-01
- Product
- TRIS(TRIMETHYLSILYL)SILANE 1873-77-4
- Price
- US $20.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10 tons
- Release date
- 2023-11-02
- Product
- TRIS(TRIMETHYLSILYL)SILANE 1873-77-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2023-01-12