2-(Trimethylsilyl)thiazole
- Product Name
- 2-(Trimethylsilyl)thiazole
- CAS No.
- 79265-30-8
- Chemical Name
- 2-(Trimethylsilyl)thiazole
- Synonyms
- 2-TST;Dondoni;Dondoni reagent;2-(trimethyl)thiazole;2-TRIMETHYLSILYTHIAZOLE;2-THIAZOLYTRIMETHYLSILANE;2-Thiazolyltrimethylsilane;2-(TRIMETHYLSILYL)THIAZOLE;2-TRIMETHYLSILANYL-THIAZOLE;trimethyl(2-thiazolyl)silane
- CBNumber
- CB5194791
- Molecular Formula
- C6H11NSSi
- Formula Weight
- 157.31
- MOL File
- 79265-30-8.mol
2-(Trimethylsilyl)thiazole Property
- Boiling point:
- 56-57 °C10 mm Hg(lit.)
- Density
- 0.985 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.497(lit.)
- Flash point:
- 135 °F
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- THF: very soluble(lit.)
- form
- Liquid
- pka
- 2.91±0.10(Predicted)
- Specific Gravity
- 0.99
- color
- Clear colorless to slightly yellow
- Water Solubility
- IMMISCIBLE
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- BRN
- 3538017
- CAS DataBase Reference
- 79265-30-8(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 23-24/25-26
- RIDADR
- 1993
- WGK Germany
- 3
- F
- 10-21
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29341000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H227Combustible liquid
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- T1299
- Product name
- 2-Trimethylsilylthiazole
- Purity
- >95.0%(GC)
- Packaging
- 1mL
- Price
- $53
- Updated
- 2024/03/01
- Product number
- T1299
- Product name
- 2-Trimethylsilylthiazole
- Purity
- >95.0%(GC)
- Packaging
- 5mL
- Price
- $210
- Updated
- 2024/03/01
- Product number
- B21903
- Product name
- 2-(Trimethylsilyl)thiazole, 97%
- Packaging
- 5g
- Price
- $159.65
- Updated
- 2024/03/01
- Product number
- B21903
- Product name
- 2-(Trimethylsilyl)thiazole, 97%
- Packaging
- 1g
- Price
- $51.2
- Updated
- 2021/12/16
- Product number
- B21903
- Product name
- 2-(Trimethylsilyl)thiazole, 97%
- Packaging
- 25g
- Price
- $661.65
- Updated
- 2024/03/01
2-(Trimethylsilyl)thiazole Chemical Properties,Usage,Production
Chemical Properties
Colorless to light yellow liqui
Physical properties
bp 51–53 °C/10 mmHg; d 0.992 g mL?1; nD 1.4980.
Uses
2-(Trimethylsilyl)thiazole is used as formyl anion equivalent; effective one-carbon homologating reagent of alkoxy aldehydes, amino aldehydes, and dialdoses.It takes part in the reactions of Homologation of Aldehydes, Metalation and Reactivity with Electrophiles, Cross-coupling Reactions, etc.
Preparation
Although 2-(trimethylsilyl)thiazole (1) is commercially available, it can be easily prepared on a multigram scale from 2-bromothiazole, n-butyllithium, and chlorotrimethylsilane as shown in eq 1.
2-(Trimethylsilyl)thiazole Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-(Trimethylsilyl)thiazole manufacturers
- Product
- 2-(Trimethylsilyl)thiazole 79265-30-8
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2018-12-21