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Methyl 2-bromo-4-fluorobenzoate

Product Name
Methyl 2-bromo-4-fluorobenzoate
CAS No.
653-92-9
Chemical Name
Methyl 2-bromo-4-fluorobenzoate
Synonyms
RARECHEM AL BF 1088;Bromo-4-fluorobenzoate;2-bromo-4-fluorobenzoate;METHYL 2-BROMO-4-FLUOROBENZOATE;Methyl 4-fluoro-2-bromobenzoate;2-bromo-4-fluoro-3-methylbenzoate;Methyl2-bromo-4-fluorobenzoate98%;Methyl 2-bromo-4-fluorobenzoate 98%;5-fluoro-2-(methoxycarbonyl)bromobenzene;methyl 2-bromo-4-fluorobenzenecarboxylate
CBNumber
CB5198865
Molecular Formula
C8H6BrFO2
Formula Weight
233.03
MOL File
653-92-9.mol
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Methyl 2-bromo-4-fluorobenzoate Property

Boiling point:
75-78/1mm
Density 
1.577
Flash point:
100℃
storage temp. 
Sealed in dry,Room Temperature
InChI
InChI=1S/C8H6BrFO2/c1-12-8(11)6-3-2-5(10)4-7(6)9/h2-4H,1H3
InChIKey
JENBPOJAZCPSEW-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=C(F)C=C1Br
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
22
HazardClass 
IRRITANT
HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
M295998
Product name
Methyl2-bromo-4-fluorobenzoate
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
M295998
Product name
Methyl2-bromo-4-fluorobenzoate
Packaging
500mg
Price
$65
Updated
2021/12/16
Matrix Scientific
Product number
047369
Product name
Methyl 2-bromo-4-fluorobenzoate
Purity
>95%
Packaging
5g
Price
$24
Updated
2021/12/16
Matrix Scientific
Product number
047369
Product name
Methyl 2-bromo-4-fluorobenzoate
Purity
>95%
Packaging
25g
Price
$79
Updated
2021/12/16
AK Scientific
Product number
J56735
Product name
Methyl2-bromo-4-fluorobenzoate
Packaging
25g
Price
$80
Updated
2021/12/16
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Methyl 2-bromo-4-fluorobenzoate Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Synthesis

DBU (1.7 equiv, 1.16 mL, 7.76 mmol) was added to a solution of 2-bromo-4-fluorobenzoicacid (1.0equiv, 1.0 g, 4.57 mmol) and iodomethane (2.0 equiv, 0.57 mL, 9.14 mmol) in CH3CN(11 mL) at 23 °C. After stirring for 48 h, the reaction was quenched with H2O(10 mL) and extracted with Et2O (2 x 10 mL). The combined organic extracts were washed with water (20 mL) and brine (20 mL), dried over Na2SO4 and filtrated. Evaporation of the solvent under reduced pressure followed by flash chromatography (SiO2, 95/5 hexane/EtOAc) afforded 1.0 g (98%)of Methyl 2-bromo-4-fluorobenzoate as a colourless oil.

Methyl 2-bromo-4-fluorobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-bromo-4-fluorobenzoate Suppliers

China 146 Germany 1 India 1 Italy 1 United Kingdom 2 United States 17 Global 168
Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
Key Organics Limited/Bionet Research
Tel
--
Fax
--
Email
enquiries@keyorganics.ltd.uk
Country
United Kingdom
ProdList
6663
Advantage
50
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View Lastest Price from Methyl 2-bromo-4-fluorobenzoate manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Methyl 2-bromo-4-fluorobenzenecarboxylate 653-92-9
Price
US $0.00-0.00/KG
Min. Order
5mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-07
Henan Aochuang Chemical Co.,Ltd.
Product
Methyl2-bromo-4-fluorobenzoate 653-92-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-27
Honest Joy Holdings Limited
Product
Methyl2-bromo-4-fluorobenzoate 653-92-9
Price
US $0.00/KG
Min. Order
1KG
Purity
99.3%
Supply Ability
100 tons
Release date
2022-02-18

653-92-9, Methyl 2-bromo-4-fluorobenzoateRelated Search:

Methyl dihydrojasmonate 2-Bromo-4-fluorobenzoic acid Methyl3-bromo-4-fluorobenzoate98%,Methyl 3-bromo-4-fluorobenzoate 98%,METHYL 3-BROMO-4-FLUOROBENZOATE METHYL 2-BROMO-5-FLUOROBENZOATE,Methyl 2-bromo-5-fluorobenzoate 98%,Methyl2-bromo-5-fluorobenzoate98% METHYL 4-BROMO-3-FLUOROBENZOATE 98,Methyl 4-bromo-3-fluorobenzoate 98% METHYL 4-BROMO-3-FLUOROBENZOATE Methyl 4-bromo-2-fluorobenzoate Methyl 3-bromo-2-fluorobenzoate METHYL 3-BROMO-5-FLUOROBENZOATE tert-Butyl 2-bromo-4-fluorobenzoate METHYL 2-BROMO-4-FLUOROBENZOATE METHYL 2-BROMO-4,5-DIFLUOROBENZOATE RARECHEM AL BI 1088 ETHYL 2-BROMO-4,5-DIFLUOROBENZOATE

  • METHYL 2-BROMO-4-FLUOROBENZOATE
  • Methyl 2-bromo-4-fluorobenzoate 98%
  • Methyl2-bromo-4-fluorobenzoate98%
  • RARECHEM AL BF 1088
  • methyl 2-bromo-4-fluorobenzenecarboxylate
  • Methyl 4-fluoro-2-bromobenzoate
  • 5-fluoro-2-(methoxycarbonyl)bromobenzene
  • Benzoic acid, 2-broMo-4-fluoro-, Methyl ester
  • Bromo-4-fluorobenzoate
  • 2-bromo-4-fluoro-3-methylbenzoate
  • 2-bromo-4-fluorobenzoate
  • 2-Bromo-4-fluorolbenzoicacid methyl ester
  • 653-92-9
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